A family of highly charged crystalline microporous metallophosphate molecular sieves designated PST-16 has been synthesized. These metallophosphates are represented by the empirical formula of:
R.sup.p+.sub.rA.sub.m.sup.+M.sub.xE.sub.yPO.sub.z
where A is an alkali metal such as potassium, R is an organoammonium cation such as ethyltrimethylammonium, M is a divalent metal such as zinc and E is a trivalent framework element such as aluminum or gallium. The PST-16 family of molecular sieves are stabilized by combinations of alkali and organoammonium cations, enabling unique metalloalumino(gallo)phosphate compositions and exhibit the CGS topology. The PST-17 family of molecular sieves has catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.

The disclosed pre-concentrator comprises: a base substrate having a trench; a metal layer conformally disposed along the inner surface of the trench; and a three-dimensional porous nanostructure disposed on the metal layer in the trench and having aligned pores connected to each other in three dimensions. The pre-concentrator can improve the concentration performance of a sample and the thermal desorption efficiency of a concentrated sample.

The invention relates to a monolithic porous material made of amorphous silica or activated alumina, comprising substantially rectilinear capillary channels that are parallel to one another, wherein: the channels have a substantially uniform cross-section relative to each other, the cross-section of each channel is regular over its entire length, the channels pass through the material from end to end, the length of the channels is equal to or more than 10 mm. The invention also relates to an annular, radial or axial chromatographic apparatus, the packing of which consists of at least one said monolithic material. The invention also relates to processes for manufacturing such a monolithic material.

Some embodiments are directed to a method for the preparation of defect-free nanosized synthetic zeolite materials, to the defect-free nanosized synthetic zeolite materials, to stable colloidal suspensions of the defect-free synthetic zeolite materials, and to the use of the defect-free nanosized synthetic zeolite materials and the stable colloidal suspensions in various applications.

Provided is a particulate water absorbent with which an absorbent body having an excellent speed of incorporating liquid and enabling reduction in release amount can be produced.

The particulate water absorbent contains poly(meth)acrylic acid (salt)-based water-absorbing resin particles as a main component, and the particulate water absorbent includes a cavity that is a space connecting to outside and a void that is a closed space not connecting to outside, in which a cavity ratio to a total volume is 10% by volume or more, and a void ratio to a total volume is 0.5% by volume or less.

The present invention provides a method for removing petroleum and other liquid hydrocarbons from a body of water, using an environmentally friendly and inexpensive bi-component granular compound with sorption and buoyant properties, wherein one of the components of the compound is a microporous absorbent material that due to its high sorption capacity, is effective in removing petroleum and other liquid hydrocarbons from the surface of a body of water, and another component is a macroporous buoyant material with closed cell structure, the subsequent extraction of the absorbent compound impregnated with petroleum and other liquid hydrocarbons from the body of water, with further hydrocarbon recovery by distillation, and microporous component re-activation, that are carried out inside a fluidized bed reactor, using superheated steam, a method of bi-component granular floating absorbent compound manufacturing.

The present disclosure is directed to absorbent articles with substrates or topsheets having repeating patterns of apertures comprising a plurality of repeat units. Each of the repeat units comprises at least three apertures.

The invention relates to a porous hydrogel matrix having substantially interconnected tunnel-shaped micropores with a three-dimensional configuration of an interconnected hollow tetrapod network. Such matrices may be used to entrap motile cells that migrate into the micropores of said matrix. The matrices of the invention are formed by a method comprising the steps of providing a solution of a hydrogel-forming material, providing a template material with a three-dimensional configuration corresponding to the negative configuration of the desired interconnected porous structure of the hydrogel material, said template material comprising interconnected zinc oxide tetrapod (t-ZnO) networks, casting the solution of hydrogel-forming material onto the template and removing the template material from the hydrogel material by acid hydrolysis of the template material.

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for their preparation and separations devices containing the chromatographic materials. The chromatographic materials of the invention have controlled porosity and comprise a chromatographic core material and one or more layers of chromatographic surface materials which each independently provide an average pore diameter, an average pore volume, or a specific surface area such that the combined layers form a chromatographic material having a predetermined or desired pattern of porosity from the core material to the outermost surface. The materials are useful for HPLC separations, normal-phase separations, reversed-phase separations, chiral separations, HILIC separations, SFC separations, affinity separations, perfusive separations, partially perfusive separations, and SEC separations.

A superabsorbent material generally free of organic solvents and having a high overall porosity and a high percentage of micropores are provided. The superabsorbent material is formed from a high-molecular weight linear water-soluble absorbent polymer and a non-reactive or latent crosslinking agent, and contains a plurality of micropores having a size of about 150 ?m or less. The superabsorbent material is formed into a variety of shapes having a high external surface to volume ratio.