The present disclosure relates to a method of decomposing a phenolic by-product, including: a step of feeding and thermally cracking a phenolic by-product stream to and in a decomposition apparatus, recovering an active ingredient from a top discharge stream, and discharging a high-boiling substance through a bottom discharge stream; a step of pressurizing each of a side discharge stream of the decomposition apparatus and a bottom discharge stream of the decomposition apparatus; a step of mixing the pressurized side discharge stream of the decomposition apparatus and the pressurized bottom discharge stream of the decomposition apparatus with each other to form a mixed stream; and a step of passing a part of the mixed stream through a reboiler, circulating the part of the mixed stream to the decomposition apparatus, and discharging a residual mixed stream.

The present disclosure relates to a method of decomposing a phenolic by-product, including: a step of feeding and thermally cracking a phenolic by-product stream to and in a decomposition apparatus, recovering an active ingredient from a top discharge stream, and discharging a high-boiling substance through a bottom discharge stream; a step of pressurizing each of a side discharge stream of the decomposition apparatus and a bottom discharge stream of the decomposition apparatus; a step of mixing the pressurized side discharge stream of the decomposition apparatus and the pressurized bottom discharge stream of the decomposition apparatus with each other to form a mixed stream; and a step of passing a part of the mixed stream through a reboiler, circulating the part of the mixed stream to the decomposition apparatus, and discharging a residual mixed stream.

The invention relates to a method and process arrangement for producing hydrocarbons from plastic containing raw material by means of a gasification process in which the plastic containing raw material is gasified with steam at low gasification temperature of 680-740° C. in a fluidized bed gasifier for forming a product mixture comprising hydrocarbons, and the residence time is below 4 s at the gasification temperature, and the product mixture is cooled rapidly after the gasification to temperature which is below 640° C. for slowing and/or stopping the gasification reaction of the plastic containing raw material in order to increase propylene yield of the gasification process. Further, the invention relates to the use of the method.

The invention relates to a method and process arrangement for producing hydrocarbons from plastic containing raw material by means of a gasification process in which the plastic containing raw material is gasified with steam at low gasification temperature of 680-740° C. in a fluidized bed gasifier for forming a product mixture comprising hydrocarbons, and the residence time is below 4 s at the gasification temperature, and the product mixture is cooled rapidly after the gasification to temperature which is below 640° C. for slowing and/or stopping the gasification reaction of the plastic containing raw material in order to increase propylene yield of the gasification process. Further, the invention relates to the use of the method.

Provided is a continuous process for converting waste plastic into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and preparing a stable blend of petroleum and the selected plastic. The amount of plastic in the blend comprises no more than 20 wt. % of the blend. The blend is passed to a refinery crude unit. A liquid petroleum gas C.sub.3 olefin/paraffin mixture is recovered from the crude unit. The C.sub.3 paraffins and C.sub.3 olefins are separated into different fractions with the C.sub.3 olefin fraction passed to a propylene polymerization reactor, and the C.sub.3 paraffin fraction passed to a dehydrogenation unit to produce additional propylene. Product streams from the crude unit can also be passed to a hydrocracking unit, with a recovered heavy fraction then being passed to an isomerization dewaxing unit to prepare base oil.

Provided is a continuous process for converting waste plastic into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and preparing a stable blend of petroleum and the selected plastic. The amount of plastic in the blend comprises no more than 20 wt. % of the blend. The blend is passed to a refinery crude unit. A liquid petroleum gas C.sub.3 olefin/paraffin mixture is recovered from the crude unit. The C.sub.3 paraffins and C.sub.3 olefins are separated into different fractions with the C.sub.3 olefin fraction passed to a propylene polymerization reactor, and the C.sub.3 paraffin fraction passed to a dehydrogenation unit to produce additional propylene. Product streams from the crude unit can also be passed to a hydrocracking unit, with a recovered heavy fraction then being passed to an isomerization dewaxing unit to prepare base oil.

Provided is a continuous process for converting waste plastic into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and preparing a stable blend of petroleum and the selected plastic. The amount of plastic in the blend comprises no more than 20 wt. % of the blend. The blend is passed to a refinery FCC unit. A liquid petroleum gas C.sub.3 olefin/paraffin mixture is recovered from the FCC unit. The C.sub.3 paraffins and C.sub.3 olefins are separated into different fractions with the C.sub.3 olefin fraction passed to a propylene polymerization reactor, and the C.sub.3 paraffin fraction passed optionally to a dehydrogenation unit to produce additional propylene.

Provided is a continuous process for converting waste plastic into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and preparing a stable blend of petroleum and the selected plastic. The amount of plastic in the blend comprises no more than 20 wt. % of the blend. The blend is passed to a refinery FCC unit. A liquid petroleum gas C.sub.3 olefin/paraffin mixture is recovered from the FCC unit. The C.sub.3 paraffins and C.sub.3 olefins are separated into different fractions with the C.sub.3 olefin fraction passed to a propylene polymerization reactor, and the C.sub.3 paraffin fraction passed optionally to a dehydrogenation unit to produce additional propylene.

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and preparing a stable blend of petroleum and the selected plastic. The amount of plastic in the blend comprises no more than 20 wt.% of the blend. The blend is passed to a refinery crude unit. A liquid petroleum gas C.sub.3-C.sub.4 olefin/paraffin mixture, and optionally naphtha stream, is recovered from the crude unit and passed to a steam cracker to make ethylene. Product streams from the crude unit can also be passed to a hydrocracking unit, with a recovered heavy fraction then being passed to an isomerization dewaxing unit to prepare base oil.

Provided is a continuous process for converting waste plastic into recycle for polyethylene polymerization. The process comprises selecting waste plastics containing polyethylene and/or polypropylene and preparing a stable blend of petroleum and the selected plastic. The amount of plastic in the blend comprises no more than 20 wt.% of the blend. The blend is passed to a refinery crude unit. A liquid petroleum gas C.sub.3-C.sub.4 olefin/paraffin mixture, and optionally naphtha stream, is recovered from the crude unit and passed to a steam cracker to make ethylene. Product streams from the crude unit can also be passed to a hydrocracking unit, with a recovered heavy fraction then being passed to an isomerization dewaxing unit to prepare base oil.