Patent classifications
B01J21/06
SCR catalyst
The present invention relates to a catalyst comprising at least one oxide of vanadium, at least one oxide of tungsten, at least one oxide of cerium, at least one oxide of titanium and at least one oxide of niobium, and an exhaust system containing said oxides.
Noble metal promoted supported indium oxide catalyst for the hydrogenation of CO.SUB.2 .to methanol and process using said catalyst
Supported catalyst for use in a process for the synthesis of methanol, characterized in that the supported catalyst comprises indium oxide in the form of In.sub.2O.sub.3 and at least one noble metal being palladium, Pd, wherein both indium oxide and at least one noble metal are deposited on a support remarkable in that the supported catalyst is a calcined supported catalyst comprising from 0.01 to 10.0 wt. % of palladium and zirconium dioxide (ZrO.sub.2) in an amount of at least 50 wt. % on the total weight of said supported catalyst.
Regeneration method and device of poisoning honeycomb catalyst
The present invention provides a regeneration method and a regeneration device of a poisoning honeycomb catalyst, and belongs to the field of catalyst regeneration. The regeneration method of the poisoning honeycomb catalyst provided by the present invention includes the following steps: carrying out microwave heating treatment on the poisoning honeycomb catalyst, and then spraying liquid nitrogen into cells of the poisoning honeycomb catalyst so that the poisoning honeycomb catalyst is regenerated. The regeneration method provided by the present invention is simple, and the efficiency of the regenerated catalyst can be increased by 90% more than the original efficiency. According to the regeneration device of a poisoning honeycomb catalyst provided by the present invention, the catalyst regeneration is carried out by using the regeneration device provided by the present invention, the regeneration operation is simple, and the catalytic efficiency of the regenerated catalyst is improved.
Method for preparation of size-modulated UiO-66 and catalyst for hydrolysis of chemical warfare agents with enhanced activity prepared thereby
The present invention relates to a method for preparing size-modulated UiO-66, which is achieved by modulating the concentrations of reactants, and a catalyst with improved activity of hydrolyzing chemical warfare agents prepared by the method.
COMPOSITIONS CONTAINING ZIRCONIUM AND CERIUM AND METHODS FOR PREPARING SAME USING OXALIC ACID AND SUPERCRITICAL DRYING
Disclosed herein are compositions containing zirconium and cerium having a surprisingly small particle size. The compositions disclosed herein contain zirconium, cerium, optionally yttrium, and optionally one or more other rare earth oxides other than cerium and yttrium. The compositions exhibit a particle size characterized by a D.sub.90 value of about 5 μm to about 30 μm and a D.sub.99 value of about 5 um to about 40 um. Further disclosed are processes of producing these compositions using oxalic acid and supercritical drying in the process. The compositions can be used as a catalyst and/or part of a catalytic system. The composition is prepared by co-precipitation using oxalic acid and supercritical drying.
Honeycomb-structured catalyst for organic substance decomposition and organic substance decomposing apparatus
A honeycomb-structured catalyst for decomposing an organic substance, which includes a catalyst particle. The catalyst particle contains a perovskite-type composite oxide represented by A.sub.xB.sub.yM.sub.zO.sub.w, where the A contains at least of Ba and Sr, the B contains Zr, the M is at least one of Mn, Co, Ni, and Fe, y+z=1, 1.001≤x≤1.05, 0.05≤z≤0.2, and w is a positive value that satisfies electrical neutrality. The toluene decomposition rate is greater than 90% when toluene is decomposed using the honeycomb-structured catalyst subjected to a heat treatment at 1200° C. for 48 hours and a gas that contains 50 ppm toluene, 80% nitrogen, and 20% oxygen as a volume concentration as a target at a space velocity of 30,000/h and a catalyst temperature of 400° C.
Biorenewable hydrocarbon compositions and their uses
Disclosed are compositions comprising dimeric decarboxylated rosins (DDCRs), methods for making them, and applications thereof. DDCR of purity from 50-100 wt. % is obtained by decarboxylating a dimeric rosin acid or by dimerizing a decarboxylated rosin, in the presence of a catalyst, followed by one or more purification steps separation on differences in boiling point. The isolated DDCR fractions display unexpectedly high T.sub.g/M.sub.n ratios, softening points and viscosities, and low polydispersities. The DDCR product comprises 50 to 100 wt. % of polycyclic hydrocarbon compounds having one or more aliphatic, unsaturated or aromatic groups, and 34-80 carbon atoms, with a molecular weight M.sub.n of 250-900 Da, and an oxygen to carbon ratio of <5%. The DDCR product has at least 50%, and up to 100% as dimeric species, with the remainder being trimeric and larger polymeric species.
Cyclonic vehicular traffic pollution control system
A filter may remove PM.sub.2.5 and/or other airborne pollutants, which filter has fibers of an average diameter of no more than 500 nm, the fibers of at least 90 wt. % polyacrylonitrile, relative to all fibers in the filter; and a catalyst of at least 90 wt. % TiO.sub.2, relative to all catalytic metals in the filter, dispersed onto the fibers. The fibers need not be charged. The TiO.sub.2 may be condensed or precipitated onto the fibers out of a liquid containing the TiO.sub.2 and the fibers by simple methods. The catalyst may be activated by UV irradiation to decompose particulate matter having an average particle size of 2.5 μm or less, i.e., PM.sub.2.5, and/or other airborne pollutants from air. Such filters may be implemented around areas of vehicle traffic, e.g., as elements of traffic lights, and may be used to controllably purify polluted air.
CATALYST MEDIUM COMPRISING HOLLOW MICROSPHERES
The present invention relates to a calcined medium, in particular a catalyst or a catalyst medium or an adsorbent/absorbent mass, in particular in the form of extrudates, pellets, granules or beads, the medium comprising a porous matrix comprising carbonates, clays, zeolites, oxides, or metal and/or silicon hydroxides, and the matrix incorporating hollow mineral microspheres having a different composition in a content of between 0.3 and 50% by weight, in particular between 0.5 and 15% by weight, of the matrix.
METHOD FOR PRODUCING GUERBET ALCOHOL
A method for producing a Guerbet alcohol, including reacting a raw material alcohol having 8 or more and 22 or less carbon atoms, in the presence of a catalyst (A) containing a first component, a second component, and a third component below: first component: copper, second component: one kind selected from the group consisting of cobalt, nickel, molybdenum, and rhenium, and third component: at least one kind selected from the group consisting of elements that are elements belonging to Groups 3 to 10 and 12 of the fourth period of the periodic table and elements belonging to Groups 3 to 7, 11, and 12 of the fifth and sixth periods of the periodic table, and are different from the element selected as the second component.