An after treatment method for a lean-burn engine is disclosed. The after treatment method is configured to control an after treatment system sequentially equipped with an ammonia production catalyst module, a selective catalytic reduction (SCR) catalyst, and a CO clean-up catalyst (CUC) on an exhaust pipe through which an exhaust gas flows and which is connected to a lean-burn engine. NH.sub.3 generation in the ammonia production catalyst module is changed according to a temperature and a temperature change rate of the SCR catalyst.

Methods and systems are provided for a low temperature NOx adsorber (LTNA). In one example, a method includes operating in a first mode, the first mode including storing exhaust NOx in an LTNA, heating the LTNA until an LTNA outlet temperature reaches a first threshold temperature, and then converting released NOx in a downstream selective catalyst reduction (SCR) device; and operating in a second mode, the second mode including heating the LTNA until the LTNA outlet temperature reaches a second threshold temperature, higher than the first threshold temperature, and converting exhaust NOx in the SCR device.

An after treatment method for a lean-burn engine is disclosed. The after treatment method is configured to control an after treatment system sequentially equipped with an ammonia production catalyst module, a selective catalytic reduction (SCR) catalyst, and a CO clean-up catalyst (CUC) on an exhaust pipe through which an exhaust gas flows and which is connected to a lean-burn engine. NH.sub.3 generation in the ammonia production catalyst module is changed according to a temperature and a temperature change rate of the SCR catalyst.

An after treatment method for a lean-burn engine is disclosed. The after treatment method is configured to control an after treatment system sequentially equipped with an ammonia production catalyst module, a selective catalytic reduction (SCR) catalyst, and a CO clean-up catalyst (CUC) on an exhaust pipe through which an exhaust gas flows and which is connected to a lean-burn engine. In the after treatment method, a rich air/fuel ratio (AFR) is controlled in multiple phases in response to detecting that conversion to the rich AFR is desired.

The present invention is directed to selective catalytic reduction catalysts that combine SCR activity with NOx absorber activity. In particular, the disclosed catalytic article includes a substrate having a first and a second material disposed thereon, wherein the first material includes a selective catalytic reduction (SCR) catalyst composition and the second material includes a nitrogen oxides (NOx) absorber composition, wherein the NOx absorber composition does not substantially oxidize ammonia, and wherein the catalytic article is effective to abate NOx from an engine exhaust gas stream. Emission treatment systems for treating an exhaust gas including a catalytic article of the invention are provided, particularly systems that include an injector adapted for the addition of ammonia to the exhaust gas stream located upstream of the catalytic article.

The present invention relates to a catalyst comprising a carrier substrate of the length L, a passive nitrogen oxide adsorber and means to control the temperature of the carrier substrate, as well as a process for cleaning of an exhaust gas emitted from a lean burn engine.

An after treatment method for a lean-burn engine is disclosed. The after treatment method is configured to control an after treatment system sequentially equipped with an ammonia production catalyst module, a selective catalytic reduction catalyst, and a CO clean-up catalyst on an exhaust pipe through which an exhaust gas flows. In the after treatment method, the engine is operated sequentially at a stoichiometric air/fuel ratio (AFR) and a lean AFR prior to entering a rich AFR.

A catalysed substrate monolith 12 for use in treating exhaust gas emitted from a lean-burn internal combustion engine, which catalysed substrate monolith 12 comprising a first washcoat coating 16 and a second washcoat coating 18, wherein the first washcoat coating comprises a catalyst composition comprising at least one platinum group metal (PGM) and at least one support material for the at least one PGM, wherein at least one PGM in the first washcoat coating is liable to volatilise when the first washcoat coating is exposed to relatively extreme conditions including relatively high temperatures, wherein the second washcoat coating comprises at least one metal oxide for trapping volatilised PGM and wherein the second washcoat coating is oriented to contact exhaust gas that has contacted the first washcoat coating.

An exhaust gas purification apparatus for an internal combustion engine includes the adsorbent, the catalyst and the heat generating element, wherein in cases where the residual capacity of the battery is smaller than a first predetermined value required for raising the temperature of the catalyst to an activation temperature thereof, and in cases where the residual capacity of the battery is larger than a second predetermined value which is smaller than the first predetermined value and which is required for raising the temperature of the adsorbent to a predetermined temperature at which the adsorbent exhibits adsorption performance required at the time of starting of the internal combustion engine, an amount of electric power to be supplied to the heat generating element from the battery is adjusted such that the temperature of the adsorbent becomes the predetermined temperature.

An exhaust after-treatment system includes a first set of exhaust after-treatment components, a second set of exhaust after-treatment components, an inlet to the exhaust after-treatment system, an outlet from the exhaust after-treatment system, and a valve and conduit arrangement configurable in a plurality of modes, in a first mode, exhaust gas entering the inlet flows through the second set of exhaust after-treatment components, then through the first set of exhaust after-treatment components, and then through the outlet. In a second mode, exhaust gas entering the inlet flows through the second set of exhaust after-treatment components without flowing through the first set of exhaust after-treatment components, and then through the outlet in a third mode, exhaust gas entering the inlet flows through the first set of exhaust after-treatment components, then through the second set of exhaust after-treatment components, and then through the outlet.