The present invention relates yolk-shell nanoparticles having both a high stability towards sintering and high H.sub.25 adsorption capacities, the use of the yolk-shell nanoparticles in a method for H.sub.2S removal from gas streams, and a corresponding method for H.sub.2S removal from gas streams also comprising the regeneration of the yolk-shell nanoparticles, wherein the yolk-shell nanoparticles provide for high H.sub.2 adsorption capacities and/or high reusability.

In some aspects, the present disclosure pertains to chromatographic materials that comprise (a) a bulk material and (b) a zwitterionic polymer covalently linked to a surface of the bulk material, in which the zwitterionic polymer comprises one or more monomer residues that comprise an amide or urea moiety, a positively charged moiety, and a negatively charged moiety. Other aspects of the present disclosure pertain to chromatographic separation devices that comprise such chromatographic materials, to chromatographic methods that employ such chromatographic separation devices, and to kits that contain (i) such chromatographic materials and (ii) one or more chromatographic devices for containing such materials.

The invention relates to the intensification of hydrogen PSA processes through utilization of specifically engineered core-shell composite adsorbents. Different embodiments of core-shell adsorbents can be used with either high or low heat capacity cores, and different adsorbent shells (e.g. activated carbon, zeolite, silica gel, alumina etc.) resulting in higher mass transfer rates and hence sharper mass transfer fronts during the PSA process. The location of the limiting impurity front determines the product purity. Therefore, with sharper impurity fronts, lower height of adsorbent bed is required, and cycle time can be proportionally reduced. Also, thermal swing during the PSA can be reduced by use of such adsorbents. The use of a high heat capacity core to reduce the thermal swing, leads to higher overall working capacity of the adsorbent bed.

In various embodiments, the present disclosure pertains to core-shell particles that comprise a porous hybrid organic-inorganic shell disposed on a surface-modified non-porous polymer particle core. In some embodiments, the present disclosure pertains to chromatographic separation devices that comprise such core-shell particles. In some embodiments, the present disclosure pertains to chromatographic methods that comprise: (a) loading a sample onto a chromatographic column comprising such core-shell particles and (b) flowing a mobile phase through the column.

The present disclosure relates to water-absorbent resin particles in which a contact angle of 0.9% by mass saline at 25° C.±2° C. is 100 degrees or larger, and an absorbent material containing the water-absorbent resin particles.

The invention relates to a method to produce a particulate activated carbon material for capturing CO.sub.2 from air, wherein the particulate activated carbon is impregnated with alkali carbonate salt such as K.sub.2CO.sub.3; and wherein the impregnated particulate activated carbon either has, determined using nitrogen adsorption methods, a pore volume of at least 0.10 cm.sup.3/g for pore sizes of at least 5 nm and a pore volume of at most 0.30 cm.sup.3/g for pore sizes of less than 2 nm or is based on a mixture of different alkali carbonate salts, or has a particular pore surface for pore sizes in the range of 2 nm-50 nm.

The present disclosure belongs to the technical field of analytical chemistry, in particular to synthesis and application of a nanomaterial for removal of patulin (Pat). The present disclosure adopts 2-Oxin as a substitute template, AM as a functional monomer, and synthetic Fe.sub.3O4@SiO.sub.2@CS-GO magnetic nanoparticles as a carrier, for preparing a magnetic MIP specific for Pat adsorption by surface imprinting. The addition of Fe.sub.3O.sub.4 makes the finally prepared molecular imprinted adsorbent material magnetic, thereby facilitating separation of a material from a matrix, eliminating complicated operation steps such as filtration and centrifugation, and facilitating recovery of materials.

The methods of the invention employ targeted magnetic particles, preferably targeted nanomagnetic particles, and targeted buoyant particles such as buoyant microparticles and microbubbles. Among the benefits of the invention is the ability to combine targeted magnetic particles with differentially targeted buoyant particles to achieve separation of two or more specifically cell targeted populations during the same work flow.

The present invention provides novel chromatographic materials, e.g., for chromatographic separations, processes for its preparation and separations devices containing the chromatographic material; separations devices, chromatographic columns and kits comprising the same; and methods for the preparation thereof. The chromatographic materials of the invention are chromatographic materials comprising having a narrow particle size distribution.

Spike particles are disclosed including a core and a plurality of spikes attached to and extending from a core surface. The core may be nonporous, superficially porous, or porous. The plurality of spikes may be nonporous or superficially porous. Superficially porous spike particles are disclosed including a porous spike particle shell disposed over a nonporous spike particle. A method for forming the spike particles is disclosed including mixing a dispersed aqueous phase having a plurality of core particles, a water emulsion drop stabilizer, and a catalyst with a continuous oil phase having an organic solvent, polyvinylpyrrolidone, and a silane precursor to form a water-in-oil emulsion system, which is reacted without stirring to form the plurality of chromatographic spike particles. A chromatographic separation device is disclosed including the spike particles, which are randomly packed in the chromatographic separation device and have an external porosity ranging from about 0.4 to about 0.9.