The aluminum silicate of the invention has: an element ratio of Si and Al, represented by Si/Al, of from 0.3 to 1.0 by molar ratio; a peak at approximately 3 ppm in a .sup.27Al-NMR spectrum; peak A at approximately −78 ppm and peak B at approximately −85 ppm in a .sup.29Si-NMR spectrum; and a peak at approximately 2θ=26.9° and a peak at approximately 2θ=40.3° in a powder X-ray diffraction spectrum. The aluminum silicate has an area ratio of peak B with respect to peak A of from 2.0 to 9.0, or does not include a tubular substance having a length of 50 nm or more as observed in a transmission electron microscope (TEM) photograph of the aluminum silicate taken at a magnification of 100,000. The aluminum silicate is produced by a method comprising: subjecting a reaction product of a silicate ion solution and an aluminum ion solution to desalting and solid separation; subjecting a resultant to a thermal treatment in an aqueous medium in the presence of an acid under concentration conditions in an aqueous medium such that a silicon atom concentration is 100 mmol/L or more and an aluminum atom concentration is 100 mmol/L or more; and subjecting a resultant to further desalting and solid separation.

A sorbent material is disclosed for the one-step separation of bio-macromolecules in a single pass extraction of DNA from complex mixtures of molecules and chemicals. In one embodiment, the sorbent material comprises a silanized material at least partially coated or formed with a polymer selected from the group consisting of a poly(aryl methacrylate), a poly(aryl acrylate), a poly(heteroaryl methacrylate, a poly(heteroaryl acrylate) and a copolymer thereof.

Compositions suitable for the purification of liquids, methods for making said compositions, and the uses of said compositions.

Compositions suitable for the purification of liquids, methods for making said compositions, and the uses of said compositions.

The present disclosure generally relates to methods for separating Δ.sup.8-THC, Δ.sup.9-THC, and related enantiomers using CO.sub.2-based chromatography.

Oxygen carriers for chemical looping and scalable methods of preparation thereof. Wet impregnation of active metal precursors into porous substrates, together with selective adsorption of the precursors on the pore surfaces, enables transition metal oxides derived from the precursors to disperse throughout the substrate, even at the nanoscale, without increased sintering or agglomeration. The porous substrate can be an oxide, for example SiO.sub.2. The oxygen carriers can comprise relatively large oxide loadings of over about 20 wt % and exhibit high reactivity over many regeneration cycles with substantially no loss in oxygen transport capacity or decrease in kinetics. The use of multiple transition metals, for example NiO in addition to CuO, can greatly enhance chemical looping performance.

The present disclosure provides a method for synthesizing fibrous silica nanospheres, the method can include, in sequence, the steps of: a) providing a reaction mixture comprising a silica precursor, a hydrolyzing agent, a template molecule, a cosurfactant and one or more solvents; b) maintaining the reaction mixture under stirring for a length of time; c) heating the reaction mixture to a temperature for a length of time; d) cooling the reaction mixture to obtain a solid, and (e) calcinating the solid to pro duce fibrous silica nanospheres, wherein desirable product characteristics such as particle size, fiber density, surface area, pore volume and pore size can be obtained by controlling one or more parameters of the method. The present disclosure further provides a method for synthesizing fibrous silica nanospheres using conventional heating such as refluxing the reactants in an open reactor, thereby eliminating the need for microwave heating in a closed reactor or the need for any pressure reactors.

A diatomite product and method of using such is disclosed. The diatomite product may comprise sodium flux-calcined diatomite, wherein the diatomite product has a crystalline silica content of less than about 1 wt %, and the diatomite product has a permeability between 0.8 darcy and about 30 darcy. In some embodiments, the diatomite product may be in particulate or powdered form. This disclosure also concerns flux-calcined silica products containing low or non-detectable levels of crystalline silica. Some of these products can be further characterized by high permeabilities and a measurable content of opal-C, a hydrated form of silicon dioxide.

A diatomite product and method of using such is disclosed. The diatomite product may comprise sodium flux-calcined diatomite, wherein the diatomite product has a crystalline silica content of less than about 1 wt %, and the diatomite product has a permeability between 0.8 darcy and about 30 darcy. In some embodiments, the diatomite product may be in particulate or powdered form. This disclosure also concerns flux-calcined silica products containing low or non-detectable levels of crystalline silica. Some of these products can be further characterized by high permeabilities and a measurable content of opal-C, a hydrated form of silicon dioxide.

This invention is directed to amorphous and crystalline titanosilicate materials that have an unexpected selectivity for cesium and strontium, especially in the presence of high levels of competing ions. The titanosilicates of this invention show very high, unexpected selectivity in the presence of such competing cations such as sodium, calcium, magnesium and potassium, such as present in seawater.