C08F4/04

METHOD FOR PRODUCING VINYL ETHER POLYMER CONTAINING HYDROCARBON GROUP BY RADICAL POLYMERIZATION

[Object] To provide a method for producing a vinyl ether polymer containing a hydrocarbon group in a stable and efficient manner, wherein decomposition of the monomer and generation of polyacetal are suppressed.

[Means for solving problem] The method for producing a vinyl ether polymer containing a hydrocarbon group according to the present invention comprises the step of polymerizing vinyl ether represented by the following formula (1):

##STR00001## wherein R.sup.1 represents an aliphatic hydrocarbon group having 1 to 10 carbons or an alicyclic hydrocarbon group having 3 to 10 carbons,
in the presence of water as a polymerization solvent and an organic azo-based compound as a radical polymerization initiator, under pH of 6 or more.

METHOD FOR PRODUCING VINYL ETHER POLYMER CONTAINING HYDROCARBON GROUP BY RADICAL POLYMERIZATION

[Object] To provide a method for producing a vinyl ether polymer containing a hydrocarbon group in a stable and efficient manner, wherein decomposition of the monomer and generation of polyacetal are suppressed.

[Means for solving problem] The method for producing a vinyl ether polymer containing a hydrocarbon group according to the present invention comprises the step of polymerizing vinyl ether represented by the following formula (1):

##STR00001## wherein R.sup.1 represents an aliphatic hydrocarbon group having 1 to 10 carbons or an alicyclic hydrocarbon group having 3 to 10 carbons,
in the presence of water as a polymerization solvent and an organic azo-based compound as a radical polymerization initiator, under pH of 6 or more.

METHOD FOR PRODUCING VINYL ETHER POLYMER CONTAINING HYDROCARBON GROUP BY RADICAL POLYMERIZATION

[Object] To provide a method for producing a vinyl ether polymer containing a hydrocarbon group in a stable and efficient manner, wherein decomposition of the monomer and generation of polyacetal are suppressed.

[Means for solving problem] The method for producing a vinyl ether polymer containing a hydrocarbon group according to the present invention comprises the step of polymerizing vinyl ether represented by the following formula (1):

##STR00001## wherein R.sup.1 represents an aliphatic hydrocarbon group having 1 to 10 carbons or an alicyclic hydrocarbon group having 3 to 10 carbons,
in the presence of water as a polymerization solvent and an organic azo-based compound as a radical polymerization initiator, under pH of 6 or more.

POLYMERIZATION INITIATOR, CURABLE COMPOSITION, DENTAL MATERIAL, AND PREPARATION KIT FOR CURABLE COMPOSITION
20210130580 · 2021-05-06 · ·

Provided is a polymerization initiator, which has an excellent curing rate and is an alternative to a polymerization initiator system using a benzoyl peroxide-aromatic amine compound, a curable composition containing the polymerization initiator, a dental material and dental filler material containing the composition, and a kit for preparing the curable composition. The polymerization initiator contains one or more compounds (A) selected from the group consisting of a pyrazolidinedione compound and/or pyrazolidine(di)thione compound (A1), a salt (A2) of the compound (A1), and a malonate compound (A3).

COMPOSITIONS COMPRISING POLY(P-PHENYLENE) AND CARBON FIBERS PRODUCED THEREFROM
20210130987 · 2021-05-06 ·

The disclosure relates to a method of making carbon fiber, the method comprising pyrolyzing poly(p-phenylene) (PPP) fiber at a temperature sufficient to convert PPP fiber substantially to carbon fiber. The disclosure also relates to pre-PPP polymer, methods for making PPP fiber from pre-PPP polymer and, in turn, making carbon fiber from PPP fiber.

Method for producing polymer
10961332 · 2021-03-30 · ·

The present invention relates to a method of producing a polymer including: polymerizing a compound represented by the following formula (3); or copolymerizing the compound represented by the following formula (3) with a compound (6) having a reactive carbon-carbon double bond and differing from the compound represented by the following formula (3), in a presence of at least one compound selected from the group consisting of compounds represented by the following formula (1) and compounds represented by the following formula (2).

Polymerization photoinhibitor

Provided herein is technology relating to polymerization and producing polymers and particularly, but not exclusively, to methods, systems, and compositions for producing articles using three-dimensional printing and for improving control of polymerization using a polymerization photoinhibitor having fast back reaction kinetics such as hexaarylbiimidazole compounds and bridged hexaarylbiimidazole compounds.

Polymerization photoinhibitor

Provided herein is technology relating to polymerization and producing polymers and particularly, but not exclusively, to methods, systems, and compositions for producing articles using three-dimensional printing and for improving control of polymerization using a polymerization photoinhibitor having fast back reaction kinetics such as hexaarylbiimidazole compounds and bridged hexaarylbiimidazole compounds.

POSITIVE-TYPE PHOTOSENSITIVE RESIN COMPOSITION AND CURED FILM PREPARED THEREFROM
20200407510 · 2020-12-31 ·

The present invention relates to a positive-type photosensitive resin composition and a cured film prepared therefrom. The positive-type photosensitive resin composition introduces a multifunctional monomer into a positive-type photosensitive resin composition comprising a mixed binder in which a siloxane copolymer is added to an acrylic copolymer, whereby the penetration of a developer into the binder can be facilitated at the time of development of a pre-baked film to increase the solubility in the developer, thereby further enhancing the pattern developability and sensitivity. Further, a cured film prepared from the composition has excellent appearance characteristics without a rough surface of the film and a scum or the like at the bottom of the film during development.

Superabsorbent polymer and preparation method thereof

A superabsorbent polymer having high centrifuge retention capacity and absorption rate prepared by using a particular foam stabilizer and a polymerization initiator. The foam stabilizer includes a sucrose ester and a polyalkylene oxide, and polymerization initiator includes a photoinitiator and a cationic azo-based initiator.