B01D53/48

Processes and systems for producing light olefins and aromatics from a mixed plastics stream
11760938 · 2023-09-19 · ·

Methods and systems for producing aromatics and light olefins from a mixed plastics stream are described. The method may include feeding a plastic feedstock to a dechlorination operation to melt the plastic feedstock to release HCl and generate a liquid plastic stream; feeding the liquid plastic stream to a pyrolysis reactor, the pyrolysis reactor to generate hydrocarbon vapors; feeding the hydrocarbon vapors to an acid gas removal reactor with a solid inorganic alkali salt disposed within the reaction vessel to remove residual HCl and sulfur-containing compounds from the hydrocarbon vapors to generate a plastic derived oil; and feeding the plastic derived oil to a fluid catalytic cracking reactor to generate a product stream comprising light olefins having a carbon number of C.sub.2-C.sub.4 and aromatics. The associated system for processing mixed plastics into aromatics and light olefins is also described.

Processes and systems for producing light olefins and aromatics from a mixed plastics stream
11760938 · 2023-09-19 · ·

Methods and systems for producing aromatics and light olefins from a mixed plastics stream are described. The method may include feeding a plastic feedstock to a dechlorination operation to melt the plastic feedstock to release HCl and generate a liquid plastic stream; feeding the liquid plastic stream to a pyrolysis reactor, the pyrolysis reactor to generate hydrocarbon vapors; feeding the hydrocarbon vapors to an acid gas removal reactor with a solid inorganic alkali salt disposed within the reaction vessel to remove residual HCl and sulfur-containing compounds from the hydrocarbon vapors to generate a plastic derived oil; and feeding the plastic derived oil to a fluid catalytic cracking reactor to generate a product stream comprising light olefins having a carbon number of C.sub.2-C.sub.4 and aromatics. The associated system for processing mixed plastics into aromatics and light olefins is also described.

Waste water evaporation methods and apparatus

A waste water processing system includes an upflow contacting column having a flue gas input for receiving flue gas having a temperature of at least 500 degrees F., a waste water input, and a flue gas output. The waste water input is coupled to a fluid injector, e.g., atomizing nozzles, positioned in the throat of a Venturi portion of the upflow contacting column or in a sidewall of the throat of the Venturi portion of the upflow contacting column. The flue gas in the upflow contacting column has a high velocity, e.g., a gas velocity exceeding 65 fps in the throat of the Venturi portion of the upflow contacting column at a position where the fluid injector is located. Drying additives such as recycled ash, lime, and/or cement may be, and sometimes are, input into the upflow contacting column downstream of the waste water input.

SYSTEM FOR THE CHEMICAL DECONTAMINATION OF CORROSIVE GASES

The use of a composition including at least one acido-basic neutralising agent for decontaminating an atmosphere contaminated by a corrosive gas, the acido-basic neutralising agent having at least 2 pKa's and being characterised by: pKa 1≤pKa 2, pKa 1>2, pKa 2<12, 4<½ (pKa 1+pKa 2)<10 pKa 1, representing the smallest of the basic pKa's and pKa 2 representing the largest of the acidic pKa's. Also, a method for decontaminating an atmosphere contaminated by a corrosive gas comprising the spraying of the neutralising agent, and to a decontamination device.

Installation for the production and a method of producing oil, gas and char for a coal black from elastomers, especially rubber waste, in the process of continuous pyrolysis

An installation for the production of oil, gas and char for carbon black, from elastomers, characterized in that, it has a screw dispenser (3) with a shaft (1), which from the loading side is closed hydraulically with a lock (2) by a nitrogen, a reactor (4), which is divided into zones A, B, C, corresponding to the subsequent stages of the pyrolysis process: zone A—the beginning of depolymerization (350° C.), zone B—carbonization (350-400° C.) and zone C—aromatic compounds cracking (400-650° C.), while a bubbler (5) hydraulically closed with a siphon (6) and a separator (7) with a hydraulic closure (8) and an oil separator (9) equipped with a transport screw (10) and an afterburner chamber (20) are installed outside the reactor (4), wherein the oil separator (9) is closed at the outlet by an accumulation shaft (12) and from the side of receiving a solid product—with a shaft (13), which is connected by an U-shaped screw conveyor (14) with economizers (11) and (15). wherein the installation is provided with a scrubber (16).

Installation for the production and a method of producing oil, gas and char for a coal black from elastomers, especially rubber waste, in the process of continuous pyrolysis

An installation for the production of oil, gas and char for carbon black, from elastomers, characterized in that, it has a screw dispenser (3) with a shaft (1), which from the loading side is closed hydraulically with a lock (2) by a nitrogen, a reactor (4), which is divided into zones A, B, C, corresponding to the subsequent stages of the pyrolysis process: zone A—the beginning of depolymerization (350° C.), zone B—carbonization (350-400° C.) and zone C—aromatic compounds cracking (400-650° C.), while a bubbler (5) hydraulically closed with a siphon (6) and a separator (7) with a hydraulic closure (8) and an oil separator (9) equipped with a transport screw (10) and an afterburner chamber (20) are installed outside the reactor (4), wherein the oil separator (9) is closed at the outlet by an accumulation shaft (12) and from the side of receiving a solid product—with a shaft (13), which is connected by an U-shaped screw conveyor (14) with economizers (11) and (15). wherein the installation is provided with a scrubber (16).

GAS-TREATING DEVICE

Provided is a gas-treating device including: an absorption device that receives an absorbent to absorb an acidic compound in a gas to be treated into the absorbent; a release device into which the absorbent having absorbed the acidic compound in the absorption device is introduced; a heater for heating the absorbent in the release device to release the acidic compound contained in the absorbent from the absorbent; and a multi-fluid heat exchanger for heating the absorbent before being supplied from the absorption device to the release device by a fluid containing the acidic compound discharged from the release device and the absorbent before being supplied from the release device to the absorption device.

PROCESSES AND SYSTEMS FOR PRODUCING LIGHT OLEFINS AND AROMATICS FROM A MIXED PLASTICS STREAM
20230365870 · 2023-11-16 · ·

Methods and systems for producing aromatics and light olefins from a mixed plastics stream are described. The method may include feeding a plastic feedstock to a dechlorination operation to melt the plastic feedstock to release HCl and generate a liquid plastic stream; feeding the liquid plastic stream to a pyrolysis reactor, the pyrolysis reactor to generate hydrocarbon vapors; feeding the hydrocarbon vapors to an acid gas removal reactor with a solid inorganic alkali salt disposed within the reaction vessel to remove residual HCl and sulfur-containing compounds from the hydrocarbon vapors to generate a plastic derived oil; and feeding the plastic derived oil to a fluid catalytic cracking reactor to generate a product stream comprising light olefins having a carbon number of C.sub.2-C.sub.4 and aromatics. The associated system for processing mixed plastics into aromatics and light olefins is also described.

PROCESSES AND SYSTEMS FOR PRODUCING LIGHT OLEFINS AND AROMATICS FROM A MIXED PLASTICS STREAM
20230365870 · 2023-11-16 · ·

Methods and systems for producing aromatics and light olefins from a mixed plastics stream are described. The method may include feeding a plastic feedstock to a dechlorination operation to melt the plastic feedstock to release HCl and generate a liquid plastic stream; feeding the liquid plastic stream to a pyrolysis reactor, the pyrolysis reactor to generate hydrocarbon vapors; feeding the hydrocarbon vapors to an acid gas removal reactor with a solid inorganic alkali salt disposed within the reaction vessel to remove residual HCl and sulfur-containing compounds from the hydrocarbon vapors to generate a plastic derived oil; and feeding the plastic derived oil to a fluid catalytic cracking reactor to generate a product stream comprising light olefins having a carbon number of C.sub.2-C.sub.4 and aromatics. The associated system for processing mixed plastics into aromatics and light olefins is also described.

Sulfur scavenging materials

Materials which react with (“scavenge”) sulfur compounds, such as hydrogen sulfide and mercaptans, are useful for limiting sulfur-induced corrosion. Surface-modified particles incorporating a hexahydrotriazine moiety are disclosed and used as sulfur scavengers. These surface-modified particles are used a filter media in fixed filter systems and as additives to fluids including sulfur compounds. The hexahydrotriazine moiety can react with sulfur compounds in such a manner as to bind sulfur atoms to the surface-modified particles, thus allowing removal of the sulfur atoms from fluids such as crude oil, natural gas, hydrocarbon combustion exhaust gases, sulfur polluted air and water. The surface-modified particles may, in general, be sized to allow separation of the particles from the process fluid by sedimentation, size-exclusion filtration or the like.