Patent classifications
B01J29/78
AMMONIA OXIDATION CATALYST DEVICE
An ammonia oxidation catalyst device, including a substrate, a first catalyst coat layer and a second catalyst coat layer, wherein: the first catalyst coat layer includes inorganic oxide particles and a catalytic noble metal supported on the inorganic oxide particles; the second catalyst coat layer includes an NO.sub.x selective reduction catalyst and a proton zeolite H-Zeolite; the first catalyst coat layer is present on the substrate; and the second catalyst coat layer is present on the first catalyst coat layer.
AMMONIA OXIDATION CATALYST DEVICE
An ammonia oxidation catalyst device, including a substrate, a first catalyst coat layer and a second catalyst coat layer, wherein: the first catalyst coat layer includes inorganic oxide particles and a catalytic noble metal supported on the inorganic oxide particles; the second catalyst coat layer includes an NO.sub.x selective reduction catalyst and a proton zeolite H-Zeolite; the first catalyst coat layer is present on the substrate; and the second catalyst coat layer is present on the first catalyst coat layer.
Multi-functional composite catalyst materials and methods of synthesizing the catalyst materials
A multi-functional composite catalyst includes a catalyst support material, a preformed catalyst material at least partially secured in the catalyst support, and at least one catalytically active compound supported by the catalyst support, the preformed catalyst material, or both. The catalyst support material may include fumed silica, alumina, fumed alumina, fumed titania, or combinations of these. A catalytic activity of the catalytically active compound may be different than a catalytic activity of the preformed catalyst material. The composite catalyst may be catalyst for producing propene from 2-butene and may include a zeolite as the preformed catalyst material and a metal oxide, such as tungsten oxide, as the catalytically active material. A method of making the composite catalyst may include aerosolizing a catalyst precursor mixture that includes a preformed catalyst material, catalyst support precursor, and catalytically active compound precursor, and drying the aerosolized catalyst precursor mixture.
Catalyst and method for preparing light olefin using direct conversion of syngas
A catalyst for preparing light olefin using direct conversion of syngas is a composite catalyst and formed by compounding component I and component II in a mechanical mixing mode. The active ingredient of component I is a metal oxide; and the component II is one or more than one of zeolite of CHA and AEI structures or metal modified CHA and/or AEI zeolite. A weight ratio of the active ingredients in the component I to the component II is 0.1-20. The reaction process has high product yield and selectivity, wherein the sum of the selectivity of the propylene and butylene reaches 40-75%; and the sum of the selectivity of light olefin comprising ethylene, propylene and butylene can reach 50-90%. Meanwhile, the selectivity of a methane side product is less than 15%.
RAPID SYNTHESIS OF A CATALYST COMPRISING A ZEOLITE HAVING AN AFX STRUCTURE AND AT LEAST ONE TRANSITION METAL FOR SELECTIVE NOX REDUCTION
The invention relates to a process for preparing a catalyst based on a zeolite of AFX structural type and on at least one transition metal, comprising at least the following steps: i) mixing, in an aqueous medium, of at least one source of silicon in oxide form SiO.sub.2, of at least one source of aluminium in oxide form Al.sub.2O.sub.3, of an organic nitrogen-comprising compound R, of at least one source of at least one alkali metal and/or alkaline-earth metal M until a homogeneous precursor gel is obtained; ii) hydrothermal treatment of said precursor gel to obtain a crystallized solid phase, iii) at least one ion exchange with a transition metal; iv) heat treatment.
The invention also relates to the catalyst capable of being obtained or directly obtained by the process and to the process for the selective reduction of NOx employing the catalyst.
Zeolite synthesis with alkaline earth metal
Provided are a novel form of AFX zeolite, a novel synthesis technique for producing pure phase small pore zeolites, a novel synthesis method for producing a zeolite with an increased Al pair content, a catalyst comprising the AFX zeolite in combination with a metal, and methods of using the same.
Zeolite synthesis with alkaline earth metal
Provided are a novel form of AFX zeolite, a novel synthesis technique for producing pure phase small pore zeolites, a novel synthesis method for producing a zeolite with an increased Al pair content, a catalyst comprising the AFX zeolite in combination with a metal, and methods of using the same.
Zeolite composite catalysts for conversion of heavy reformate to xylenes
Embodiments of zeolite composite catalysts and methods of producing the zeolite composite catalysts are provided, where the methods comprise dissolving in an alkaline solution a catalyst precursor comprising at least one mesoporous zeolite while heating, stirring, or both to yield a dissolved zeolite solution, where the mesoporous zeolite has a molar ratio of SiO.sub.2/Al.sub.2O.sub.3 of at least 30, where the mesoporous zeolite comprises zeolite beta, adjusting the pH of the dissolved zeolite solution, aging the pH adjusted dissolved zeolite solution to yield solid zeolite composite from the dissolved zeolite solution, and calcining the solid zeolite composite to produce the zeolite composite catalyst, where the zeolite composite catalyst has a mesostructure comprising at least one disordered mesophase and at least one ordered mesophase, and where the zeolite composite catalyst has a surface area defined by the Brunauer-Emmett-Teller (BET) analysis of at least 600 m.sup.2/g.
Group III base stocks and lubricant compositions
Disclosed are Group III base stocks comprising at least 30 wt % naphthenes, a viscosity index from 120 to 145; and a unique ratio of molecules with multi-ring naphthenes to single ring naphthenes (2R+N/1RN). A method for preparing the base stocks is also disclosed. Also disclosed is a lubricating oil having the base stock as a major component, and an additive as a minor component.
USE OF A CATALYST FOR PRODUCTION OF METHANOL FROM METHANE, A METHOD OF PRODUCTION OF METHANOL FROM METHANE, THE CATALYST AND A METHOD OF PRODUCTION THEREOF
The present invention relates to the use of a catalyst for production of methanol from methane, wherein the catalyst comprises a zeolite having Al pairs in the skeleton of at least 10 percent, based on the total number of all aluminium atoms in the zeolite, and further comprising a transition metal cation coordinated at beta-cationic positions, selected from the group consisting of Fe, Co, Mn, and Ni, wherein the ratio of the transition metal to Al is in the range of from 0.01 to 0.5; and with the proviso that the zeolite is not ZSM-5 and mordenite. The present invention further relates to the method of production of methanol, the catalyst for production of methanol by direct oxidation of methane, and to a method of production thereof.