Provided is a method for manufacturing a slurry for a positive electrode of a nonaqueous electrolyte secondary battery containing an alkali metal complex oxide, the method making it possible to reliably deaerate surplus carbonic acid gas after an alkali component of a slurry containing the alkali metal complex oxide is neutralized within a short period of time. The method for manufacturing a slurry for a positive electrode of a nonaqueous electrolyte secondary battery includes a step of manufacturing an electrode slurry including a step of performing a neutralization treatment on an alkali component in the slurry by using inorganic carbon dissolved in a solvent of the slurry and a step of deaerating the inorganic carbon in the slurry as carbonic acid gas by causing cavitation.

According to one embodiment, an active material is provided. This active material includes active material particles containing orthorhombic Na-containing niobium titanium composite oxide, and satisfies the following formula (1):

1≦A5/A0  (1) where A5 is a mole content ratio of a Li mole content L5 to a total of a Ti mole content T5 and a Nb mole content N5, and A0 is a mole content ratio of a Li mole content L0 to a total of a Ti mole content T0 and a Nb mole content N0.

A manganese oxide contains M1, optionally M2, Mn and O. M1 is selected from the group consisting of In, Sc, Y, Dy, Ho, Er, Tm, Yb and Lu. M2 is different from M1, and M2 is selected from the group consisting of Bi, In, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu. These ceramic materials are hexagonal in structure, and provide superior materials for gas separation and oxygen storage.

The present disclosure relates to a cathode active material, and more particularly, to a cathode active material doped with a trivalent metal (Me) and a lithium secondary battery comprising the same. According to one aspect, there is provided the cathode active material doped with the trivalent metal (Me), represented by the formula Li.sub.xMn.sub.2Me.sub.yO.sub.4 (here, x is from 0.5 to 1.3, and y is from 0.01 to 0.1). According to the present disclosure, release of manganese ions of the cathode active material greatly reduces, and consequently, capacity and cycle life of the battery may be significantly improved.

A powder for an air electrode in a solid oxide fuel cell, the powder consisting of: a metal composite oxide having a perovskite-type single phase crystal structure represented by A1.sub.1-xA2.sub.xBO.sub.3-δ, where the element A1 is at least one selected from the group consisting of La and Sm, the element A2 is at least one selected from the group consisting of Ca, Sr, and Ba, the element B is at least one selected from the group consisting of Mn, Fe, Co, and Ni, 0<x<1, and the δ is an oxygen deficiency amount. When a cross section of a molded body obtained by compression molding the powder is observed at a magnification of 500 times, and a characteristic X-ray intensity of the element B is measured by an energy dispersive X-ray spectroscopy, the number of regions each having an intensity of 50% or higher of a maximum of the characteristic X-ray intensity of the element B and occupying 0.04% by area or more of the observation field of view is five or less.

Process for manufacturing a lithiated transition metal oxide, said process comprising the steps of (a) mixing at least one lithium salt and a precursor selected from transition metal oxides, transition metal oxyhydroxides, transition metal hydroxides, and transition metal carbonates, (b) pre-calcining the mixture obtained in step (a) at a temperature in the range of from 300 to 700° C., and (c) calcining the pre-calcined mixture according to step (b) in a multi-stage fluidized bed reactor at a temperature in the range of from 550° C. to 950° C., wherein the temperatures in step (b) and (c) are selected in a way that step (c) is being performed at a temperature higher than that of step (b).

A negative thermal expansion material and a preparation method thereof, and a negative thermal expansion film and a preparation method thereof are provided. The negative thermal expansion material includes Eu.sub.0.85Cu.sub.0.15MnO.sub.3-δ, wherein 0≤δ≤2.

Supplemental lithium can be used to stabilize lithium ion batteries with lithium rich metal oxides as the positive electrode active material. Dramatic improvements in the specific capacity at long cycling have been obtained. The supplemental lithium can be provided with the negative electrode, or alternatively as a sacrificial material that is subsequently driven into the negative electrode active material. The supplemental lithium can be provided to the negative electrode active material prior to assembly of the battery using electrochemical deposition. The positive electrode active materials can comprise a layered-layered structure comprising manganese as well as nickel and/or cobalt.

A binder-free, self-supporting electrode including an electrochemically active material in the absence of a binder and a current collector is claimed. The electrochemically active material is a self-supporting transition metal oxide. A method of regenerating the electrode to restore capacity of the electrode is also claimed.

A positive electrode active material contains a lithium composite oxide and a covering material. The lithium composite oxide has a crystal structure that belongs to space group Fd-3m. The ration I.sub.(111)/I.sub.(400) of a first integrated intensity I.sub.(111) of a first peak corresponding to a (111) plane to a second integrated intensity I.sub.(400) of a second peak corresponding to a (400) plane in an XRD pattern of the lithium composite oxide satisfies 0.05≤I.sub.(111)/I.sub.(400)≤0.90. The covering material has an electron conductivity of 10.sup.6 S/m or less.