A porous calcium silicate hydrate, a preparation method thereof and an adsorbent are provided. The preparation method of the porous calcium silicate hydrate includes: leaching fly ash with an alkali agent to obtain a silicate leaching solution; adding the silicate leaching solution dropwise to a calcium hydroxide suspension at a constant rate, and conducting stirring and a heating reaction to obtain a calcium silicate hydrate gel; and mixing the calcium silicate hydrate gel with an organic alcohol solvent, conducting azeotropic distillation, and then conducting separation, drying and calcination to obtain the porous calcium silicate hydrate.

A method for producing a modified sawdust sorbent. The method involves sulfonating sawdust with sulfuric acid and oxidizing the sulfonated sawdust with hydrogen peroxide. The method yields a modified sawdust sorbent containing sulfonated and oxidized cellulose. The modified sawdust sorbent has a higher surface area, higher organic dye adsorption capacity, and more rapid organic dye adsorption rate than unmodified sawdust. A method for organic dye removal from water includes using the modified sawdust sorbent to absorb dyes from water.

A method for producing a modified sawdust sorbent. The method involves sulfonating sawdust with sulfuric acid and oxidizing the sulfonated sawdust with hydrogen peroxide. The method yields a modified sawdust sorbent containing sulfonated and oxidized cellulose. The modified sawdust sorbent has a higher surface area, higher organic dye adsorption capacity, and more rapid organic dye adsorption rate than unmodified sawdust. A method for organic dye removal from water includes using the modified sawdust sorbent to absorb dyes from water.

The present invention discloses a method for separating propylene, propyne, propane and propadiene from mixed gas, wherein, comprising: a high purity component can be obtained as metal-organic frameworks as adsorbents through adsorptive separation and purification of a mixed gas containing propylene, propyne, propane and propadiene a general structural formula of the metal-organic framework material is [M(C.sub.4O.sub.4)(H.sub.2O)].Math.1.5H.sub.2O, wherein M is metal ions, the metal-organic framework material is a three-dimensional network structure formed by transition metal ions or alkaline earth metal ions and squaric acid through coordination bonds or intermolecular forces. The metal-organic framework materials of the present invention exhibit excellent adsorption and separation performances for propylene, propyne, propane and propadiene. The cheap and available raw materials for the synthesis, simple operation, and low cost make it cost-efficient for preparation of such metal-organic frameworks. Besides, the good regeneration and repeatability, the adsorption performances kept intact with that of the original one after being activated under vacuum for several times, indicating that they have a great promising and potential for industrial application.

Disclosed are a transition metal-doped carbon microsphere, a preparation method therefor and an application thereof. The transition metal-doped carbon sphere has a uniform solid porous structure, and the transition metal is uniformly distributed inside the carbon sphere. The preparation method comprises that a carbon microsphere uniformly doped with manganese, vanadium, molybdenum and tungsten is prepared by means of a one-step hydrothermal method, is mixed with potassium oxalate, and is roasted in a protective atmosphere to obtain an activated metal-doped carbon sphere. The doped transition metal elements remain uniformly dispersed after being roasted, and do not agglomerate. The transition metal-doped carbon microsphere obtained has the following characteristics: it exhibits good adsorption properties for heavy metal ions Cr(VI), with the maximum adsorption amount being 660.7 mg/g; it can achieve advanced removal of Cr(VI) from the wastewater of which the initial Cr(VI) concentration is lower than 200 mg/L, with the residual Cr(VI) concentration after adsorption being lower than 0.05 mg/L; and it shows good application prospect in the treatment of wastewater containing heavy metal.

The present disclosure is related to processes for efficient large-scale preparation of alkylated cyclodextrins. The processes of the present disclosure provide high purity alkylated cyclodextrins with high purity and low levels of chloride while improving efficiency, increasing batch size, and reducing total process time.

Methods for producing porous graphic carbon microspheres having improved separation properties over conventional porous graphitic carbons. The methods include dispersing a monovinyl aromatic monomer, a polyvinyl aromatic monomer, and an initiator in a solvent, contacting porous silica microspheres with the monomer dispersion for a time sufficient for the monomers to coat the porous silica microspheres, polymerizing the monomers to form copolymer coated microspheres, sulfonating the copolymer, pyrolyzing the sulfonated copolymer, digesting the carbon microspheres to dissolve the silica leaving porous carbon microspheres, pyrolyzing the porous carbon microspheres, and graphitizing the porous carbon microspheres to form porous graphitic carbon microspheres. Further provided are improved porous graphitic carbon microspheres and chromatography columns including the improved porous graphitic carbon microspheres described herein.

An adsorbent that includes: particles of a layered material including one or plural layers; and one or more metal atoms selected from Al, Mg, Ca, Ba, Fe, Zn, Mn, or Cu. The one or plural layers include a layer body represented by: M.sub.mX.sub.n wherein M is at least one metal of Group 3, 4, 5, 6, or 7, X is a carbon atom, a nitrogen atom, or a combination thereof, n is 1 to 4, and m is more than n and 5 or less. A modifier or terminal T exists on a surface of the layer body, T is at least one of a hydroxyl group, a fluorine atom, a chlorine atom, an oxygen atom, or a hydrogen atom, and the M of the layer body is bonded to at least one of a chlorine atom, a phosphorus atom, an iodine atom, or a sulfur atom.

An adsorbent that includes a particle of a layered material that contains one or a plurality of layers; and contains Li. The one or plural layers includes a layer body represented by: M.sub.mX.sub.n where, M represents at least one Group-3, -4, -5, -6, or -7 metal, X represents a carbon atom, a nitrogen atom, or a combination thereof, n is 1 to 4, and m is larger than n, and equal to or less than 5; and a modified/terminal part T resides on a surface of the layer body, T represents at least one selected from the group consisting of hydroxy group, fluorine atom, chlorine atom, oxygen atom, and hydrogen atom, the modified/terminal part T residing on a surface of the layer body, the particle has an average thickness of 1 nm to 10 nm, and the adsorbent has a Li content of 0.0001% by mass to 0.0020% by mass.

A metal oxide impregnated activated carbon and a method of making the metal oxide impregnated carbon wherein the application of metal oxide impregnants are chemisorbed to active sites in a pore structure using atomic layer deposition to enable targeted impregnant compositions and configurations on activated carbons used for air purification devices.