Configurations and related processing schemes of direct or indirect inter-plants (or both) heating systems synthesized for grassroots medium grade crude oil semi-conversion refineries to increase energy efficiency from specific portions of low grade waste heat sources are described. Configurations and related processing schemes of direct or indirect inter-plants (or both) heating systems synthesized for integrated medium grade crude oil semi-conversion refineries and aromatics complex for increasing energy efficiency from specific portions of low grade waste sources are also described.

Apparatus and methods for denitrification and desulfurization of and dust removal from an FCC tail gas by ammonia-based process. The apparatus may include a first-stage waste heat recovery system a denitrification system, a dust removal and desulfurization system, a tail gas, exhaust system, and an ammonium sulfate post-processing system. The dust removal and desulfurization system may include as deducting tower and an absorption tower disposed separately. The top and the bottom of the absorption tower may be connected respectively to the tail gas exhaust system and the ammonium sulfate post-processing system. The absorption tower may include sequentially, from bottom to top, an oxidation section, an absorption section, and a fine particulate control section. The methods may be implemented with the apparatus.

Methods of sequestering carbon dioxide (CO.sub.2) are provided. Aspects of the methods include contacting an aqueous capture ammonia with a gaseous source of CO.sub.2 under conditions sufficient to produce an aqueous ammonium carbonate. The aqueous ammonium carbonate is then combined with a cation source under conditions sufficient to produce a solid CO.sub.2 sequestering carbonate and an aqueous ammonium salt. The aqueous capture ammonia is then regenerated from the from the aqueous ammonium salt. Also provided are systems configured for carrying out the methods.

A gas scrubber may include an absorption apparatus configured for receiving a gas and absorbing the gas in an absorption medium, as well as an evaporation apparatus configured for evaporating at least a part of the liquid that is introduced. The absorption apparatus may have an introduction apparatus for the gas, an apparatus for circulating the absorption solution that has reacted with the gas, a discharge apparatus for at least a part of the absorption solution that has reacted with the gas, and a cooling system for the circulating absorption solution. The absorption apparatus and the evaporation apparatus can be connected via a heat exchanger such that heat content of the absorption solution that has reacted with the gas is used at least in part for the evaporation.

Systems and methods for providing regeneration heat to a sorbent material and subsequently recovering a significant portion of the heat are provided. The systems and methods are useful, for example, for energy-efficient direct capture of carbon dioxide (CO.sub.2) from the atmosphere or flue gases. The systems and methods include introducing steam generated by an evaporator into a reactor of the system to directly heat sorbent material in the reactor and to purge desorbed CO.sub.2 from the reactor using the steam. Water condensing within the reactor is drained and returned to the evaporator. The purged steam and CO.sub.2 from the reactor are directed to a vapor re-compressor to lift their temperature and then to a condenser or re-boiler where the water is condensed and separated from the CO.sub.2 and latent heat transferred to the cooling water is recovered, optionally via use of a jet ejector.

Systems and methods for providing regeneration heat to a sorbent material and subsequently recovering a significant portion of the heat are provided. The systems and methods are useful, for example, for energy-efficient direct capture of carbon dioxide (CO.sub.2) from the atmosphere or flue gases. The systems and methods include introducing steam generated by an evaporator into a reactor of the system to directly heat sorbent material in the reactor and to purge desorbed CO.sub.2 from the reactor using the steam. Water condensing within the reactor is drained and returned to the evaporator. The purged steam and CO.sub.2 from the reactor are directed to a vapor re-compressor to lift their temperature and then to a condenser or re-boiler where the water is condensed and separated from the CO.sub.2 and latent heat transferred to the cooling water is recovered, optionally via use of a jet ejector.

A process for hydrotreating a feed stream comprising a biorenewable feedstock is disclosed. The process comprises hydrotreating the feed stream in the presence of a hydrotreating hydrogen stream and a hydrotreating catalyst to provide a hydrotreated stream. The hydrotreated stream is separated into a hydrotreated liquid stream and a hydrotreated gas stream. The hydrotreated liquid stream is subjected to stripping to provide a stripper off-gas stream. At least a portion of the stripper off-gas stream is contacted with a caustic stream to provide a sulfur-lean gas stream and a sulfur-rich caustic stream. The sulfur-rich caustic stream is further treated to provide a treated gas stream.

In accordance with exemplary inventive practice, a catalytic system and a temperature swing adsorption system are thermally integrated. The temperature range of the adsorption system is lower than the catalyst operating temperature. Benefits of inventive practice include reduction of total energy consumption and of generated waste-heat. Total energy consumption is reduced by transferring some of the waste-heat generated by the catalytic system into the adsorption system during the sorbent heat-up portion of the sorbent regeneration cycle. The heat is transferred using a thermal reservoir, which accumulates heat from the catalytic apparatus and transfers it to the adsorption apparatus at a later time, and which is repeatedly cycled as the sorbent is cycled. The catalytic system and the adsorption system can be inventively integrated in various ways to reduce the total energy consumed, and/or to modify the sorbent regeneration temperature profile, and/or to obtain an optimum power load profile.

Methods of sequestering carbon dioxide (CO.sub.2) are provided. Aspects of the methods include contacting an aqueous capture ammonia with a gaseous source of CO.sub.2 under conditions sufficient to produce an aqueous ammonium carbonate. The aqueous ammonium carbonate is then combined with a cation source under conditions sufficient to produce a solid CO.sub.2 sequestering carbonate and an aqueous ammonium salt. The aqueous capture ammonia is then regenerated from the from the aqueous ammonium salt. Also provided are systems configured for carrying out the methods.

Configurations and related processing schemes of specific inter-plants and hybrid, intra- and inter-plants waste heat recovery schemes for thermal energy consumption reduction in integrated refining-petrochemical facilities synthesized for grassroots medium grade crude oil semi-conversion refineries to increase energy efficiency from specific portions of low grade waste heat sources are described. Configurations and related processing schemes of specific inter-plants and hybrid, intra- and inter-plants waste heat recovery schemes for thermal energy consumption reduction in integrated refining-petrochemical facilities synthesized for integrated medium grade crude oil semi-conversion refineries and aromatics complex for increasing energy efficiency from specific portions of low grade waste sources are also described.