A method for preparing a sorbent precursor, which may be sulphided and used to remove heavy metals such as mercury from fluid streams, includes the steps of: (i) mixing together an inert particulate support material and one or more binders to form a support mixture, (ii) shaping the support mixture by granulation in a granulator to form agglomerates, (iii) coating the agglomerates with a coating mixture powder including a particulate copper compound and one or more binders to form a coated agglomerate, and (iv) drying the coated agglomerate to form a dried sorbent precursor.

A system that uses single or multiple elements arranged in a single unit or multiple arrays for the extraction, purification, and concentration of lithium and other constituents from a brine that can be constructed in a mobile unit.

A short channel ordered mesoporous carbon loaded indium cobalt sulfide and indium nickel sulfide ternary composite photocatalyst, and a preparation method and application thereof. The short channel ordered mesoporous carbon loaded indium cobalt sulfide and indium nickel sulfide ternary composite photocatalyst is prepared by mixing pretreated short channel mesoporous carbon with cobalt salt, nickel salt, indium salt and reducing agent with a hydrothermal reaction. The short channel ordered mesoporous carbon is obtained by calcining a short channel ordered mesoporous silica and a carbon source under the protection of nitrogen, wherein the short channel ordered mesoporous silica is prepared by carrying out reactions of sol-gel-hydrothermal-calcination sequentially using a mixture of a surfactant, a hydrochloric acid solution, ammonium fluoride and tetraethyl orthosilicate. The photocatalyst has strong adsorption and visible light catalytic activity on VOCs, and can effectively adsorb and decompose the enriched VOCs in situ on the surface of the catalyst.

Disclosed are systems and methods for processing liquefied natural gas (LNG). A LNG production system may include a contaminant removal process with one or more sets of sorbent beds co-loaded with a metal sulfide sorbent and/or metal oxide sorbent. In some examples, the contaminant removal process may include one or more molecular sieve dehydrators co-loaded with a 3A or 4A sieve and a 3A or 4A sieve impregnated with silver. The one or more sets of sorbent beds may be arranged at various locations throughout the LNG production system including upstream of or downstream of heavy component removal beds having activated carbon. In some instances, the LNG production system may include a regeneration process for moving heated fluid, typically feed gas, through a first heavy component removal bed while maintaining other heavy component removal beds online to reduce downtime for the LNG production system, increase production efficiency, and decrease an amount of greenhouse gases released from defrost and flare-offs.

Methods of sulfurizing metal containing particles in the absence of hydrogen are described. One method includes contacting a bed of metal containing particles with a gaseous stream comprising hydrogen sulfide and inert gas under reaction conditions sufficient to produce sulfided metal containing particles. The gaseous stream is introduced into a vertical reactor at an inlet positioned at the bottom portion of the reactor and any unreacted hydrogen sulfide and inert gas is removed at an outlet positioned above the inlet. The sulfided metal containing particles can be removed from the reactor and stored.

The invention provides an apparatus for polymer chromatography, comprising at least one column that comprises a first stationary phase comprising one of the following: A) a material comprising at least one non-carbon atom, excluding glass or a metal, selected from molybdenum sulfide MoS2, tungsten sulfide WS2, silicon carbide SiC, boron nitride BN, or combinations thereof, or B) glass, or a metal, or combinations thereof, and a material comprising at least one non-carbon atom selected from molybdenum sulfide MoS2, tungsten sulfide WS2, silicon carbide SiC, boron nitride BN, or combinations thereof. The invention also provides a method for polymer chromatography, comprising introducing a solution, comprising a polymer, into a liquid flowing through a first stationary phase, and wherein the first stationary phase comprises one of foregoing materials (A) or (B).

A method is described for preparing a sorbent comprising the steps of: (i) mixing together an inert particulate support material and one or more binders to form a support mixture, (ii) shaping the support mixture by granulation in a granulator to form agglomerates, (iii) coating the agglomerates with a coating mixture powder comprising a particulate copper sulphide and one or more binders to form a coated agglomerate, and (iv) drying the coated agglomerate to form a dried sorbent.

Ion separation media are described herein employing thermoelectric materials and architectures. In some embodiments, an ion separation medium comprises a layer of inorganic nanoparticles having a Seebeck coefficient sufficient to transport ionic species in a liquid medium along surfaces of the layer in the presence of a thermal gradient.

In some embodiments, the present disclosure pertains to methods of removing heteroatoms from a fluid by associating the fluid with one or more adsorbents, where the association results in the removal of the heteroatoms from the fluid. The association may occur by associating the fluid with a single adsorbent or a plurality of adsorbents in a sequential manner that maximizes heteroatom removal efficacy. The methods may be utilized to remove heteroatom-containing compounds from various fluids, such as fuels, hydrocarbons, alcohols, water, organic solvents, and combinations thereof. The one or more adsorbents may include, without limitation, activated carbon, zeolites, ion exchanged zeolites, ion impregnated zeolites, alumina, alumina nanowires, carbon-based supports, and combinations thereof. The methods of the present disclosure can be utilized to reduce heteroatoms in the fluid by more than about 50%, by more than about 80%, or by more than about 99%.

An emissions control system including a fluidized bed apparatus containing a reactive sorbent material is disclosed for gaseous and non-gaseous contaminated emissions. The reactive sorbent material may be CZTS, CZTS-Alloy, or a carbon-based sorbent material. The fluidized bed apparatus is configured with one or more closed loop sorbent recycling subsystems. The sorbent recycling subsystems include the capability to separate sorbents from each other, separate contaminates from sorbents for disposal and/or recycling, clean and/or rejuvenate sorbents for return to the fluidized bed apparatus, dispose of spent and exhausted sorbents, and replace the spent and exhausted sorbents with new sorbent to maintain consistent sorbent function in the fluidized bed apparatus. Monitoring sensors provide information useful in a method for establishing and maintaining consistent process parameter controls.