Disclosed herein is a carbon nanodot-polyacrylic acid composite hydrogel including a polyacrylic acid-based gel matrix having carboxyl groups, and a plurality of fluorescent carbon nanodots having amino groups on surfaces thereof. The fluorescent carbon nanodots are formed by subjecting polyethylenimine and hydrochloric acid to a hydrothermal reaction, and are distributed in the polyacrylic acid-based gel matrix. The amino groups of the fluorescent carbon nanodots are covalently bonded with the carboxyl groups of the polyacrylic acid-based gel matrix. Also disclosed herein are a method for preparing and a formulation for forming a carbon nanodot-polyacrylic acid composite hydrogel.

Techniques regarding chemical compounds with antimicrobial functionality are provided. For example, one or more embodiments describe herein can comprise a monomer that can comprise a molecular backbone. The molecular backbone can comprise a bis(urea)guanidinium structure covalently bonded to a functional group, which can comprise a radical. Also, the monomer can have supramolecular assembly functionality.

The invention relates to the use of a composition as rheology control agent comprising (A) silicate and (B) a polyethylenimine comprising the structure (I), wherein R.sup.1 is formula (I), or part of the polyethylenimine, and wherein R.sup.2 is H or an organic group, R.sup.3 is H or an organic group, with the proviso that one of R.sup.2 or R.sup.3 is H and wherein the polyethyleneimine has a weight average molecular weight Mw in the range of 40000 to 300000 g/mol before the reaction with the epoxide compound.

##STR00001##

Disulfide-containing benzoxazine monomers of formula I

##STR00001##

Also a process for synthesizing a disulfide-containing benzoxazine monomer of formula I comprises the following steps consisting of providing a mixture comprising an amino disulfide compound:H.sub.2N—R—NH.sub.2, wherein R is as defined for the monomer of formula I, an aldehyde derivative; phenolic derivatives, stirring the mixture under a temperature of from 50° C. to 130° C. for 1 h to 48 h, for obtaining the monomer of formula I; wherein the respective stoichiometry of the amino disulfide compound: aldehyde derivative:phenolic derivatives is 1:4: x.sub.1+x.sub.2, with x.sub.1+x.sub.2=2 and 0<x.sub.1;x.sub.2<2. Also a process for preparing a polybenzoxazine derivative vitrimer comprising a polymerization of the benzoxazine monomer at temperatures within the range of from 100° C. to 250° C. for 1 h to 24 h, for obtaining the polybenzoxazine derivatives vitrimer. Also polybenzoxazine derivative vitrimers, presenting at least one of the following characteristics of Tg values of from 0° C. to 250° C.; and relaxation temperature values, above the Tg values, of from 0° C. to 250° C.

Provided is a polymer comprising a hydrolysable polymer backbone, the polymer backbone comprising (i) monomer units comprising a hydrophobic side chain; and (ii) monomer units comprising a cationic side chain; wherein the cationic side chain comprises a polyamine with at least one tertiary amine and only a single nucleophilic center, optionally at the terminus of the polyamine, as well as a method of preparing said polymer, and a method of delivering a nucleic acid and/or polypeptide to a cell using the polymer.

Benzoxazine compounds, methods of making them, polymers made therefrom and methods of polymerizing the benzoxazines. These renewable benzoxazine monomers and polymers that utilize the variety of building blocks found in renewable plant biomass, demonstrate excellent processability and large temperature windows for processing of resin systems.

Disclosed are compositions comprising a) an antimicrobial agent, which is selected from the group consisting of biocides containing halogen atoms and/or containing phenolic moieties, formic acid, chlorine dioxide, chlorine dioxide generating compounds, dialdehydes; components containing an antimicrobial metal such as antimicrobial silver, and b) a polyamine, especially a polyethylenimine. The polyamine is effective as a booster for the antimicrobial agent.

A curable composition containing more than 80% by weight of a blend of benzoxazines, wherein the blend includes (A) one or more multifunctional benzoxazines and (B) a liquid, non-halogenated monofunctional benzoxazine. This composition has been found to be stable at high temperatures, e.g. 180° C.-250° C., and suitable for making composite materials using conventional techniques such as prepregging and liquid resin infusion.

A composite conductive polymer, a preparation method thereof and application thereof are disclosed, wherein a mixed solution A is used in the preparation process of the composite conductive polymer, which comprises the following two components: (i) a strong oxidant selected from at least one of permanganate, persulfate, dichromate and perchlorate; (ii) an oxidizing agent containing a metal ion capable of being reduced to elementary substance. The preparation process is simple and easy to operate, with low cost and favorable environmental protection and the obtained composite conductive polymer containing metal in elementary form, has good film-forming property and the film thereof can completely cover the surface of the insulating substrate, with excellent electrical conductivity, which therefore can be widely used in electroplating materials and semiconductor materials and other fields.

The invention relates to a process for manufacturing wet strength resins, which process comprises a polyamide reactor (11) for amidation, an EHH reactor (12) for epihalohydrin addition, a maturing tank (15) for maturing, a ring-closure and cross-linking reactor (16) for polymerization, and in the process a reaction mixture containing at least EHH and at least polyaminoamide epihalohydrin adduct is manufactured. The process further comprises between the maturing tank (15) and the ring-closure and cross-linking reactor (16) a membrane unit (20) comprising a membrane by dividing the reaction mixture stream from the membrane unit (20) into two streams: a permeate stream (202) comprising un-reacted epi-halohydrin and a reject stream (201) comprising EHH/PAIM adduct guided to the ring-closure and cross-linking reactor (16).