The present invention relates to the field of solid materials for the adsorption of lithium. In particular, the present invention relates to a novel process for preparing a solid crystalline material formed preferably in extrudate form, of formula (LiCl).sub.x.2Al(OH).sub.3,nH.sub.2O with n being between 0.01 and 10, x being between 0.4 and 1, comprising a step a) to precipitate boehmite under specific conditions of temperature and pH, a step to place the precipitate obtained in contact with a specific quantity of LiCl, at least one forming step preferably via extrusion, said process also comprising a final hydrothermal treatment step, all allowing an increase in lithium adsorption capacity and in the adsorption kinetics of the materials obtained compared to prior art materials, when used in a process to extract lithium from saline solutions.

A method of recovering lithium from energy process water includes the steps of: removing alkaline earth metals from the water; passing the treated water through a reactor column containing a titanium oxide molecular sieve that adsorbs lithium ions; eluting the lithium ions from the molecular sieve using a strong acid solution; and collecting the resulting lithium-rich eluate fluid from the reactor column. The reactor column may include a diffuser core at the inlet tapered from a wider base to a narrow inner end as well as a first screen through which the fluid flows. Fluid exits the inner volume of the column through an outlet tube including a mounted end and walls that taper from the mounted end to a narrower tip; the walls include a second screen through which the fluid flows.

A method of recovering lithium from energy process water includes the steps of: removing alkaline earth metals from the water; passing the treated water through a reactor column containing a titanium oxide molecular sieve that adsorbs lithium ions; eluting the lithium ions from the molecular sieve using a strong acid solution; and collecting the resulting lithium-rich eluate fluid from the reactor column. The reactor column may include a diffuser core at the inlet tapered from a wider base to a narrow inner end as well as a first screen through which the fluid flows. Fluid exits the inner volume of the column through an outlet tube including a mounted end and walls that taper from the mounted end to a narrower tip; the walls include a second screen through which the fluid flows.

Devices for the separation of components within a fluid are disclosed herein. The device typically includes layers of spacers and separation surfaces. The separation panels have channels with functionalized surfaces to attract and retain components within the fluid. The separation panels include a border (housing) to constrain the fluid.

Devices for the separation of components within a fluid are disclosed herein. The device typically includes layers of spacers and separation surfaces. The separation panels have channels with functionalized surfaces to attract and retain components within the fluid. The separation panels include a border (housing) to constrain the fluid.

The present invention relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from minerals, and recycled products.

The present invention relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from minerals, and recycled products.

Certain embodiments described herein are directed to systems and methods that can be used to analyze species in a fluid stream. In some configurations, a sorbent tube effective to directly sample aromatics and/or polyaromatics in a fluid stream is described.

The present disclosure relates to a method of separating a compound of interest, particularly unsaturated compound(s) of interest, from a mixture. The compound is separated using a column having a chromatographic stationary phase material for various different modes of chromatography containing a first substituent and a second substituent. The first substituent minimizes compound retention variation over time under chromatographic conditions. The second substituent chromatographically and selectively retains the compound by incorporating one or more aromatic, polyaromatic, heterocyclic aromatic, or polyheterocyclic aromatic hydrocarbon groups, each group being optionally substituted with an aliphatic group. In some examples, the present disclosure can include a chromatographic system having a chromatographic column having a stationary phase with a chromatographic substrate containing silica, metal oxide, an inorganic-organic hybrid material, a group of block copolymers, or a combination thereof.

The montmorillonite-based liquid chromatography column is a chromatography column, which may be steel, packed with unmodified montmorillonite for use in normal phase liquid chromatography, particularly high-performance liquid chromatography (HPLC). The column may be prepared by sieving montmorillonite to achieve a desired particle size range, preferably in the micrometer range, i.e., montmorillonite microparticles, and more preferably between 5-10 m. The montmorillonite microparticles are suspended in a solvent, for example, ethanol, and packed into a column for use in HPLC. Before packing, the montmorillonite microparticles may be dried by, for example, heating for a period of time, e.g., by heating preferably at about 100 C. for at least 2 hours. The packing may be performed at a pressure of at least 5000 psi, and more preferably, between 5000-7000 psi. The column may be used for separation of simple polar compounds under relatively low pressure conditions.