A plastic-to-oil plant for converting plastics into petrochemical products is disclosed. Operation shall be energy- and resource-efficient. To reach this aim, the inventions suggests a plastic-to-oil plant, having a cracking reactor for a pyrolysis reaction, wherein plastics, in particular polyolefins, are converted into at least gasified pyrolysis products and char.

A process for pyrolysis of a mixed plastic stream that contains polyvinyl chloride (PVC) is provided in which the chloride from PVC is removed from an initial melting reactor that melts the mixed plastic stream. Chloride is removed in a vapor stream from the initial melting reactor with additional chloride removed from addition of sorbents to the pyrolysis reactor and in adsorbent beds downstream of the pyrolysis reactor. The pyrolysis reactor has a configuration comprising two cylindrical ring structures, an inner cylindrical ring structure within an outer cylindrical ring structure wherein a circulation liquid supply stream enters said pyrolysis reactor tangentially relative to a ring edge of said two cylindrical ring structures and wherein solid particles move in a downward direction to a bottom of the pyrolysis reactor.

A process for producing one or more of benzene, toluene, or mixed xylenes may include combining one or more aromatic feed chemicals, one or more aromatic-based polymers, hydrodearylation catalyst, and hydrogen in a hydrodearylation unit to form a chemical product. The process may also include passing the chemical product out of the hydrodearylation unit, where the chemical product comprises one or more of benzene, toluene, and mixed xylenes. Additionally, a system for producing one or more of benzene, toluene, or mixed xylenes may include a mixing unit and a hydrodearylation unit. An aromatic feed stream and an aromatic-based polymer stream may be in fluid communication with a mixing unit. A mixing unit effluent stream may be in fluid communication between the mixing unit and the hydrodearylation unit. A chemical product stream may be in fluid communication with the hydrodearylation unit.

The present invention relates to a process for oiling essentially organic starting products with a higher molecular weight, in which hydrocarbons, preferably in liquid or semi-solid form, and a residual material with a high carbon content are obtained by the impact of high temperatures.

A process for upgrading a pyrolysis oil comprising treating the pyrolysis oil with an upgrading solution to provide a mixture comprising an extract phase and a raffinate phase, wherein the upgrading solution comprises a polar organic solvent, and wherein the pyrolysis oil is a derived from the pyrolysis of plastic or rubber, or a combination thereof, and an upgraded pyrolysis oil prepared by said process.

Systems and methods are provided for integration of a reactor for polyolefin pyrolysis with the effluent processing train for a steam cracker. The polyolefins can correspond to, for example, polyolefins in plastic waste. Integrating a process for polyolefin pyrolysis with a steam cracker processing train can allow a mixture of polymers to be converted to monomer units while reducing or minimizing costs and/or equipment footprint. This can allow for direct conversion of polyolefins to the light olefin monomers in high yield while significantly lowering capital and energy usage due to integration with a steam cracking process train. The integration can be enabled in part by selecting feeds with appropriate mixtures of various polymer types and/or by limiting the volume of the plastic waste pyrolysis product relative to the volume from the steam cracker(s) in the steam cracking process train. By selecting plastic waste and/or other polyolefin sources with an appropriate mixture of polyolefins as the feedstock, the resulting polyolefin pyrolysis product can be separated in a steam cracking process train to produce separate fractions for various polymer grade small olefin products.

A device and process for the conversion of aromatic compounds, includes/uses: a unit for the separation of the xylenes suitable for treating a cut comprising xylenes and ethylbenzene and producing an extract comprising para-xylene and a raffinate; an isomerization unit suitable for treating the raffinate and producing an isomerate enriched in para-xylene which is sent to a fractionation train; a pyrolysis unit suitable for treating biomass, producing a pyrolysis effluent feeding, at least partially, the feedstock, and producing a pyrolysis gas comprising CO and H.sub.2; a Fischer-Tropsch synthesis reaction section suitable for treating, at least in part, the pyrolysis gas, producing a synthesis effluent sent, at least in part, to the pyrolysis unit.

A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.

A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More specifically cracking the cracker feedstock in said cracker furnace to provide an olefin-containing effluent stream; wherein the hydrocarbon composition is predominantly ethane.

Disclosed herein are methods for producing hydrocarbons from a subterranean reservoir that is penetrated by an injection well and a production well. The methods comprise operating the injection well under a set of injection parameters and operating the production well under a set of production parameters to produce a production fluid that has an API gravity that changes over time (ΔAPI) as the method is advanced towards an ultimate recovery factor (RF.sub.o,u) for the reservoir. The methods further comprises modulating the injection parameters, the production parameters, or a combination thereof to decrease or increase the API gravity of the production fluid depending on whether ΔAPI and RF.sub.o,u satisfy a set of requirements as disclosed herein.