A flexible material is disclosed comprising a flexible substrate, a sorbent comprising zirconium hydroxide and a binder, wherein the solids weight ratio of the binder to the zirconium hydroxide is in the range 1:1 to 1:120. Also disclosed is a process for production of a fabric, comprising: providing a flexible material, providing at least one sorbent dispersion comprising zirconium hydroxide and a binder, applying the sorbent dispersion to the flexible material to produce a treated flexible material, squeezing the treated flexible material under pressure, and passing the pressed treated flexible material through a stenter.

A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula A.sub.x(L.sup.-x) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula A.sub.x(L.sup.-x)/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula H.sub.x(L.sup.- .sup.x)/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M.sup.+y(B).sub.y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M.sup.+y(B).sub.y][H.sub.x(L.sup.-x)]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M.sup.+yL.sup.-x)/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.

The present disclosure provides novel solid sorbents synthesized by the reaction of polyamines with polyaldehyde phosphorus dendrimer (P-dendrimer) compounds for metal sequestration. The sorbents are highly stable and exhibit desirable thermodynamics and reaction kinetics with a wide variety of metals including heavy metals and rare earth elements. The sorbents can be easily regenerated for repeated use to extract metals from an aqueous solution. The materials are stable to aqueous and organic media, as well as strong acid and bases. The sorbents maintain full capacity over many cycles of use.

The present invention relates to a molding comprising a zeolitic material having framework type MWW, wherein the framework structure comprises Ti, Si, and O, wherein the zeolitic material further comprises Zn and an alkaline earth metal M, the molding further comprising a binder, wherein the molding exhibits a specific Lewis acidity. Further, the present invention relates to the method of preparation of said molding and the use thereof.

Systems and methods for reducing the burden of recharging on patients and caregivers are provided. The systems and methods use a microbe removal layer upstream of a sorbent cartridge in a sorbent-based dialysis system. The systems and methods can determine whether the bacterial content and remaining capacity of a non-recharged sorbent module are suitable for the sorbent module to be reused safely and effectively without recharging.

Macroporous desiccant based honeycomb matrix containing the macroporous desiccant synthesized “in-situ”, the desiccant having a differential water adsorption. Process for the “in-situ” preparation of the macroporous desiccant based honeycomb matrix including the steps of soaking honeycomb substrate impregnated with water glass, in aqueous metal salt(s) solution or acid solution, or combination thereof, until such time that the hydrogel honeycomb matrix is obtained and thermally activating the hydrogel honeycomb matrix to produce macroporous desiccant based honeycomb matrix.

Copper sulfide of the formula Cu.sub.xS.sub.y, wherein x and y are integer or non-integer values, wherein (i) the copper sulfide has a sulfur 2p XPS spectrum with peaks at 162.3 eV (±1 ev), 163.8 eV (±1 ev) and 68.5 eV (±1 ev), characterised in that the peak at 168.5 eV has a lower value of counts per second (CPS) than both the peak at 162.3 eV and the peak at 163.8 eV; and (ii) the copper sulfide has a copper 2p XPS spectrum with peaks at 932.0 eV (±2 ev) and 933.6 eV (±3 eV) and characterised in that the XPS spectrum does not comprise identifiable satellite peaks at 939.8 eV and 943.1 eV (±3 eV).

The invention relates to a method to produce a particulate activated carbon material for capturing CO.sub.2 from air, wherein the particulate activated carbon is impregnated with alkali carbonate salt such as K.sub.2CO.sub.3; and wherein the impregnated particulate activated carbon either has, determined using nitrogen adsorption methods, a pore volume of at least 0.10 cm.sup.3/g for pore sizes of at least 5 nm and a pore volume of at most 0.30 cm.sup.3/g for pore sizes of less than 2 nm or is based on a mixture of different alkali carbonate salts, or has a particular pore surface for pore sizes in the range of 2 nm-50 nm.

A trivalent doped cerium oxide composition is beneficial to aid in the removal of biological contaminants, such as bacteria, viruses, fungi, protozoa (e.g., amoebae), yeast and algae. These trivalent doped cerium oxide compositions can be used to remove these biological contaminants from fluids, including air and water, and from solid surfaces. The compositions also include a support material. Also described are methods of using compositions containing these trivalent doped cerium oxide compositions to remove biological contaminants.

Provided herein are methods of making an adsorbent bed useful as a micro-reactor, or a catalytic and/or separation device. The adsorbent bed comprises a metal-organic framework composite. In the present methods, one or more metal-organic frameworks in powder form are mixed in a liquid to produce a metal-organic framework suspension or other type of metal-organic framework coating. A monolith is coated with the suspension or coating to provide the metal-organic framework composite having at least one metal-organic framework coating layer deposited on and bounded to the monolith. The metal-organic framework composite produced has a BET surface area of about 1 m.sup.2/g to about 300 m.sup.2/g and/or a comparative BET surface area of about 40% to about 100% relative to the metal-organic framework monolith, and pore size between about 1 nm and about 50 nm.