A pre-ceramic support structure for additive manufacturing, that upon thermal processing, is soluble in various solvents.

A pre-ceramic support structure for additive manufacturing, that upon thermal processing, is soluble in various solvents.

A pre-ceramic support structure for additive manufacturing, that upon thermal processing, is soluble in various solvents.

A pre-ceramic support structure for additive manufacturing, that upon thermal processing, is soluble in various solvents.

A non-sintered high-strength lightweight aggregate one-shot prepared from sulfur-based and alkaline-based solid wastes by stirring, granulation, and foaming, and a preparation method therefor and use thereof. The non-sintered high-strength lightweight aggregate is prepared from a sulfur-based solid waste, an alkaline-based solid waste, an auxiliary cementing material, a ferro-aluminum-sulfur cementing material, water, and a foaming agent as raw materials. Based on the mass of the total solid, the total content of the sulfur-based solid waste, the alkaline-based solid waste, and the auxiliary cementing material is 80-90 wt %, and the content of the ferro-aluminum-sulfur cementing material is 10-20 wt %. The mass ratio of the water to the total solid is (15-20):(80-85). The foaming agent accounts for 0.3-0.7% of the mass of the total solid. The mass ratio between the sulfur-based solid waste, the alkaline-based solid waste, and the auxiliary cementing material is (27-33):(27-33):(18-25).

A non-sintered high-strength lightweight aggregate one-shot prepared from sulfur-based and alkaline-based solid wastes by stirring, granulation, and foaming, and a preparation method therefor and use thereof. The non-sintered high-strength lightweight aggregate is prepared from a sulfur-based solid waste, an alkaline-based solid waste, an auxiliary cementing material, a ferro-aluminum-sulfur cementing material, water, and a foaming agent as raw materials. Based on the mass of the total solid, the total content of the sulfur-based solid waste, the alkaline-based solid waste, and the auxiliary cementing material is 80-90 wt %, and the content of the ferro-aluminum-sulfur cementing material is 10-20 wt %. The mass ratio of the water to the total solid is (15-20):(80-85). The foaming agent accounts for 0.3-0.7% of the mass of the total solid. The mass ratio between the sulfur-based solid waste, the alkaline-based solid waste, and the auxiliary cementing material is (27-33):(27-33):(18-25).

A feedstock material for use as a support material in an additive manufacturing system includes a pre-ceramic material in powder form. The preceramic material comprises calcium carbonate, sodium carbonate, sodium aluminate or combinations thereof. The feedstock material includes a thermoplastic binder having the pre-ceramic material dispersed therein, wherein the pre-ceramic material and the thermoplastic binder are in a filament form. The filament is configured to be melted and extruded to form a support structure for a ceramifable article in a layer by layer manner, wherein the pre-ceramic material is at least about 50% of the feedstock material.

A feedstock material for use as a support material in an additive manufacturing system includes a pre-ceramic material in powder form. The preceramic material comprises calcium carbonate, sodium carbonate, sodium aluminate or combinations thereof. The feedstock material includes a thermoplastic binder having the pre-ceramic material dispersed therein, wherein the pre-ceramic material and the thermoplastic binder are in a filament form. The filament is configured to be melted and extruded to form a support structure for a ceramifable article in a layer by layer manner, wherein the pre-ceramic material is at least about 50% of the feedstock material.

A composition and a method for producing mesoporous carbon materials with a chiral or achiral organization. In the method, a polymerizable inorganic monomer is reacted in the presence of nanocrystalline cellulose to give a material of inorganic solid with cellulose nanocrystallites organized in a chiral nematic organization. The cellulose can be carbonized through thermal treatment under inert atmosphere (e.g., nitrogen or argon) and the silica may subsequently be removed using aqueous solutions of sodium hydroxide (NaOH) or hydrogen fluoride (HF) to give the stable mesoporous carbon materials that retain the chiral nematic structure of the cellulose. These materials may be obtained as free-standing films with very high surface area. Through control of the reaction conditions the pore-size distribution may be varied from predominantly microporous to predominantly mesoporous materials. These are the first materials to use cellulose as both the structural template and carbon source for a mesoporous carbon material. These are also the first carbon materials to combine mesoporosity with long-range chiral ordering. Possible applications for these materials include: charge storage devices (e.g. supercapacitors and anodes for Li-ion batteries), adsorbents, gas purifiers, light-weight nanocomposite materials, catalyst supports (e.g., for chiral transformations), gas storage, and as a hard-template to generate other materials, preferably with chiral structures.

A composition and a method for producing mesoporous carbon materials with a chiral or achiral organization. In the method, a polymerizable inorganic monomer is reacted in the presence of nanocrystalline cellulose to give a material of inorganic solid with cellulose nanocrystallites organized in a chiral nematic organization. The cellulose can be carbonized through thermal treatment under inert atmosphere (e.g., nitrogen or argon) and the silica may subsequently be removed using aqueous solutions of sodium hydroxide (NaOH) or hydrogen fluoride (HF) to give the stable mesoporous carbon materials that retain the chiral nematic structure of the cellulose. These materials may be obtained as free-standing films with very high surface area. Through control of the reaction conditions the pore-size distribution may be varied from predominantly microporous to predominantly mesoporous materials. These are the first materials to use cellulose as both the structural template and carbon source for a mesoporous carbon material. These are also the first carbon materials to combine mesoporosity with long-range chiral ordering. Possible applications for these materials include: charge storage devices (e.g. supercapacitors and anodes for Li-ion batteries), adsorbents, gas purifiers, light-weight nanocomposite materials, catalyst supports (e.g., for chiral transformations), gas storage, and as a hard-template to generate other materials, preferably with chiral structures.