A laminate containing a metallic base layer and a transparent colored layer formed on the metallic base layer. The metallic base layer contains an aluminum pigment, a light-scattering component, a surface adjusting agent, and a rheology control agent, the aluminum pigment being present in an amount of 15 to 70 parts by mass, on a solids basis; and the light-scattering component being present in an amount of 5 to 55 parts by mass, on a solids basis, based on 100 parts by mass of the metallic base layer. The transparent colored layer contains a resin component, a curing agent, and a color pigment, the color pigment being present in an amount of 0.5 to 10 parts by mass, based on 100 parts by mass of the resin solids content of the transparent colored layer.

A laminate containing a metallic base layer and a transparent colored layer formed on the metallic base layer, wherein, when

X=[(C*45).sup.2+(C*75).sup.2)].sup.1/2, and

Y=[(L*15).sup.2+(C*15).sup.2)].sup.1/2+[(L*25).sup.2+(C*25).sup.2)].sup.1/2,

X is 64 or more, and Y is 191 or more; and the measured value of graininess (HG value) is 45 or less,
with the proviso that C*15, C*25, C*45, and C*75 represent chroma calculated from spectral reflectances of light illuminated at an incident angle of 45 degrees with respect to the laminate and received at respective angles of 15 degrees, 25 degrees, 45 degrees, and 75 degrees deviated from the specular reflection light, and that L*15 and L*25 represent lightness calculated from spectral reflectances of light illuminated at an incident angle of 45 degrees with respect to the laminate and received at respective angles of 15 degrees and 25 degrees deviated from the specular reflection light.

A bilayer coating for thermal management has a bottom layer composed of aluminum microflakes dispersed in a Nitrile Butadiene Rubber-co-Urea (NBR-U) polymer binder, and a top layer composed of nanoparticle pigments in the NBR-U polymer binder. The top layer has a transmittance larger than 0.7 at IR wavelengths, and the bottom layer has an emissivity less than 0.4 and a reflectance larger than 0.6 in mid-IR wavelengths from 7 to 14 m.

The problem to be solved by the present invention is to provide an effect pigment dispersion that exhibits excellent water resistance, that can form metallic or pearly luster, and that further exhibits high stability; and to provide a method for forming a multilayer coating film. The present invention provides an effect pigment dispersion that contains water, a wetting agent (A), a flake-effect pigment (B), and a phosphate-group-containing cellulose-based rheology control agent (C). The effect pigment dispersion has a solids content of 0.1 to 10 parts by mass, per 100 parts by mass of all of the components of the effect pigment dispersion; and has a viscosity of 100 to 10000 mPa.Math.sec as measured with a Brookfield viscometer at a rotational speed of 6 revolutions per minute.

The problem to be solved by the present invention is to provide an effect pigment dispersion that exhibits excellent water resistance, that can form metallic or pearly luster, and that further exhibits high stability; and to provide a method for forming a multilayer coating film. The present invention provides an effect pigment dispersion that contains water, a wetting agent (A), a flake-effect pigment (B), and a phosphate-group-containing cellulose-based rheology control agent (C). The effect pigment dispersion has a solids content of 0.1 to 10 parts by mass, per 100 parts by mass of all of the components of the effect pigment dispersion; and has a viscosity of 100 to 10000 mPa.Math.sec as measured with a Brookfield viscometer at a rotational speed of 6 revolutions per minute.

FF properties of a multilayer coating film configured to exhibit a warm color through a lustrous layer (14) and a translucent colored layer (15) are improved to achieve a metallic textured color having a high-quality color tone. The lustrous layer (14) is configured such that Y(10) is 50 or more and 950 or less and that Y(25) is 0.05 or more and 0.35 or less times the Y(10), where Y(10) represents a Y value, of an XYZ color system, of reflected light measured at a light receiving angle of 10 and Y(25) represents a Y value of the reflected light measured at the light receiving angle of 25 in a case where a light incident angle is 45. A concentration C of a warm color pigment of the colored layer (15) is 1% by mass or more and 17% by mass or less.

A multilayer coating film includes a colored base layer 14 formed directly or indirectly on a surface of a coating target 11, and a luster material-containing layer 15 layered on the colored base layer 14 and containing flaked luster materials 22 and a colorant 23. With respect to the luster material-containing layer 15 in a state without the colorant, Y(10) of the XYZ color system is set to be 50 or more and 850 or less, and Y(20) is set to be equal to kY(10), where k is in a range of 0.2k0.6 and is determined according to the Y(10). The colorant concentration C of the luster material-containing layer is determined according to k. The surface reflectance R(%) of the colored base layer is determined according to the colorant concentration C of the luster material-containing layer and the Y(10).

A method for forming a multilayer coating film, comprising: (1) applying a yellow pigment-containing paint (X) to a substrate to form at least one layer of a yellow coating film; (2) applying an effect pigment dispersion (Y) to the yellow coating film to form an effect coating film; (3) applying a clear paint (Z) to the effect coating film to form a clear coating film; and (4) heating the yellow coating film, the effect coating film, and the clear coating film to separately or simultaneously cure the coating films, wherein the multilayer coating film has an h value of 60 to 120, the multilayer coating film has a Y5 value of 200 or more, and the multilayer coating film has a CS value of 90 or more, wherein the CS value is expressed by a specific equation.

Provided is a method for forming a multilayer coating film including the following steps (1) to (4): (1) applying a base paint (X) to a substrate to form a base coating film; (2) applying a specific effect pigment dispersion (Y) to the base coating film formed in step (1) to form an effect coating film with a specific dry film thickness; (3) applying a clear paint (Z) to the effect coating film formed in step (2) to form a clear coating film; and (4) heating the uncured base coating film, the uncured effect coating film, and the uncured clear coating film formed in steps (1) to (3) to simultaneously cure these three coating films.

FF properties of a multilayer coating film configured to exhibit a warm color through a lustrous layer (14) and a translucent colored layer (15) are improved to achieve a metallic textured color having a high-quality color tone. The lustrous layer (14) contains, in a mixed state, a high-reflection flake (21) having a visible light reflectance of 90 % or more and a low-reflection flake (22) having a visible light reflectance that is half (i.e., ) or smaller than the visible light reflectance of the high-reflection flake (21) as the luster material. When both of the high-reflection flake (21) and the low-reflection flake (22) are projected on a bottom of the lustrous layer (14), a ratio of a projected area of the flakes (21) and (22) on the bottom of the lustrous layer (14) is 100 %.