Patent classifications
B01J27/224
Porous alpha-SiC-containing shaped body having a contiguous open pore structure
The present invention relates to a porous alpha-SiC-containing shaped body with a gas-permeable, open-pored pore structure comprising platelet-shaped crystallites which are connected to form an interconnected, continuous skeletal structure, wherein the skeletal structure consists of more than 80 wt.-% alpha-SiC, relative to the total weight of SiC, a process for producing same and its use as a filter component.
Porous alpha-SiC-containing shaped body having a contiguous open pore structure
The present invention relates to a porous alpha-SiC-containing shaped body with a gas-permeable, open-pored pore structure comprising platelet-shaped crystallites which are connected to form an interconnected, continuous skeletal structure, wherein the skeletal structure consists of more than 80 wt.-% alpha-SiC, relative to the total weight of SiC, a process for producing same and its use as a filter component.
PEROVSKITE CATALYSTS ENHANCED COMBUSTION ON POROUS MEDIA
The effects of different perovskite catalysts, catalytic active materials with a crystal structure of ABO.sub.3, on matrix stabilized combustion in a porous ceramic media are explored. Highly porous silicon carbide ceramics are used as a porous media for a catalytically enhanced matrix stabilized combustion of a lean mixture of methane and air. A stainless steel combustion chamber was designed incorporating a window for direct observation of the flame within the porous media. Perovskite catalytic enhancement of SiC porous matrix with La0.75Sr0.25Fe0.6Cr0.35Ru0.05O3; La0.75Sr0.25Fe0.6Cr0.4O3; La0.75Sr0.25Fe0.95Ru0.05O3; La0.75Sr0.25Cr0.95Ru0.05O3; and LaFe0.95Ru0.05O3, for example, were used to enhance combustion. The flammability limits of the combustion of methane and air were explored using both inert and catalytically enhanced surfaces of the porous ceramic media. By coating the SiC porous media with perovskite catalysts it was possible to lower the minimum stable equivalence ratio.
POROUS IRON-SILICATE WITH RADIALLY DEVELOPED BRANCH, AND IRON-CARBIDE/SILICA COMPOSITE CATALYST PREPARED THEREFROM
The present invention provides an iron-carbide/silica composite catalyst that is highly reactive to a Fischer-Tropsch synthesis by firstly forming an iron-silicate structure having large specific surface area and well-developed pores through a hydrothermal reaction of an iron salt with a silica particle having a nanostructure, and then activating the iron-silicate structure in a high temperature carbon monoxide atmosphere. When using the iron-carbide/silica composite catalyst according to the present invention in the Fischer-Tropsch synthesis reaction, it is possible to effectively prepare liquid hydrocarbon with a high CO conversion rate and selectivity.
Catalyst supports—composition and process of manufacture
A catalyst support comprising at least 95% silicon carbide, having surface areas of 10 m.sup.2/g and pore volumes of 1 cc/g. A method of producing a catalyst support, the method including mixing SiC particles of 0.1-20 microns, SiO.sub.2 and carbonaceous materials to form an extrusion, under inert atmospheres, heating the extrusion at temperatures of greater than 1400 C., and removing residual carbon from the heated support under temperatures below 1000 C. A catalyst on a carrier, comprising a carrier support having at least about 95% SiC, with a silver solution impregnated thereon comprising silver oxide, ethylenediamine, oxalic acid, monoethanolamine and cesium hydroxide. A process for oxidation reactions (e.g., for the production of ethylene oxide, or oxidation reactions using propane or methane), or for endothermic reactions (e.g., dehydrogenation of paraffins, of ethyl benzene, or cracking and hydrocracking hydrocarbons).
Catalyst supports—composition and process of manufacture
A catalyst support comprising at least 95% silicon carbide, having surface areas of 10 m.sup.2/g and pore volumes of 1 cc/g. A method of producing a catalyst support, the method including mixing SiC particles of 0.1-20 microns, SiO.sub.2 and carbonaceous materials to form an extrusion, under inert atmospheres, heating the extrusion at temperatures of greater than 1400 C., and removing residual carbon from the heated support under temperatures below 1000 C. A catalyst on a carrier, comprising a carrier support having at least about 95% SiC, with a silver solution impregnated thereon comprising silver oxide, ethylenediamine, oxalic acid, monoethanolamine and cesium hydroxide. A process for oxidation reactions (e.g., for the production of ethylene oxide, or oxidation reactions using propane or methane), or for endothermic reactions (e.g., dehydrogenation of paraffins, of ethyl benzene, or cracking and hydrocracking hydrocarbons).
Improved Catalyzed Soot Filter
A catalyzed soot filter, in particular for the treatment of Diesel engine exhaust, comprises a coating design which ensures soot particulates filtration, assists the oxidation of carbon monoxide (CO), and produces low H.sub.2S emissions during normal engine operations and regeneration events.
Improved Catalyzed Soot Filter
A catalyzed soot filter, in particular for the treatment of Diesel engine exhaust, comprises a coating design which ensures soot particulates filtration, assists the oxidation of carbon monoxide (CO), and produces low H.sub.2S emissions during normal engine operations and regeneration events.
Processes for producing trifluoroiodomethane and trifluoroacetyl iodide
The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25 C. to about 400 C. to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200 C. to about 600 C. to produce a final product stream comprising the trifluoroiodomethane.
Processes for producing trifluoroiodomethane and trifluoroacetyl iodide
The present disclosure provides a process for producing trifluoroiodomethane, the process comprising providing a reactant stream comprising hydrogen iodide and at least one trifluoroacetyl halide selected from the group consisting of trifluoroacetyl chloride, trifluoroacetyl fluoride, trifluoroacetyl bromide, and combinations thereof, reacting the reactant stream in the presence of a first catalyst at a first reaction temperature from about 25 C. to about 400 C. to produce an intermediate product stream comprising trifluoroacetyl iodide, and reacting the intermediate product stream in the presence of a second catalyst at a second reaction temperature from about 200 C. to about 600 C. to produce a final product stream comprising the trifluoroiodomethane.