In embodiments, a packing material for supported liquid extraction has a sorbent media that includes synthetic silica particles. In embodiments, the synthetic silica particles can have physical properties relating to one or more of particle surface area, shape, size, or porosity. In one embodiment, synthetic silica particles have a surface area less than about 30 m.sup.2/g. In another embodiment, the synthetic silica particles have an approximately uniform particle shape. In further examples, synthetic silica particles have a particle size in a range of about 30-150 μm inclusive or greater than about 200 μm. In another embodiment, synthetic silica particles are arranged to have a pore size greater than about 500 Angstroms. In an embodiment, an apparatus for supported liquid extraction includes a container and a sorbent media that includes synthetic silica particles. In a further embodiment, a method for extracting target analytes through supported liquid extraction is provided.

The present invention relates yolk-shell nanoparticles having both a high stability towards sintering and high H.sub.25 adsorption capacities, the use of the yolk-shell nanoparticles in a method for H.sub.2S removal from gas streams, and a corresponding method for H.sub.2S removal from gas streams also comprising the regeneration of the yolk-shell nanoparticles, wherein the yolk-shell nanoparticles provide for high H.sub.2 adsorption capacities and/or high reusability.

Disclosed is a method for preparing a hybrid organic/inorganic composition including inorganic nanoparticles functionalized by at least one molecule chosen from photoluminescent charged organic molecules, the method including bringing into contact, in a single-phase solvent medium, at least one photoluminescent charged organic molecule and non-swelling phyllosilicate nanoparticles having a thickness of 1 nm to 100 nm, and a larger dimension of 10 nm to 10 μm. Also disclosed are hybrid photoluminescent nanoparticles compositions obtained by this method.

Disclosed is a method for preparing a hybrid organic/inorganic composition including inorganic nanoparticles functionalized by at least one molecule chosen from photoluminescent charged organic molecules, the method including bringing into contact, in a single-phase solvent medium, at least one photoluminescent charged organic molecule and non-swelling phyllosilicate nanoparticles having a thickness of 1 nm to 100 nm, and a larger dimension of 10 nm to 10 μm. Also disclosed are hybrid photoluminescent nanoparticles compositions obtained by this method.

The present disclosure relates to a porous liquid or a porous liquid enzyme that includes a high surface area solid and a liquid film substantially covering the high surface area solid. The porous liquid or porous liquid enzyme may be contacted with a fluid that is immiscible with the liquid film such that a liquid-fluid interface is formed. The liquid film may facilitate mass transfer of a substance or substrate across the liquid-fluid interface. The present disclosure also provides methods of performing liquid-based extractions and enzymatic reactions utilizing the porous liquid or porous liquid enzyme of the present disclosure.

A method of preparing a superabsorbent polymer, which enables the preparation of the superabsorbent polymer exhibiting an improved absorption rate while maintaining excellent absorption performances is provided. The method of preparing the superabsorbent polymer includes carrying out a crosslinking polymerization of a water-soluble ethylene-based unsaturated monomer having acidic groups which are at least partially neutralized, in the presence of an internal crosslinking agent having a predetermined chemical structure to form a water-containing gel polymer, gel-pulverizing the water-containing gel polymer, drying, pulverizing, and size-sorting the gel-pulverized water-containing gel polymer to form a base polymer powder, and carrying out a surface crosslinking of the base polymer powder by a heat treatment in the presence of a surface crosslinking agent, wherein the gel-pulverizing is carried out by extruding the water-containing gel polymer through a porous plate having a plurality of holes using a screw extruder mounted inside a cylindrical pulverizer under a condition that a chopping index is 28 (/s) or more.

A smart sand includes raw sand particles, synthetic SiO.sub.2 particles attached to the raw sand particles, a first material attached to a first set of the synthetic SiO.sub.2 particles, a second material attached to a second set of the synthetic SiO.sub.2 particles, and a third material attached to the first material. Each of the first to third materials is different from each other.

A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula A.sub.x(L.sup.-x) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula A.sub.x(L.sup.-x)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula H.sub.x(L.sup.- .sup.x)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M.sup.+y(B).sub.y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M.sup.+y(B).sub.y][H.sub.x(L.sup.-x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M.sup.+yL.sup.-x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.

A silica-based stationary phase for chromatography columns and the methods of preparing such. More particularly, but not by way of limitation, a silica-based stationary phase that is substantially free of polyethers (e.g., polymer glycols). Also, a chromatography column comprising a silica-based stationary phase substantially free of polyethers (e.g., polymer glycols) within its channels as either a thin-film coating and/or a monolith and/or a monolithic coating. More particularly, a micro-electro-mechanical system (MEMS) chromatograph comprising a silica-based monolith substantially free of polyethers (e.g., polymer glycols) as the stationary phase within the micro-channels of the column.

A method for producing a chemical reactor device based on a fluid flow comprises obtaining a substrate with a fluid channel defined by a channel wall, in which an ordered set of silicon pillar structures is positioned in the fluid channel and electrochemically anodising at least the silicon pillar structures to make the silicon pillar structures porous at least to a certain depth. After the anodising, the substrate and pillar structures are thermally treated, the treatment being carried out at a temperature, with a duration and in an atmosphere such that any silicon oxide layer formed has a thickness of less than 20 nm. The substrate and the pillar structures are further functionalized.