Inorganic siloxane ladder polymers with metal-aza/thio crown complexes, and methods of making and using such siloxane ladder polymers are disclosed. The polymers described herein may exhibit self-healing properties, a low dielectric constant, and a low refractive index. These siloxane ladder polymers are anchored to transparent, high-refractive index (RI) metal nanoparticles, such as ZrO.sub.2, via aza/thio crown macromolecules. The siloxane ladder polymers may be considered as living polymer network since the polymer active chain ends may further undergo anionic polymerization.

Described is a production process for the preparation of an organic titanium derivative useful for the preparation of yellow inks for digital printing on ceramics, comprising the following steps: (i) mixing an organic and/or inorganic compound of titanium (IV) and a 1,3-diol of formula:

##STR00001## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently selected from H and a linear or branched C1-C6 alkyl radical, in the presence of at least an organic solvent immiscible with water and subsequent removal of reaction by-products; (ii) adding water to the reaction mixture in a H.sub.2O:Ti2 molar ratio and subsequent removal of unreacted water and reaction by-products; (iii) maturing the reaction mixture at a temperature of 180-200 C. for 16-50 hours.

Also described are the titanium derivative obtainable by means of the above-reported process, an ink that contains the derivative and a method of digital printing on ceramics that uses said ink.

The organic-inorganic composite of the present invention includes an organic compound having a carbonyl group, an inorganic compound containing a metal component, and a silver component. The ratio of the number of metal atoms in the inorganic compound to the number of carbon atoms in the organic compound is from 0.04 to 1.60, and the ratio of the number of silver atoms in the silver component to the number of carbon atoms in the organic compound is from 0.07 to 0.55. The organic-inorganic composite may include, for example, an inorganic compound having a metal matrix structure containing a metal M and oxygen, an organic compound having a carbonyl group, and silver ions. The carbonyl group is bonded to a side chain R.sup.1 of the organic compound and has an end group R.sup.2.

An organic-inorganic composite of the present invention includes metal oxide particles and an organic polymer compound including a monomer containing organic ligands and a vinyl-based monomer having organic ligands which are bonded to a polymer chain through covalent bonds and the organic polymer compound is bonded to the metal oxide particles by the organic ligands forming a complex with metal atoms on the surface of the metal oxide particles. According to the organic-inorganic composite, the metal oxide particles and the organic polymer compound containing the organic ligands can be chemically bonded, therefore, light emission characteristics such as light emission intensity or stabilization of light emission wavelength can be improved, and transparency and mechanical characteristics such as thermal stability or hardness can also be improved.

The embodiments described herein pertains to a new design method to produce copper, silver or gold based metal functional coordination polymers with excellent potential towards optoelectronic devices, gas storage and separation, optical sensors, and other applications.

Compositions, methods and processes for producing an electrically conductive metal-organic material is disclosed, wherein the material is based on a coordination polymer consisting of a plurality of ligands and metal ions, each coordinated with a ligand to impart conductivity to the material. Further provided are methods of deposition and use to produce conductive textiles, stretchable, flexible and transparent devices and surfaces. The electrically conductive metal-organic material may be used in a variety of fields including wearable electronics, sensors (gas, wearable, sweat, temperature, humidity), batteries, supercapacitors, electronic and pressure sensitive textiles/cotton/paper, electromagnetic shielding fabric, triboelectric nanogenerators, conductive paints/inks, antistatic coatings, conductive spray for flexible, transparent, and pressure sensitive glass/elastomers/plastics.

Parts made by additive manufacturing are often structural in nature, rather than having functional properties conveyed by a polymer or other component. Printed parts having piezoelectric properties may be formed using compositions comprising a plurality of piezoelectric particles non-covalently interacting with at least a portion of a polymer material via - bonding, hydrogen bonding, electrostatic interactions stronger than van der Waals interactions, or any combination thereof. The piezoelectric particles may be dispersed in the polymer material and remain substantially non-agglomerated when combined with the polymer material. The polymer material may comprise at least one thermoplastic polymer, optionally further including a polymer precursor. The compositions may define an extrudable material that is a composite having a form factor such as a composite filament, a composite pellet, a composite powder, or a composite paste. Additive manufacturing processes using the compositions may comprise forming a printed part by depositing the compositions layer-by-layer.

A population of nanocomposite particles including nanoparticles and poly (ethylene imine) (PEI) grafted thereto. In some embodiments there is no intervening layer between the nanoparticles and the PEI. Methods of making and using nanocomposite particles are also disclosed.

The disclosure relates to various compositions, related systems and articles, and methods of making and using the same. In some aspects, the disclosure relates to compositions containing a nanostructured organic compound, compositions containing an organic compound and a metal-organic framework embedded within the organic compound, and compositions containing an organic compound that is at least partially crystalline and a crystalline metal oxide distributed within the organic compound, as well as related methods of making (e.g., methods of depolymerizing polymers), methods of use (e.g., energy storage, contamination removal), articles (e.g., electrodes), and systems (e.g., energy storage systems, systems containing such energy storage systems) from the compositions of the disclosure. In some aspects, the disclosure relates to a composition that includes a silicon-containing material and a polymer made of imide monomers, as well as related systems and articles, and methods of making and using the same.

The present invention relates to a Zn-based organic coordination nanoparticles and a preparation method therefor, a photoresist composition, and use thereof. Zinc acetate, m-methylbenzoic acid and a nitrogen-containing organic ligand are mixed and stirred in an organic solvent, and are then subjected to a post-treatment to obtain a Zn-based organic coordination nanoparticles having a chemical general formula of [Zn.sub.mX.sub.n(CH.sub.3COO).sub.tY.sub.pH.sub.q].sub.r, wherein X is m-methylbenzoate; CH.sub.3COO represents acetate; Y is the nitrogen-containing organic ligand; r is the degree of polymerization; m, n, p, q, n and r are each independently selected from any integer of 1-20; and t is selected from any integer of 0-20. In the present invention, the Zn-based organic coordination nanoparticles are used as a film-forming agent of a photoresist, and compared with an existing photoresists, the prepared photoresist has lithographie properties of a high resolution, a high sensitivity and a low line roughness.