Treated articles and a process of producing the treated articles, systems having treated articles, and processes incorporating treated articles are disclosed. The treated articles include a metal or metallic substrate, and a surface treatment of the metal or metallic substrate, the surface treatment having fluorine, silicon, and carbon. The systems include a flow path, with the surface treatment being within the flow path. The processes include flowing a fluid through the flow path.

To provide a process for producing a fluoroolefin copolymer powder for powder coating material, which presents excellent stability of a fluoroolefin copolymer solution obtainable by polymerization in its production process, and which is capable of forming a cured film having an excellent appearance when used for a powder coating material. A monomer mixture comprising specific monomers is polymerized in an organic solvent in the presence of specific amounts of hydrotalcite and at least one compound (B) selected from a potassium salt, a sodium salt, a magnesium salt and a hindered amine-type light stabilizer, to obtain a suspension; an insoluble component is removed from the suspension to obtain a fluoroolefin copolymer solution having a pH of from 3.8 to 6.5 and an APHA value within a range of from 1 to 200; and the organic solvent is removed from the solution to obtain the fluoroolefin copolymer powder.

To provide a composition for powder coating material capable of forming a coating film having excellent water and oil repellency, capable of maintaining excellent water and oil repellency even when the surface is rubbed or when used in an environment in contact with water, and having excellent resistance to adhesion of organisms such that organisms such as mold, algae, etc. are less likely to adhere thereto; a powder coating material; and a coated article. The composition for powder coating material comprises polymer (A) composed of at least one member selected from polymer (A1) and polyvinylidene fluoride, and polymer (B). The polymer (A1) is a fluorinated non-block copolymer having units based on a fluoroolefin and units based on a monomer having a crosslinkable group. The polymer (B) is a fluorinated block copolymer having a segment (α) in which the content of fluorine atoms is at least 20 mass %, and a segment (β) in which the content of fluorine atoms is less than 20 mass %, wherein the difference in the numerical value of the content of the fluorine atoms represented by mass %, between in the segment (α) and in the segment (β) is at least 10, and at least one of the segment (α) and the segment (β) has a hydroxy group.

A method of manufacturing a bi-layered coating is provided, which includes applying a primer paint on a substrate, wherein the primer paint includes 100 parts by weight of a first polyvinyl fluoride, 20 to 50 parts by weight of an assistance resin, and 150 to 170 parts by weight of a first latent solvent, and wherein the assistance resin is polyester modified epoxy resin, polyester type polyurethane resin, phenoxy resin, or a combination thereof. The primer paint is baked and dried to form a primer coating. A finish paint is then applied onto the primer coating, wherein the finish paint includes 100 parts by weight of a second polyvinyl fluoride and 120 to 150 parts by weight of a second latent solvent. The finish paint is baked and dried to form a finish coating on the primer coating.

A method of manufacturing a coating is provided, which includes applying a primer paint on a substrate, wherein the primer paint includes 100 parts by weight of a first PVF, 30-70 parts by weight of an assistance resin, 5-30 parts by weight of a curing agent, 100-120 parts by weight of a first latent solvent, 3-methoxy-3-methyl-1-butanol, and water. The first latent solvent, 3-methoxy-3-methyl-1-butanol, and water have a weight ratio of 60:10-20:40-60. The method also applies a finish paint on the primer paint, wherein the finish paint includes 100 parts by weight of a second PVF, 100-120 parts by weight of a second latent solvent, 3-methoxy-3-methyl-1-butanol, and water, wherein the second latent solvent, 3-methoxy-3-methyl-1-butanol, and water have a weight ratio of 50:10-20:30-60. The primer paint and the finish paint are baked and dried to form a coating.

A coating composition includes a fluoroethylene vinyl ether copolymer, a cross-linking agent, and water. The coating composition reduces the operating temperature of an overhead conductor by at least about 5° C. or more compared to a similar uncoated overhead conductor when the operating temperatures of each overhead conductor are measured at about 100° C. or higher and the coating composition is substantially free of solvent. Methods for making a coating composition and for making a coated overhead conductor are disclosed.

To provide a repairing method, by which a coated article having high adhesion between a PVDF coating film and a repair coating film and favorable processability of the repair coating film can be obtained, and a repaired coated article.

A method for repairing a first coating film, which comprises applying a second coating material (repairing coating material) to a position to be repaired of a first coating film (PVDF coating film) formed by applying a first coating material to the surface of a substrate, to form a second coating film (repair coating film) thereby to repair the first coating film,

wherein the first coating material is a powder coating material containing PVDF (A) and a resin (B), wherein the second coating material is a coating material containing a fluororesin (L) and a titanium oxide pigment (M), and wherein the content of the titanium oxide pigment (M) is from 15 to 190 parts by mass per 100 parts by mass of the fluororesin (L).

This coated metal sheet for exterior covering has a metal sheet and a top coating layer disposed on the metal sheet, the top coating layer is configured from a fluororesin and contains a gloss control agent comprising 0.01-15 vol % of microporous particles and a matte agent comprising primary particles, and the coated metal sheet satisfies the belowmentioned formulae. In the number-based particle size distribution of the gloss control agent and the matte agent, R is the number average particle size (μm) of the gloss control agent, D1.sub.97.5 and D2.sub.97.5 represent the 97.5% particle size (μm) of the gloss control agent and the matte agent, Ru is the upper limit particle size (μm) of the gloss control agent, and T is the top coating layer thickness (μm).

D1.sub.97.5/T≦0.9

Ru≦1.2T

R≧1.0

0.5≦D2.sub.97.5/T≦7.0

3≦T≦40.

This coated metal sheet for exterior covering has a metal sheet and a top coating layer disposed on the metal sheet, the top coating layer is configured from a fluororesin and contains a gloss control agent comprising 0.01-15 vol % of microporous particles and a matte agent comprising primary particles, and the coated metal sheet satisfies the belowmentioned formulae. In the number-based particle size distribution of the gloss control agent and the matte agent, R is the number average particle size (μm) of the gloss control agent, D1.sub.97.5 and D2.sub.97.5 represent the 97.5% particle size (μm) of the gloss control agent and the matte agent, Ru is the upper limit particle size (μm) of the gloss control agent, and T is the top coating layer thickness (μm).

D1.sub.97.5/T≦0.9

Ru≦1.2T

R≧1.0

0.5≦D2.sub.97.5/T≦7.0

3≦T≦40.

To provide a powder coating material capable of forming a coating film excellent in weather resistance, coating film appearance and surface smoothness; and a coated article having a coating film made of such a powder coating material. A powder coating material comprising a powder composed of a first composition which is a first composition for powder coating material comprising a fluororesin having a fluorine content of at least 10% by mass and a plasticizer having a melting point of from 60 to 200° C. and having a cyclic hydrocarbon group in the molecule, wherein the content of the plasticizer is from 0.1 to 40 parts by mass, to 100 parts by mass of the resin component contained in the first composition. And, a powder coating material comprising a powder composed of a second composition containing the fluororesin and a powder composed of a third composition containing a resin other than the fluororesin, wherein at least one of the second composition and the third composition contains a plasticizer, and the content of the plasticizer is from 0.1 to 40 parts by mass, to 100 parts by mass in total of the resin components contained in the second composition and the third composition.