This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has been modified by substituting some of the BTC ligand (1,3,5, benzene tricarboxylic acid) with 5-aminoisophthalic acid (AIA). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60 C. for 6 hours. This is an unexpected result versus the MOF containing only the BTC ligand. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams.

This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has open coordination sites and has been post synthesis modified by partially occupying the open sites with a ligand such as acetonitrile (CH.sub.3CN). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60 C. for 6 hours. This is an unexpected result versus the MOF which has not been post treated with ligands such as acetonitrile. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams.

Three dimensional (3D), porous, Sr(II)/Ir(III) layered double hydroxide materials with a spherical/balls like shape, are composed of nanohexagonal sheets intercalated with 1-(1-hydroxy-4-methyl-2-phenylazo)-2-naphthol-4-sulfonic acid have a number of uses including removing undesirable organic compounds and materials from polluted water. This removal can be accomplished without disturbing the pH of the water, and with high absorption capacity (2000 mg of pollutants/1 mg of LDH). The spherical/ball like materials are easily cleaned and are amenable to being reused several times.

The present invention provides mixed metal oxide-hydroxide biopolymer composite beads for fluoride removal from groundwater and a process for the preparation thereof. The beads developed in the instant invention relate to novel granular adsorption medium which comprises two or more metal oxide-hydroxide/hydroxide/oxide nanoparticles and calcium alginate as supporting medium. The said mixed metal oxide-hydroxides and biopolymer composite (MBC) beads are useful for the treatment of fluoride containing drinking water by both batch and continuous mode operations. The MBC beads also showed arsenic sorption performance from spiked water by batch mode.

An oil absorbent product and a method of removing oil contaminants from a water flow are disclosed, in which the product according to the invention is placed in a filter composition and the saturated product can be regenerated for further use. Uses of the method and the product for the removal of oil contamination from water and for the absorption of oil spills, are also mentioned.

The disclosed subject matter relates to a reactive matrix for the sorption/desorption of a heat transfer fluid (FG) in a reactor of a cold production device, this matrix comprising a compacted mixture of sorbent, of the manganese chloride monohydrate type, and expanded natural graphite in a preferred proportion of 79/21. The disclosed subject matter also relates to a method for manufacturing a wafer from this matrix and a reactor comprising a stack of such wafers.

The disclosed subject matter relates to a reactive matrix for the sorption/desorption of a heat transfer fluid (FG) in a reactor of a cold production device, this matrix comprising a compacted mixture of sorbent, of the manganese chloride monohydrate type, and expanded natural graphite in a preferred proportion of 79/21. The disclosed subject matter also relates to a method for manufacturing a wafer from this matrix and a reactor comprising a stack of such wafers.

The invention relates to a superior core-in-shell adsorbent comprising adsorbent, and an inert core, wherein said core possesses a porosity less than 10%, and has a volumetric thermal capacity greater than 1 J/K*cc. The adsorbents of the invention possess good physical strength, and allow a longer cycle time, thereby reducing the blowdown (vent) losses compared to known adsorbents.

The invention relates to an adsorber design for a vacuum/pressure swing adsorption (VSA, VPSA, PSA) process designed to obtain oxygen product from air utilizing the adsorbents of the invention.

The invention relates generally to sorbents and sorption devices for extracting compounds. The invention relates to a sorbent comprising a polymer and microdiamond. The invention also relates to a sorption device comprising the sorbent. The invention further relates to methods of using the sorption device for extracting organic compounds from a fluid and for preparing a sample containing organic compounds for analysis.

Disclosed is a method for preparing an acid-resistant Zr-metal-organic framework (Zr-MOF) material with selective adsorption of hexavalent chromium, which is specifically a method for preparing a MOF material with selective adsorption of hexavalent chromium. The present invention aims to solve the technical problems that the existing MOFs have poor water stability, is unstable in an aqueous solution, and therefore may structurally collapse. In addition, the micropore characteristics of most MOFs have affected the mass transfer rate of the adsorbate, which in turn limits the industrial application thereof. The MOF of the present invention has excellent water stability and acid resistance, showing a strong adaptability and great potential in treating mostly acidic industrial wastewater. As a new functional material for water treatment, the MOF has optimal selective adsorption capacity and a desirable adsorption capacity for hexavalent chromium in water, which improves the recycling and later resource utilization.