Transparent, impact-resistant, anti-icing coatings are disclosed. In some variations, a transparent anti-icing coating comprises: a continuous matrix of a hardened material; asymmetric templates that inhibit wetting of water, wherein the asymmetric templates have a length scale from about 10-300 nanometers; porous voids surrounding the asymmetric templates, wherein the porous voids have a length scale from about 15-500 nanometers; and nanoparticles that inhibit heterogeneous nucleation of water, wherein the nanoparticles have an average size from about 5-50 nanometers. Disclosed coatings have transparencies of 90% or higher light transmission. These coatings utilize lightweight and environmentally benign materials that can be rapidly formed into coatings. A uniform distribution of particles and asymmetric templates throughout the coating allows it to be abraded, yet retain its anti-icing function as well as transparency. Therefore if the surface is damaged during use, freshly exposed surface is identical to that which was removed, for extended lifetime.

A low VOC aqueous coating composition capable of providing coating films with balanced properties of low gloss and good stain resistance.

The problem to be solved by the present invention is to provide an aqueous coating composition that can form a multilayer coating film having excellent storage stability, excellent adhesion to plastic base materials, excellent finish, and excellent coating film performance, such as water resistance; and to also provide a coating method using the composition. The present invention provides an aqueous coating composition comprising (A) an aqueous dispersion of a modified polyolefin, (B) an aqueous acrylic resin and/or an aqueous polyester resin, and (C) a phosphoric acid compound represented by a specific formula; and also provides a method for forming a coating film, comprising applying the aqueous coating composition, as well as an article coated with the aqueous coating composition.

Provided is a composition for forming a plating base on which plating is applied without a pretreatment, especially any activation process for the plating base, conventionally believed to be necessary, as well as a thus-formed plating base and a method of forming a plating coat over the plating base. The plating base is a coating film formed by applying and drying a metal nanoparticle dispersion liquid or a metal nanoparticle dispersion ink in which metal nanoparticles are protected with a small amount of protecting agent. Thus, a metal film can be formed by plating without operations such as substrate cleaning or catalyst imparting and activating. Since it is not necessary to wash the substrate with acid or base solution or to heat-treat it at a high temperature, many variations of materials become available for the substrate.

Water-based solvent-free and IR reflecting surface treatment composition comprising/consisting of the following compounds: a base comprising a. 30 to 60% by weight of an acrylic resin; b. 1 to 10% by weight of an alkyd resin; c. 0.1 to 2% by weight of a polyolefin; d. 0.1 to 1% by weight of an ammonium salt; e. Less than 0.1% by weight of a preservative; f. Water such that base reaches 100% by weight:
and a paste comprising i. metal oxides having a mean particle size between 0.05 and 5 μm ii. a polymeric binder

A dispersion comprised of at least 49 wt % of additive particles, a polymerizable monomer, a dispersant and a solvent. Upon polymerization the dispersion forms a hard coat with a haze of at most 0.5% and a transmission of at least 90%. A hard coat comprises at least 49 wt % of additive particles dispersed in a polymer. A method of making a hard coat comprises forming a dispersion, applying the dispersion to one side of a substrate, and polymerizing the dispersion. The hard coat has a haze of at most 0.5% and a transmission of at least 90%.

Disclosed herein is a silicone-modified polyimide resin composition of solvent free type. The composition is suitable for use as an adhesive and a coating material which are capable of hardening upon irradiation with ultraviolet rays and/or visible rays. Also, it is saved from drooling even in the case of light filling with an inorganic compound and it is saved from bubble entrapment and nonuniformity at the time of application with heavy filling. It further exhibits good moldability due to its thixotropic properties. Moreover, it exhibits improved adhesion to polyolefin resins without impairing the past properties. Finally, it gives rise to a cured product which is not excessively hard, with a low elastic modulus, despite filling with an inorganic compound. The composition of the present invention includes components (A) to (B) listed below and is characterized by being fluid at 25° C. and free of solvent: (A) silicone-modified polyimide resin; (B) polymerizable compound; (C) polymerization initiator, (D) hydrophobic fumed silica; and (E) adhesion auxiliary agent.

Anticorrosive coating compositions as disclosed comprise a binding polymer and an aluminum phosphate corrosion inhibiting pigment dispersed therein. The coating composition comprises up to 25 percent by weight aluminum phosphate. The binding polymer can include solvent-borne polymers, water-borne polymers, solventless polymers, and combinations thereof. The aluminum phosphate is made by sol gel process of combining an aluminum salt with phosphoric acid and a base material. Aluminum phosphate colloidal particles are nanometer sized, and aggregate to form substantially spherical particles. The coating composition provides a controlled delivery of phosphate anions of 100 to 1,500 ppm, depending on post-formation treatment of the aluminum phosphate, and has a total solubles content of less than 1500 ppm, The amorphous aluminum phosphate is free of alkali metals and alkaline earth metals, and has a water adsorption potential of up to about 25 percent by weight water when present in a cured film.

A composite structure disclosed includes a base (X) and a layer (Y). The layer (Y) includes a mixture of a metal oxide (A), a phosphorus compound (B), and a compound (L.sup.a) (silicon compound). Examples of the phosphorus compound (B) and the compound (L.sup.a) include a compound containing a site capable of reacting with the metal oxide (A). When the number of moles of metal atoms (M) derived from the metal oxide (A) is denoted by N.sub.M and the number of moles of Si atoms derived from the compound (L.sup.a) is denoted by N.sub.Si, 0.01≦N.sub.Si/N.sub.M≦0.30 is satisfied. When the number of moles of phosphorus atoms derived from the phosphorus compound (B) is denoted by N.sub.P, 0.8≦N.sub.M/N.sub.P≦4.5 is satisfied.

A metallic nanoparticle dispersion includes metallic nanoparticles and a compound according to Formula I, ##STR00001##
wherein X represents the necessary atoms to form a substituted or unsubstituted ring. The presence of small amounts of the compound according to Formula I increases the conductivity of metallic layers or patterns formed from the metallic nanoparticle dispersions at moderate curing conditions.