To provide a sterilizer preventing ultraviolet ray absorption in a body of a case body and emitting ultraviolet rays to a portion to be sterilized without involving positioning with high accuracy. A sterilizer 1a has a case body 2 containing a member having an ultraviolet-ray transmission property and a flow passage formed thereinside and an ultraviolet-ray irradiation portion 3 irradiating a predetermined portion of a member configuring the case body 2 with ultraviolet rays, in which ultraviolet rays emitted from the ultraviolet-ray irradiation portion 3 travel in a body of the case body 2 to be radiated at least from an end surface on an output end side of the case body 2.

A method for desalinating a brine includes the use of a cooled intermediate-cold-liquid (ICL), which combines with the brine in a crystallization or freezing tank to produce a slurry of ice, brine, and ICL. The method includes steps for separating the ICL, ice and brine, and returning the separated ICL to the source of cooled ICL tank. The method concludes with the steps of passing the separated brine to the crystallization tank, and melting the separated ice to form desalinated water. The method is significant in that it produces desalinated liquid water and solid salts. The combination of superior heat transfer with high quality purified water and competitive desalination economy makes the disclosed freeze desalination technology an attractive solution for desalination of highly concentrated brines produced in a variety of industries, including but not limited to the oil and gas industry and reject brine management.

A method for desalinating a brine includes the use of a cooled intermediate-cold-liquid (ICL), which combines with the brine in a crystallization or freezing tank to produce a slurry of ice, brine, and ICL. The method includes steps for separating the ICL, ice and brine, and returning the separated ICL to the source of cooled ICL tank. The method concludes with the steps of passing the separated brine to the crystallization tank, and melting the separated ice to form desalinated water. The method is significant in that it produces desalinated liquid water and solid salts. The combination of superior heat transfer with high quality purified water and competitive desalination economy makes the disclosed freeze desalination technology an attractive solution for desalination of highly concentrated brines produced in a variety of industries, including but not limited to the oil and gas industry and reject brine management.

A process and system for treating fluid comprising water, radioactive particulate, dissolved ions, and a neutron absorber are provided. The fluid is received from a cutting zone for recover), of radioactive components. The process comprises receiving a fluid in a crystallization unit, the fluid comprising the water, the radioactive particulate, and the neutron absorber dissolved in the fluid; cooling the fluid below a freezing point of the fluid to form a first crystal comprising the water and to form a second crystal comprising the neutron absorber, the second crystal having a greater density than the first crystal; and separating the first crystal from the second crystal, the radioactive particulate, and the dissolved ions.

A controlled-type recalcitrant high-concentration freeze-separation apparatus, includes: a condenser having therein a condenser stainless antifreeze tube formed in a cell and tube form, and a condenser copper refrigerant tube formed in a cell and tube form inside the stainless antifreeze tube to block direct contact between circulating water flowing into the condenser and the condenser copper refrigerant tube; and an evaporator having therein an evaporator stainless antifreeze tube formed in a form of a cell and tube inside, and an evaporator copper refrigerant tube formed in a cell and tube form inside the evaporator stainless antifreeze tube to block direct contact between circulating water flowing into the evaporator and the evaporator copper refrigerant tube.

A controlled-type recalcitrant high-concentration freeze-separation apparatus, includes: a condenser having therein a condenser stainless antifreeze tube formed in a cell and tube form, and a condenser copper refrigerant tube formed in a cell and tube form inside the stainless antifreeze tube to block direct contact between circulating water flowing into the condenser and the condenser copper refrigerant tube; and an evaporator having therein an evaporator stainless antifreeze tube formed in a form of a cell and tube inside, and an evaporator copper refrigerant tube formed in a cell and tube form inside the evaporator stainless antifreeze tube to block direct contact between circulating water flowing into the evaporator and the evaporator copper refrigerant tube.

The present invention is a process, a method, and system for recovery and concentration of dissolved ammonium bicarbonate from a wastewater containing ammonia (NH3) using gas separation, condensation, and crystallization, each at controlled operating temperatures. The present invention includes 1) removal of ammonia from waste (sludges, semi-solids, and solids and liquids) without the use of chemicals at a temperature of at least 80 degrees Celsius, 2) condensing the gaseous containing ammonia, carbon dioxide and water vapor to remove water vapor concentrating the amount of gaseous ammonia and carbon dioxide, 3) concentrating the ammonia and carbon dioxide in the water by established means, such as concentrating the gas using partial condensation followed by passing the concentrated gas through an absorption column at a temperature of between about 20 and 50 degrees Celsius to form dissolved ammonium carbonate and ammonium bicarbonate, or total condensation followed by dewatering using reverse osmosis, and 4) crystallizing concentrated dissolved ammonium carbonate and ammonium bicarbonate at a temperature of less than about 35 degrees Celsius to form solid ammonium bicarbonate and ammonium carbonate.

In a method for treating waste water containing ammonium salts, sodium sulfate crystal is obtained by freezing crystallization, then the pH value of the waste water is adjusted to a specific range, and next sodium chloride crystal and ammonia water is obtained by evaporation. Alternatively, the pH value of the waste water is adjusted to a specific range, then sodium chloride crystal and ammonia water is obtained by evaporation, and next sodium sulfate crystal is obtained by freezing crystallization. This method can recover ammonia, sodium sulfate, and sodium chloride from the waste water.

A method for treating wastewater, comprising: (i) injecting a hydrate-forming gas (e.g., propane) into the wastewater under conditions of elevated pressure and reduced temperature to form a solid hydrate composed of the hydrate-forming gas and water from the wastewater; and (ii) separating the solid hydrate from the wastewater to result in removal of water from the wastewater, thereby resulting in partially dewatered wastewater, and optionally, (iii) lowering the pressure and/or raising the temperature of the solid hydrate to decompose the solid hydrate into reformed hydrate-forming gas and reformed water, and further optionally, recycling the reformed hydrate-forming gas for use in step (i) and/or capturing the reformed water from step (iii) and further decontaminating until suitable for release into waterway or for use in a process. The invention is also directed to an apparatus for practicing the method described above.

A method for treating wastewater, comprising: (i) injecting a hydrate-forming gas (e.g., propane) into the wastewater under conditions of elevated pressure and reduced temperature to form a solid hydrate composed of the hydrate-forming gas and water from the wastewater; and (ii) separating the solid hydrate from the wastewater to result in removal of water from the wastewater, thereby resulting in partially dewatered wastewater, and optionally, (iii) lowering the pressure and/or raising the temperature of the solid hydrate to decompose the solid hydrate into reformed hydrate-forming gas and reformed water, and further optionally, recycling the reformed hydrate-forming gas for use in step (i) and/or capturing the reformed water from step (iii) and further decontaminating until suitable for release into waterway or for use in a process. The invention is also directed to an apparatus for practicing the method described above.