Patent classifications
B01J29/78
Catalysts and process for liquid hydrocarbon fuel production
The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.
Catalysts and process for liquid hydrocarbon fuel production
The present invention provides a novel process and system in which a mixture of carbon monoxide and hydrogen synthesis gas, or syngas, is converted into hydrocarbon mixtures composed of high quality gasoline components, aromatic compounds, and lower molecular weight gaseous olefins in one reactor or step. The invention utilizes a novel molybdenum-zeolite catalyst in high pressure hydrogen for conversion, as well as a novel rhenium-zeolite catalyst in place of the molybdenum-zeolite catalyst, and provides for use of the novel catalysts in the process and system of the invention.
Molecular sieves and a process for making molecular sieves
Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.
Molecular sieves and a process for making molecular sieves
Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.
Catalyst for Producing C8 Aromatic Hydrocarbon Having Reduced Ethylbenzene Content and Preparation Method Therefor
Disclosed are a catalyst and a preparation method therefor, the catalyst being able to maintain a high production yield of C8 aromatic hydrocarbons in the process of converting a feedstock containing alkyl aromatics to C8 aromatic hydrocarbons such as mixed xylene through disproportionation/transalkylation/dealkylation while reducing a content of ethylbenzene in the products.
Molecular sieve intergrowths of cha and aft having an “<i>sfw</i>-GME tail,” methods of preparation and use
Molecular sieves comprising intergrowths of cha and aft having an “sfw-GME tail”, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-“sfw-GME tail”. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.
Molecular sieve intergrowths of cha and aft having an “<i>sfw</i>-GME tail,” methods of preparation and use
Molecular sieves comprising intergrowths of cha and aft having an “sfw-GME tail”, at least one structure directing agent (SDA) within the framework of the molecular sieve, an intergrowth of CHA and GME framework structures, cha cavities, and aft cavities are described. A first SDA comprising either an N,N-dimethyl-3,5-dimethylpiperidinium cation or a N,N-diethyl-2,6-dimethylpiperidinium cation is required. A second SDA, which can further be present, is a CHA or an SFW generating cation. The amount of the second SDA-2 used can change the proportion of the components in the cha-aft-“sfw-GME tail”. Activated molecular sieves formed from SDA containing molecular sieves are also described. Compositions for preparing these molecular sieves are described. Methods of preparing a SDA containing JMZ-11, an activated JMZ-11, and metal containing activated JMZ-11 are described. Methods of using activated JMZ-11 and metal containing activated JMZ-11 in a variety of processes, such as treating exhaust gases and converting methanol to olefins are described.
Nano-sized zeolite catalyst having a high silica to alumina ratio
A catalyst includes a zeolite, wherein the zeolite has: a CHA framework; a particle size less than or equal to 100 nanometers; and a silica to alumina mole ratio in the range of about 50:1 to about 150:1. The catalyst can include a metal dopant. The catalyst can be used for purifying a product by flowing a reactant across the catalyst to form the product; and condensing or separating the product. The product can be an olefin or alkenes with an increased carbon chain. The catalyst can be used for selective catalytic reduction of nitrogen oxide or a gas to liquid reaction. A method of producing the catalyst can include selecting the concentration of a crystal growth inhibitor based on the ratio of the silica precursor and an alumina precursor such that the zeolite crystals have a mean particle size less than or equal to 100 nanometers.
PROCESS FOR DEPARAFFINNING A MIDDLE DISTILLATE FEEDSTOCK USING A CATALYST BASED ON IZM-2 ZEOLITE AND AN MFI-TYPE ZEOLITE
The present invention relates to a process for deparaffinning a middle distillate feedstock, to convert, in good yield, feedstocks having high pour points into at least one cut having an improved pour point.
Said process is performed with at least one catalyst comprising at least one hydro-dehydrogenating phase containing at least one metal from group VIB and at least one metal from group VIII of the Periodic Table of the Elements, and a support comprising at least one IZM-2 zeolite, a zeolite of WI framework type code and at least one binder.
PROCESS FOR DEPARAFFINNING A MIDDLE DISTILLATE FEEDSTOCK USING A CATALYST BASED ON IZM-2 ZEOLITE AND AN MFI-TYPE ZEOLITE
The present invention relates to a process for deparaffinning a middle distillate feedstock, to convert, in good yield, feedstocks having high pour points into at least one cut having an improved pour point.
Said process is performed with at least one catalyst comprising at least one hydro-dehydrogenating phase containing at least one metal from group VIB and at least one metal from group VIII of the Periodic Table of the Elements, and a support comprising at least one IZM-2 zeolite, a zeolite of WI framework type code and at least one binder.