B01D53/9418

Systems and methods for mixing exhaust gas and reductant

A mixing assembly for an exhaust aftertreatment system includes a mixing body, an upstream plate, a downstream plate, and a swirl plate. The mixing body includes an upstream mixing body opening and a downstream mixing body opening. The upstream mixing body opening is configured to receive exhaust gas. The upstream plate is coupled to the mixing body. The upstream plate includes a plurality of upstream plate openings. Each of the plurality of upstream plate openings is configured to receive a flow percentage that is less than 50% of the total flow of the exhaust gas. The downstream plate is coupled to the mixing body downstream from the upstream plate in a direction of exhaust gas flow. The downstream plate includes a downstream plate opening. The swirl plate is positioned between the upstream plate and the downstream plate and defines a swirl collection region and a swirl concentration region.

METHOD OF MAKING AFX ZEOLITES HAVING HIGH THERMAL STABILITY
20210394165 · 2021-12-23 ·

A method of forming an AFX zeolite in a hydrothermal synthesis that exhibits a silica to alumina (SiO.sub.2AI.sub.2O.sub.3) molar ratio (SAR) that is between 8:1 and 26:1; has a morphology that includes one or more of cubic, spheroidal, or rhombic particles with a crystal size that is in the range of about 0.1 micrometer (μm) to 10 μm. This AFX zeolite also exhibits a Brönsted acidity that is in the range of 1.2 mmol/g to 3.6 mmol/g as measured by ammonia temperature programmed desorption. A catalyst formed by substituting a metal into the framework of the zeolite exhibits about a 100% conversion of NO emissions over the temperature range of 300° C. to 650° C.

Exhaust gas purifying catalyst

This exhaust gas purifying catalyst is provided with a substrate 10 and a catalyst layer 20 formed on a surface of the substrate 10. The catalyst layer 20 contains zeolite particles 22 that support a metal, and a rare earth element-containing compound 24 that contains a rare earth element. The rare earth element-containing compound 24 is added in such an amount that the molar ratio of the rare earth element relative to Si contained in the zeolite 22 is 0.001 to 0.014 in terms of oxides.

Nitrogen oxide reduction catalyst regenerable at low temperature

Provided is a nitrogen oxide (NO.sub.X) reduction catalyst including an active site including at least one of a metal vanadate expressed by [Chemical Formula 1] and a metal vanadate expressed by [Chemical Formula 2], and a support for loading the active site thereon.
(M.sub.1).sub.XV.sub.2O.sub.X+5  [Chemical Formula 1] (where M.sub.1 denotes one selected from among manganese (Mn), cobalt (Co), and nickel (Ni), and X denotes a real number having a value between 1 and 3.)
(M.sub.2).sub.YVO.sub.4  [Chemical Formula 2] (where M.sub.2 denotes one selected from among lanthanum (La), cerium (Ce), praseodymium (Pr), neodymium (Nd), promethium (Pm), samarium (Sm), europium (Eu), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), and lutetium (Lu), and Y denotes a real number having a value between 0.5 and 1.5).

EXHAUST TREATMENT SYSTEM FOR A LEAN BURN ENGINE

The present invention relates generally to the field of exhaust treatment systems for purifying exhaust gas discharged from a lean burn engine. The exhaust treatment system comprises a Diesel Oxidation Catalyst (DOC), a Catalyzed Soot Filter (CSF), a reductant injector, an AEI zeolite based Selective Catalyzed Reduction (SCR) catalyst and an Ammonia Oxidation Catalyst (AMOX) downstream to the AEI zeolite based SCR catalyst.

Process for producing a catalyst and catalyst as such

To be able to produce an SCR catalyst (2), in particular one having a zeolite fraction (Z) as catalytically active fraction, in a reliable process and at the same time achieve good catalytic activity of the catalyst (2), an inorganic binder fraction (B) which is catalytically inactive in the starting state and has been treated to develop catalytic activity is mixed into a catalyst composition (4). The inorganic binder component for the binder fraction (B) is, in the starting state, preferably porous particles (10), in particular diatomaceous earth, which display mesoporosity. To effect catalytic activation, the individual particles (10) are either coated with a catalytically active layer (12) or transformed into a catalytically active zeolite (14) with maintenance of the mesoporosity.

Integrated emissions control system

The disclosure provides a monolithic wall-flow filter catalytic article including a substrate having an aspect ratio of from about 1 to about 20, and having a functional coating composition disposed on the substrate, the functional coating composition including a first sorbent composition, an oxidation catalyst composition, and optionally, a second sorbent composition. The monolithic wall-flow filter catalytic article may be in a close-coupled position close to the engine. The disclosure further provides an integrated exhaust gas treatment system including the monolithic wall-flow filter catalytic article and may additionally include a flow-through monolith catalytic article. The flow-through monolith catalytic article includes a substrate having a selective catalytic reduction (SCR) coating composition disposed thereon. The integrated exhaust gas treatment system simplifies the traditional four-article system into a two-article Catalyzed Soot Filter (CSF) plus Selective Catalytic Reduction (SCR) CSF+SCR arrangement.

SELECTIVE CATALYTIC REDUCTION CATALYST ON A FILTER SUBSTRATE

A selective catalytic reduction catalyst for the treatment of an exhaust gas stream of a passive ignition engine, the catalyst comprising a porous wall-flow filter substrate comprising an inlet end, an outlet end, a substrate axial length (w) extending between the inlet end and the outlet end, and a plurality of passages defined by porous internal walls of the porous wall flow filter substrate; wherein the catalyst further comprises a first coating, said first coating extending over x % of the substrate axial length from the inlet end toward the outlet end of the substrate, x being in the range of from 10 to 100, wherein the first coating comprises copper and an 8-membered ring pore zeolitic material; wherein the catalyst further comprises a second coating, the second coating extending over y % of the substrate axial length from the outlet end toward the inlet end of the substrate, y being in the range of from 20 to 90, wherein the second coating comprises copper, and optionally an 8-membered ring pore zeolitic material; wherein the catalyst optionally further comprises a third coating; wherein x+y is at least 90; wherein y % of w from the outlet end toward the inlet end of the substrate define the outlet zone of the coated substrate and (100−y) % of w from the inlet end toward the outlet end of the substrate define the inlet zone of the coated substrate; wherein the ratio of the loading of copper in the inlet zone, Cu(in), calculated as CuO, relative to the loading of copper in the outlet zone, Cu(out), calculated as CuO, Cu(in):Cu(out), is less than 1:1.

Cu-P CO-SUPPORTED ZEOLITE, AND SELECTIVE CATALYTIC REDUCTION CATALYST AND CATALYST FOR EXHAUST GAS USING SAME

Provided are a high-performance Cu—P co-supported zeolite and the like having excellent thermal endurance and catalyst performance. A Cu—P co-supported zeolite comprising at least a small pore size zeolite, and an extra-backbone copper atom and an extra-backbone phosphorus atom supported on the small pore size zeolite, wherein a silica-alumina ratio (SiO.sub.2/Al.sub.2O.sub.3) is 7 or more and 20 or less, a ratio of the copper atom to a T atom (Cu/T) is 0.005 or more and 0.060 or less, a ratio of the phosphorus atom to the T atom (P/T) is 0.005 or more and 0.060 or less, and a ratio of the phosphorus atom to the copper atom (P/Cu) is 0.1 or more and 3 or less.

METHOD

The present disclosure relates to a method for forming a catalyst article comprising: (a) forming a slurry having a solids content of up to 50 wt % by mixing together at least the following components a crystalline molecular sieve in an H.sup.+ or NH.sub.4.sup.+ form, an insoluble active metal precursor and an aqueous solvent at a temperature in the range 10 to 35° C.; (b) coating a substrate with the slurry formed in step (a); and (c) calcining the coated substrate formed in step (b) to form a catalyst layer on the substrate. The present disclosure further relates to a catalyst article, particularly a catalyst article which is suitable for use in the selective catalytic reduction of nitrogen oxides, and to an exhaust system.