The present invention relates to new coating compositions for the preparation of functional surface coatings on various base material substrates. The coating compositions are based on a silazane-containing polymer and a non-polymeric phenolic compound comprising at least two and not more than four aromatic units in its molecular structure. The coating compositions provide improved physical and chemical surface properties and may be applied by user-friendly coating methods.

The present disclosure is directed to a vessel having a lumen defined at least in part by a wall, the wall having an interior surface facing the lumen, and the interior surface comprising a coating. The coating is configured to prevent the leaching of metal ions from the vessel wall into a fluid contained within the lumen and stored in contact with the coating. The vessels are used to store an aqueous drug product, typically an aqueous drug product containing an active agent and one or more excepients, such as a polysorbate stabilizer. The coated vessels are effective to reduce degradation of the active agent and/or one or more excipients, e.g. a polysorbate stabilizer.

The present disclosure is directed to a vessel having a lumen defined at least in part by a wall, the wall having an interior surface facing the lumen, and the interior surface comprising a coating. The coating is configured to prevent the leaching of metal ions from the vessel wall into a fluid contained within the lumen and stored in contact with the coating. The vessels are used to store an aqueous drug product, typically an aqueous drug product containing an active agent and one or more excepients, such as a polysorbate stabilizer. The coated vessels are effective to reduce degradation of the active agent and/or one or more excipients, e.g. a polysorbate stabilizer.

To provide a new silicon-containing polymer making it possible to form a cured film has features that its residual stress is small and crack resistance is high. A polycarbosilazane having particular cyclic structures.

To provide a siliceous film manufacturing composition that can fill a narrow and a high aspect ratio trench and can produce a thick siliceous film. [Means for Solution] The present invention provides a siliceous film manufacturing composition that comprises, (a) a block copolymer having a linear and/or cyclic polysilane backbone block with or more silicon atoms and a polycarbosilane backbone block with or more silicon atoms, and (b) a solvent.

A separator for a rechargeable lithium battery includes a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer is formed from a coating layer composition including an organosilazane compound, inorganic particles, an initiator, and a solvent, the coating layer includes a curable binder of the organosilazane compound and inorganic particles, the curable binder of the organosilazane compound includes a copolymer including a structural unit represented by Chemical Formula 1, a structural unit represented by Chemical Formula 2, and a structural unit represented by Chemical Formula 3, and a nitrogen (N) atom derived from Chemical Formula 1 is greater than about 0 at % and less than about 5 at % (atomic percent) in the coating layer, and a rechargeable lithium battery. Chemical Formula 1 to Chemical Formula 3 are as defined in the specification.

A separator for a rechargeable lithium battery includes a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer is formed from a coating layer composition including an organosilazane compound, inorganic particles, an initiator, and a solvent, the coating layer includes a curable binder of the organosilazane compound and inorganic particles, the curable binder of the organosilazane compound includes a copolymer including a structural unit represented by Chemical Formula 1, a structural unit represented by Chemical Formula 2, and a structural unit represented by Chemical Formula 3, and a nitrogen (N) atom derived from Chemical Formula 1 is greater than about 0 at % and less than about 5 at % (atomic percent) in the coating layer, and a rechargeable lithium battery. Chemical Formula 1 to Chemical Formula 3 are as defined in the specification.

A separator for a rechargeable lithium battery includes a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer is formed from a coating layer composition including an organosilazane compound, inorganic particles, an initiator, and a solvent, the coating layer includes a curable binder of the organosilazane compound and inorganic particles, the curable binder of the organosilazane compound includes a copolymer including a structural unit represented by Chemical Formula 1, a structural unit represented by Chemical Formula 2, and a structural unit represented by Chemical Formula 3, and a nitrogen (N) atom derived from Chemical Formula 1 is greater than about 0 at % and less than about 5 at % (atomic percent) in the coating layer, and a rechargeable lithium battery. Chemical Formula 1 to Chemical Formula 3 are as defined in the specification.

To provide an amorphous silicon forming composition, which has high affinity with a substrate, is excellent in filling properties, and is capable of forming a thick film. [Means for Solution] An amorphous silicon forming composition comprising: (a) a block copolymer comprising a linear and/or cyclic block A having a polysilane skeleton comprising 5 or more silicon and a block B having a polysilazane skeleton comprising 20 or more silicon, wherein at least one silicon in the block A and at least one silicon in the block B are connected by a single bond and/or a crosslinking group comprising silicon, and (b) a solvent.

To provide an amorphous silicon forming composition, which has high affinity with a substrate, is excellent in filling properties, and is capable of forming a thick film. [Means for Solution] An amorphous silicon forming composition comprising: (a) a block copolymer comprising a linear and/or cyclic block A having a polysilane skeleton comprising 5 or more silicon and a block B having a polysilazane skeleton comprising 20 or more silicon, wherein at least one silicon in the block A and at least one silicon in the block B are connected by a single bond and/or a crosslinking group comprising silicon, and (b) a solvent.