Methods for synthesizing macroscale 3D heteroatom-doped carbon nanotube materials (such as boron doped carbon nanotube materials) and compositions thereof. Macroscopic quantities of three-dimensionally networked heteroatom-doped carbon nanotube materials are directly grown using an aerosol-assisted chemical vapor deposition method. The porous heteroatom-doped carbon nanotube material is created by doping of heteroatoms (such as boron) in the nanotube lattice during growth, which influences the creation of elbow joints and branching of nanotubes leading to the three dimensional super-structure. The super-hydrophobic heteroatom-doped carbon nanotube sponge is strongly oleophilic and an soak up large quantities of organic solvents and oil. The trapped oil can be burnt off and the heteroatom-doped carbon nanotube material can be used repeatedly as an oil removal scaffold. Optionally, the heteroatom-doped carbon nanotubes in the heteroatom-doped carbon nanotube materials can be welded to form one or more macroscale 3D carbon nanotubes.

The invention provides an apparatus for polymer chromatography, comprising at least one column that comprises a first stationary phase comprising one of the following: A) a material comprising at least one non-carbon atom, excluding glass or a metal, selected from molybdenum sulfide MoS2, tungsten sulfide WS2, silicon carbide SiC, boron nitride BN, or combinations thereof, or B) glass, or a metal, or combinations thereof, and a material comprising at least one non-carbon atom selected from molybdenum sulfide MoS2, tungsten sulfide WS2, silicon carbide SiC, boron nitride BN, or combinations thereof. The invention also provides a method for polymer chromatography, comprising introducing a solution, comprising a polymer, into a liquid flowing through a first stationary phase, and wherein the first stationary phase comprises one of foregoing materials (A) or (B).

Related are a chemical warfare agent (CWA) decontaminant, a method of decontaminating a CWA using the CWA decontaminant, and a product including the CWA decontaminant. The CWA decontaminant may include a metal-organic framework (MOF) including at least one metallic compound among metal hydroxide, metal hydride, metal acetate, metal methoxide, and metal oxide, and the at least one metallic compound may be dispersed either on a surface of the MOF or in pores of the MOF, or both.

An exhaust gas purifying composition of the present invention contains zeolite that is BEA zeolite having an SiO.sub.2/Al.sub.2O.sub.3 molar ratio of greater than 25 and 600 or less and containing phosphorus. Furthermore, the exhaust gas purifying composition preferably contains zirconium in addition to phosphorus. Furthermore, the zeolite has an SiO.sub.2/Al.sub.2O.sub.3 molar ratio of from 30 to 150. The present invention provides an exhaust gas purifying composition having excellent HC adsorbability for exhaust gas purification in internal combustion engines such as gasoline engines.

A chemical filter includes a first buffer layer, at least one first filter layer disposed on the first buffer layer and including a pair of first air-permeable bodies facing each other and at least one first adsorption layer between the pair of first air-permeable bodies, and a second filter layer disposed on the first filter layer and including a pair of second air-permeable bodies facing each other and at least one second adsorption layer between the pair of second air-permeable bodies, wherein the first filter layer is configured to be attachable to and detachable from the second filter layer.

Graphite oxide, graphene oxide and/or graphene-containing composites for use in a filter assemblies and methods of making the same are described. Fluid treatment systems using a filter assembly having graphite oxide, graphene oxide and/or graphene-containing composites are also described. The filter assemblies and systems described herein can be used to purify contaminated fluids including water, aqueous solutions, a gas or mixture of gases, or any combination thereof. The graphite oxide, graphene oxide and/or graphene-containing composites can also have one or more of a zeolite, a boron nitride, a rare earth element, and an ionic salt incorporated therein for specific uses and desired properties.

The invention relates to a corrosion-resistant, reactive adsorbent which is made up of element iron on a carbon carrier plus sulfur and additional phosphorus as well as a method for producing this reactive adsorbent and use thereof for removal of reductively degradable pollutants in contaminated groundwater and wastewater.

A method for removing arsenic from a liquid includes adding a two-dimensional metal carbide adsorbent to the liquid to adsorb the arsenic from the liquid. The two-dimensional metal carbide adsorbent can include at least one MXene, having the formula M.sub.n+1X.sub.n, where n=1, 2 or 3, where M is an early transition metal, such as scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo) or the like, and X is either carbon or nitrogen. The MXene may be Ti.sub.3C.sub.2.

Metal-Organic Frameworks (MOFs) comprising an isoreticular series of MOFs based on face centered cubic (feu) topology. These MOFs can contain a rare earth metal (RE) located at the center and a ligand, for example, terephthalic acid or bipyridine and their extended forms. These MOFs can be combined with single walled carbon nanotubes (SWCNTs) to obtain a carbon nanotube (CNT)-metal organic framework (MOF) composite (CNT@MOF). This CNT@MOF is useful for, e.g., removing dyes from wastewater and can be tailored to meet the size of the dye to be removed.

Carbonaceous material that is activated to form precursor activated carbon is further enhanced by doping with iron and nitrogen and calcining. The resultant sorbent material has excellent catalytic properties which are useful in the field of fluid purification. The further enhancement can be performed in a single stage process or a dual stage process. The carbonaceous material includes those obtained from coal, wood, or coconut shells. The described treatment processes result in a sorbent material that has excellent performance in removing chloramine and similar compounds from fluids such as water that is intended for drinking.