Compositions including a combination of (meth)acryloyl-terminated monomers and oligomers prepared by co-reacting reactants having active hydrogen groups with an acrylating agent are disclosed. Polymerizates formed using the combinations of (meth)acryloyl-terminated monomers and oligomers exhibit a high hardness, excellent thermomechanical properties, and a high refractive index. The compositions can be used to fabricate optical components.

Diffuser Elms may include a substrate and a plurality of diffusing particles uniformly distributed in the substrate. An absolute value of a difference between a refractive index of the diffusing particles and a refractive index of the substrate is less than or equal to 0.25, a diameter of the diffusing panicles ranges from 1 μm to 6 μm, and a weight percentage of the diffusing particles in the substrate ranges from 1‰ to 12‰, such that both a light transmittance and a haze of the diffuser film are greater than 80%.

The invention relates to a method for manufacturing an ophthalmic lens having at least one optical function, comprising the step of providing a starting optical system of the lens, having a basic optical function and the step of additively manufacturing an additional optical element of the lens, by deposition of multiple predetermined bulking components made of at least one material having a predetermined refractive index, directly onto the front surface and/or the rear surface of the starting optical system; wherein the additive manufacturing step comprises the step of determining a manufacturing guideline for the additional optical element on the basis of the characteristics of said at least one optical function to be provided to the lens, the characteristics of said at least one basic optical function, the geometric characteristics of the starting optical system, and the predetermined refractive index of the material.

A method of altering a refractive property of a crosslinked acrylic polymer material by irradiating the material with a high energy pulsed laser beam to change its refractive index. The method is used to alter the refractive property, and hence the optical power, of an implantable intraocular lens after implantation in the patient's eye. In some examples, the wavelength of the laser beam is in the far red and near IR range and the light is absorbed by the crosslinked acrylic polymer via two-photon absorption at high laser pulse energy. The method also includes designing laser beam scan patterns that compensate for effects of multiphone absorption such as a shift in the depth of the laser pulse absorption location, and compensate for effects caused by high laser pulse energy such as thermal lensing. The method can be used to form a Fresnel lens in the optical zone.

The invention relates to a method for manufacturing an ophthalmic lens having at least one optical function, comprising the step (200) of providing a starting optical system of the lens, having a basic optical function and the step (500) of additively manufacturing an additional optical element of the lens, by deposition of multiple predetermined bulking components made of at least one material having a predetermined refractive index, directly onto the front surface and/or the rear surface of the starting optical system; wherein the additive manufacturing step comprises the step of determining a manufacturing guideline for the additional optical element on the basis of the characteristics of said at least one optical function to be provided to the lens, the characteristics of said at least one basic optical function, the geometric characteristics of the starting optical system, and the predetermined refractive index of the material.

The present invention is related to a method and apparatus for the volumetric fabrication of three-dimensional objects or articles from photoresponsive materials loaded with scattering particles, by adjusting the refractive index of said photoresponsive material (12) so as to match the refractive index of said scattering particles (30), and/or using a light source emitting light of a wavelength longer than 630 nm, preferably in a range from 630 nm to 1050 nm, more preferably in a range from 650 nm to 900 nm.

An optically anisotropic polymer thin film includes a crystallizable polymer and an additive configured to interact with the polymer (e.g., via π-π interactions) to facilitate chain alignment and, in some examples, create a higher crystalline content within the polymer thin film. The polymer thin film may be characterized by a bimodal molecular weight distribution where the molecular weight of the additive may be less than approximately 50% of the molecular weight of the crystallizable polymer. Example crystallizable polymers include polyethylene naphthalate, polyethylene terephthalate, polybutylene naphthalate, polybutylene terephthalate, as well as derivatives thereof. Example additives, which may occupy up to approximately 10 wt. % of the polymer thin film, include aromatic ester oligomers, aromatic amide oligomers, and polycyclic aromatic hydrocarbons, for example. The optically anisotropic polymer thin film may be characterized by a refractive index greater than approximately 1.7 and an in-plane birefringence greater than approximately 0.2.

A method of altering a refractive property of a crosslinked acrylic polymer material by irradiating the material with a high energy pulsed laser beam to change its refractive index. The method is used to alter the refractive property, and hence the optical power, of an implantable intraocular lens after implantation in the patient's eye. In some examples, the wavelength of the laser beam is in the far red and near IR range and the light is absorbed by the crosslinked acrylic polymer via two-photon absorption at high laser pulse energy. The method also includes designing laser beam scan patterns that compensate for effects of multiphone absorption such as a shift in the depth of the laser pulse absorption location, and compensate for effects caused by high laser pulse energy such as thermal lensing. The method can be used to form a Fresnel lens in the optical zone.

A lens for directing light from an LED light source. The lens is formed by a plurality of layers and has a light-receiving inner-surface defining a pair of cavities. A portion of the inner-surface which defines one of the cavities is at least partially formed by an innermost layer of the plurality of layers. At least a portion of another of the plurality of layers extends inwardly between the pair of cavities. Another aspect of this invention is an optic member including a plurality of the lenses for directing light received from a plurality of spaced apart LED light sources.

An eye-mountable device is provided that includes a plurality of rigid polymer layers separated by liquid crystal layers. Certain eye-mountable devices includes a first rigid polymer layer, a second rigid polymer layer, and a liquid crystal layer between the first and second rigid polymer layers. The liquid crystal layer has a refractive index that is electrically controllable between an ordinary refractive index and an extraordinary refractive index, and the first rigid polymer layer and second rigid polymer layer include materials having a refractive index similar to the ordinary refractive index of the liquid crystal layer. The first rigid polymer layer and second rigid polymer layer may also include a combination of monomer-derived units that provide cast-moldable materials with high oxygen permeability. Methods for fabricating the eye-mountable device and for changing the focal length of the eye-mountable device are also provided.