A hot-melt adhesive comprising a thermoplastic resin and a first crystalline material, wherein when in differential scanning calorimetric measurement of the hot-melt adhesive, Tc (° C.) is a peak temperature of the highest peak of exothermic peaks observed in a temperature reduction process at 10° C./min following heating to 150° C. and Tm (° C.) is a peak temperature of the highest peak of endothermic peaks observed in a temperature increasing process at 10° C./min following the temperature reduction process, Tm-Tc is 20.0 to 70.0° C., and a tetrahydrofuran-soluble matter of the hot-melt adhesive has a weight-average molecular weight Mw, as measured by gel permeation chromatography, of 100,000 to 400,000.

Disclosed is a photocurable material composition having a cured product which has both deflection temperature under load of 40° C. or more and Charpy impact strength (with a notch) of 20 kJ/m.sup.2 or more after ultraviolet irradiation and the cured product thereof. The photocurable material composition comprises at least a monofunctional acrylate having a five-membered ring containing an ether bond and a polycarbonate resin soluble in the monofunctional acrylate, wherein the content of the monofunctional acrylate having a five-membered ring containing an ether bond is 18% by weight to 80% by weight and the content of the polycarbonate resin is 10% by weight to 40% by weight.

Disclosed is a photocurable material composition having a cured product which has both deflection temperature under load of 40° C. or more and Charpy impact strength (with a notch) of 20 kJ/m.sup.2 or more after ultraviolet irradiation and the cured product thereof. The photocurable material composition comprises at least a monofunctional acrylate having a five-membered ring containing an ether bond and a polycarbonate resin soluble in the monofunctional acrylate, wherein the content of the monofunctional acrylate having a five-membered ring containing an ether bond is 18% by weight to 80% by weight and the content of the polycarbonate resin is 10% by weight to 40% by weight.

A photocurable composition includes a compound having one (meth)acryloyl group in one molecule and not having a urethane bond and a photoradical polymerization initiator as essential components, and further includes a compound having one (meth)acryloyl group in one molecule and not having a urethane bond, a compound having a (meth)acryloyl group and a urethane bond, and a compound having another ethylenically unsaturated group as optional components, in which a viscosity of the photocurable composition at 25° C. is 1 Pa.Math.s to 100 Pa.Math.s. The photocurable composition is a material for forming a resin layer on at least a part of a side surface of a laminated electrode body in an all-solid-state battery.

A photocurable composition includes a compound having one (meth)acryloyl group in one molecule and not having a urethane bond and a photoradical polymerization initiator as essential components, and further includes a compound having one (meth)acryloyl group in one molecule and not having a urethane bond, a compound having a (meth)acryloyl group and a urethane bond, and a compound having another ethylenically unsaturated group as optional components, in which a viscosity of the photocurable composition at 25° C. is 1 Pa.Math.s to 100 Pa.Math.s. The photocurable composition is a material for forming a resin layer on at least a part of a side surface of a laminated electrode body in an all-solid-state battery.

Disclosed are compositions which include a polymer with a nucleophilic group and a 1,1-disubstituted alkene disposed on the polymer. Disclosed is a composition containing a polymer which includes a nucleophilic group. In addition, also disclosed are methods of making a composition including a polymer with a nucleophilic group and a 1,1-disubstituted alkene disposed on the polymer, methods of chain extending or cross linking a polymer with a nucleophilic group with a 1,1-disubstituted alkene and methods of polymerizing a 1,1-disubstituted alkene.

Disclosed are compositions which include a polymer with a nucleophilic group and a 1,1-disubstituted alkene disposed on the polymer. Disclosed is a composition containing a polymer which includes a nucleophilic group. In addition, also disclosed are methods of making a composition including a polymer with a nucleophilic group and a 1,1-disubstituted alkene disposed on the polymer, methods of chain extending or cross linking a polymer with a nucleophilic group with a 1,1-disubstituted alkene and methods of polymerizing a 1,1-disubstituted alkene.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a monomer having an aliphatic group containing at least 15 carbon atoms. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a packaging coated with the composition.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a monomer having an aliphatic group containing at least 15 carbon atoms. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a packaging coated with the composition.

The present invention refers to a hybrid photopolymer composition for additive manufacturing, —comprising 50-95% by weight of a free radically curable-component, farther comprising at least one (meth)acrylate monomer or oligomer, 5-49% by weight of a cationically curable component, further comprising a cycloaliphatic epoxide, an oxetane mixture, containing a monooxetane compound and a polyoxetane compound, and a thermoplastic polycaprolactone with a molecular weight of 20,000-100,000 g/mol, a free radical photoinitiator, a UV blocker, a cationic photoinitiator, optionally a cationic photosensitiser, and optionally a thermal initiator, wherein the percent by weight is based on the total weight of the photopolymer' composition. The invention also relates to the use of a photopolymer composition according to the present invention for producing a three-dimensional object through additive manufacturing and to a three-dimensional object obtained through additive manufacturing using the photopolymer composition—according the present invention.