One aspect of the present invention relates to a carbonaceous material that has a benzene adsorption amount of 30 to 60%, a vitamin B12 adsorption amount of more than 50.0 mg/g, and a micropore volume of mesopores of 0.13 to 0.30 cm.sup.3/g as calculated from a nitrogen adsorption isotherm by a BJH method.

An object is to provide an adsorbing material using activated carbon fiber, suitable for motor vehicle canisters, and enabling reduction in pressure loss. Another object is to provide a formed adsorber using activated carbon fiber, with improved mechanical strength, and having excellent effects of an adsorbing material for canisters. The formed adsorber for canisters satisfies the following conditions (1) to (3). (1) The formed adsorber includes: an adsorbing material including activated carbon fiber; and a binder. (2) A ratio of a content of the binder to a content of the adsorbing material including the activated carbon fiber is 0.3 to 20 parts by weight of the binder to 100 parts by weight of the adsorbing material including the activated carbon fiber. (3) The activated carbon fiber has a fiber size of 13.0 μm or larger.

An object is to provide a new form of formed adsorbers suitable for high performance canisters.

A formed adsorber for a canister is to satisfy the following conditions.

The formed adsorber satisfies a condition where P.sub.0.2/100 expressed by Equation 1:

P.sub.0.2/100=X÷Y×100  (Equation 1)

is 120% or less.

In Equation 1 above, X represents an amount of n-butane gas adsorbed per 100 parts by weight of the adsorbing material at 25° C. under an atmosphere where a gas pressure of n-butane gas is 0.2 kPa, and Y represents an amount of n-butane gas adsorbed per 100 parts by weight of the adsorbing material at 25° C. under an atmosphere where a gas pressure of n-butane gas is 100 kPa.

In one aspect, the present invention provides a chromatographic stationary phase material for various different modes of chromatography represented by Formula 1: [X](W).sub.a(Q).sub.b(T).sub.c (Formula 1). X can be a high purity chromatographic core composition having a surface comprising a silica core material, metal oxide core material, an inorganic-organic hybrid material or a group of block copolymers thereof. W can be absent and/or can include hydrogen and/or can include a hydroxyl on the surface of X. Q can be a functional group that minimizes retention variation over time (drift) under chromatographic conditions utilizing low water concentrations. T can include one or more hydrophilic, polar, ionizable, and/or charged functional groups that chromatographically interact with the analyte. Additionally, b and c can be positive numbers, with the ratio 0.05≤(b/c)≤100, and a≥0.

An X-ray amorphous magnesium carbonate is disclosed that is characterized by a cumulative pore volume of pores with a diameter smaller than 10 nm of at least 0.018 cm.sup.3/g, and a specific surface areas of at least 60 m.sup.2/g. The X-ray amorphous magnesium carbonate is produced by reacting an inorganic magnesium compound with alcohol in a CO.sub.2 atmosphere. The X-ray amorphous magnesium carbonate can be a powder or a pellet and acts as a desiccant in, for example, production of food, chemicals or pharmaceuticals.

A product includes a highly adsorptive structure comprising: a substrate, wherein the substrate comprises a plurality of microchannels; and a carbon aerogel adhered to the substrate. The carbon aerogel is characterized by having physical characteristics of in situ formation on the substrate. Moreover, An adsorptive cooling system includes: a first highly adsorptive structure positioned to receive thermal energy from a thermal energy source, the first highly adsorptive structure comprising: a first substrate; and a first carbon aerogel adhered to the first substrate; a second highly adsorptive structure positioned to receive thermal energy from the thermal energy source, the second highly adsorptive structure comprising: a second substrate; and a second carbon aerogel adhered to the second substrate. The first substrate and/or the second substrate independently comprise a plurality of microchannels.

The invention is directed to a nanostructured composite material comprising a mixture of at least one metal particle such as iron and a carbon material from biomass such as D-glucose, D-glucosamine hydrochloride or a-cyclodextrin. The invention is also directed to a composition comprising the composite material comprising the composite material and an inorganic salt, and a method for synthesizing the composite material comprising immersing the carbon material into a solution of metal ions, drying the impregnated carbon particle and subjecting the impregnated carbon particle to a carbothermal reduction process. The nanostructured composite material is useful as an oxygen scavenging layer in a multi-layer film which comprises the oxygen scavenging layer and an oxygen barrier layer that retards the permeation of oxygen from an external environment.

This disclosure provides a sensor for detecting an analyte. The sensor can include an antenna and sensing material both disposed on a substrate, where the sensing is electrically coupled to the antenna. The sensing material can include a carbon structure including a multi-modal distribution of pore sizes that define a surface area including bonding sites configured to interact with one or more additives and the analyte. The carbon structure is configured to generate a resonant signal indicative of one or more characteristics of the analyte in response to an electromagnetic signal. The carbon structure can include distinctly sized interconnected channels defined by the surface area and configured to be infiltrated by the analyte, and exposed surfaces configured to adsorb the analyte. Each of the interconnected channels can include microporous pathways and/or mesoporous pathways, which can increase a responsiveness of the sensing material proportionate to the analyte within the carbon structure.

A highly adsorptive structure includes: a substrate; and a metal-organic framework (MOF) comprising a plurality of metal atoms coordinated to a plurality of organic spacer molecules; wherein the MOF is coupled to at least one surface of the substrate, wherein the MOF is configured to adsorb and desorb a refrigerant under predetermined thermodynamic conditions. The refrigerant includes one or more materials selected from the group consisting of: acid halides, alcohols, aldehydes, amines, chlorofluorocarbons, esters, ethers, fluorocarbons, perfluorocarbons, halocarbons, halogenated aldehydes, halogenated amines, halogenated hydrocarbons, halomethanes, hydrocarbons, hydrochlorofluorocarbons, hydrofluoroethers, hydrofluoroolefins, inorganic gases, ketones, nitrocarbon compounds, noble gases, organochlorine compounds, organofluorine compounds, organophosphorous compounds, organosilicon compounds, oxide gases, refrigerant blends and thiols.

This invention relates to a continuous process for the preparation of a metal-organic framework comprising a hydrophobic compound. The process comprises the steps of: (a) providing a first component comprising either (i) a metal-organic framework, or (ii) a first reactant which includes at least one metal in ionic form and a second reactant which includes at least one ligand capable of associating with the metal in ionic form in order to form a metal-organic framework, (b) providing a hydrophobic compound, and (c) mixing the first component and the hydrophobic compound in order to form the metal-organic framework comprising the hydrophobic compound. The invention also relates to the use of a hydrophobic polymer, a silane compound and/or a siloxane compound to improve the water stability of a metal-organic framework.