Patent classifications
B01D53/8609
Supported solid phase catalyst, and preparation method and use thereof
The present invention belongs to the flue gas desulfuration field. Specifically, the present invention relates to a supported solid-phase catalyst for oxidizing the by-product magnesium sulfite in a magnesium desulfuration process, and to preparation method and use thereof. The catalyst uses an activated carbon particle as a support, and cobalt nitrate, manganese nitrate, copper nitrate and ferrous nitrate as catalytically active components. The preparation method is as follows: mixing the pre-treated activated carbon support with the catalytically active components, followed by oscillating, standing under microwave irradiation, filtrating, drying, baking, so as to obtain the supported solid-phase catalyst. Raw materials of the present invention are inexpensive and easily available; the preparation process is simple; the catalyst has prominent catalytic effect and can be widely used in the magnesium desulfuration process in medium-sized and small-sized boilers of 75t or more to improve the recovery rate of the desulfuration by-product and reduce energy consumption of the oxidation system; the catalyst has a low amount of catalytically active components and causes low residue in the solution and hence no secondary pollution problem, and has a high generalization value.
SYSTEMS AND METHODS FOR POST COMBUSTION MERCURY CONTROL USING SORBENT INJECTION AND WET SCRUBBING
A sorbent composition for removing mercury from flue gas is provided. The sorbent composition contains at least a powdered sorbent, an oxidant and a catalyst. Methods of cleaning flue gas are also provided, which includes injecting the sorbent composition into the flue gas, wherein the powdered sorbent has a fifty percent distribution particle size of from about 25 micrometers to about 75 micrometers.
Pretreatment desulfurization method for ship fuel oil using pretreatment desulfurization agent
Proposed is a pretreatment desulfurization method for marine fuel oil. The method includes a step of preparing a pretreatment desulfurization agent including (a) at least one oxide selected from the group consisting of SiO2, Al2O3, Fe2O3, TiO2, MgO, MnO, CaO, Na2O, K2O, and P2O3, (b) at least one metal selected from the group consisting of Li, Cr, Co, Ni, Cu, Zn, Ga, Sr, Cd, and Pb, and (c) at least one liquid composition selected from the group consisting of sodium tetraborate (Na2B4O7.10H2O), sodium hydroxide (NaOH), sodium silicate (Na2SiO3). and hydrogen peroxide (H2O2). The method also includes a step of feeding the pretreatment desulfurization agent to a fuel supply line through which marine fuel oil is supplied to a marine engine at a certain ratio so that a fluid mixture containing the marine fuel oil and the pretreatment desulfurization agent is supplied to the marine engine, thereby adsorbing and removing sulfur oxides during combustion of the fluid mixture.
Continuous process and apparatus for purifying SO2-containing gases
The invention relates to a continuous process for purifying a gas containing 60-99 percent SO.sub.2 (sulfur dioxide) by volume and 1 to 40 percent steam by volume, followed by synthesis of SO.sub.3 (sulfur trioxide) without first drying the gas, and to an apparatus for carrying out said method.
Gas treatment process and apparatus
A process for cleaning process gas removes sulfur oxides (SOx), nitrogen oxides (NOx), and particulate matter (PM) to produce a tail gas substantially free of these pollutants. The process oxidizes and absorbs SOx and NOx for storage as liquid acids. In some embodiments a PM removal stage and/or a SOx removal stage are provided in a close-coupled higher-pressure environment upstream from a turbocharger turbine. The process has example application in cleaning exhaust gases from industrial processes and large diesel engines such as ship engines.
CONTAMINANT REMOVAL FOR CATALYTIC FUEL TANK INERTING SYSTEM
A fuel tank inerting system is disclosed. The system includes a fuel tank and a catalytic reactor with an inlet, an outlet, a reactive flow path between the inlet and the outlet, and a catalyst on the reactive flow path. The catalytic reactor is arranged to receive fuel from a fuel flow path in operative communication with the fuel tank and oxygen from an oxygen source, and to catalytically react a mixture of the fuel and oxygen along the reactive flow path to generate an inert gas. An inert gas flow path provides inert gas from the catalytic reactor to the fuel tank. An adsorbent is disposed along the fuel flow path or along the reactive flow path.
Method for desulfurization of selective catalytic reduction devices
Described herein is a desulfurization method for desulfurizing a SCR device treating an exhaust gas. The desulfurization method includes injecting a reductant into the exhaust gas upstream from or into the SCR device and increasing a temperature of the exhaust gas.
SULFUR DIOXIDE REMOVAL FROM WASTE GAS
A process where a gas, containing SO.sub.2 and O.sub.2 is brought in contact with a mixture of from 95% vol. to 50% vol. of activated carbon catalyst and from 5% vol. to 50% vol. of an inert filler material, where the SO.sub.2 is converted to H.sub.2SO.sub.4 on the activated carbon catalyst and is then washed from the activated carbon catalyst to obtain a H.sub.2SO.sub.4 solution.
CATALYST MIXTURE FOR THE TREATMENT OF WASTE GAS
A catalyst comprises a mixture of 95% vol. to 30% vol. of an activated carbon catalyst and from 5% vol. to 70% vol. of a filler material as well as a configuration of such a catalyst for the removal of SO.sub.2, heavy metals and/or dioxins form waste gas and liquids.
AIR POLLUTION CONTROL SYSTEM
An air pollution control system includes adenitration device that removes nitrogen oxide in flue gas from a boiler; a heat transfer tube for recovering part of heat of the flue gas after denitration; a precipitator that removes soot and dust in the flue gas after heat recovery; a desulfurization device that removes sulfur oxide in the flue gas discharged from the precipitator; a heat transfer tube for heating the flue gas discharged from the desulfurization device; a circulation pump that circulates a heat medium between the heat transfer tubes; a heat medium heater provided to the circulation pipe to heat the heat medium; and a control device that controls the heat medium heater based on an ammonia concentration at an outlet of the denitration device. The control device causes the heat medium heater to heat the heat medium when the ammonia concentration is higher than a certain value.