C10G1/002

Circular economy for plastic waste to polypropylene via oil refinery with filtering and metal oxide treatment of pyrolysis oil
11359147 · 2022-06-14 · ·

Provided in one embodiment is a continuous process for converting waste plastic comprising polyethylene and/or polypropylene into recycle for polypropylene polymerization. The process comprises selecting waste plastics containing polyethylene, polypropylene, or a mixture thereof, and passing the waste plastics through a pyrolysis reactor to thermally crack at least a portion of the polyolefin waste and produce a pyrolyzed effluent. The pyrolyzed effluent is separated into offgas, a pyrolysis oil comprising a naphtha, diesel and heavy fractions, and char. The pyrolysis oil, or at least a fraction, is passed to a filtration/metal oxide treatment, with the treated product passed to a refinery FCC unit. A liquid petroleum gas C.sub.3 olefin/paraffin mixture fraction is recovered from the FCC unit, as well as a C.sub.4 olefin/paraffin mixture fraction. The C.sub.3 olefin fraction can be passed to a propylene polymerization reactor, and the C.sub.3 paraffin passed to a dehydrogenation unit to produce propylene for further polymerization.

RECOVERY OF ALIPHATIC HYDROCARBONS

The invention relates to a process for the recovery of aliphatic hydrocarbons from a liquid hydrocarbon feedstock stream, which comprises aliphatic hydrocarbons and additionally comprises aromatic hydrocarbons and/or polar components, said process comprising the steps of: feeding the liquid hydrocarbon feedstock stream to a first column; feeding a first solvent stream which comprises an organic solvent to the first column at a position which is higher than the position at which the liquid hydrocarbon feedstock stream is fed; contacting at least a portion of the liquid hydrocarbon feedstock stream with at least a portion of the first solvent stream; and recovering at least a portion of the aliphatic hydrocarbons by liquid-liquid extraction of aromatic hydrocarbons and/or polar components with organic solvent, resulting in a stream comprising recovered aliphatic hydrocarbons and optionally organic solvent and a bottom stream from the first column comprising organic solvent and aromatic hydrocarbons and/or polar components.

MULTIFUNCTIONAL SHIP FOR COLLECTING AND RECYCLING OCEAN WASTE AND MANAGEMENT SYSTEM THEREOF
20220177082 · 2022-06-09 ·

A multifunctional ship for the collection and recycling of ocean debris and the system thereof may include a hull; a detection device provided on the hull to detect ocean debris floating on the sea or deposited on the seabed; a collection device installed on the hull to collect the ocean debris detected by the detection device; a sorting device installed on the hull to sort the ocean debris collected by the collection device; a compressing device installed on the hull to compress the sorted ocean debris to compress and remove moisture and reduce the volume; a waste plastic recycling device installed on the hull to produce recycled oil by thermally decomposing the waste plastic compressed in the compressing device; a storage tank installed at the bottom of the hull to store the recycled oil produced; and a purifier for purifying wastewater generated in the process of producing recycled oil.

TREATING AND STEAM CRACKING A COMBINATION OF PLASTIC-DERIVED OIL AND USED LUBRICATING OILS TO PRODUCE HIGH-VALUE CHEMICALS
20220177785 · 2022-06-09 ·

Systems and methods for producing one or more olefins using waste plastics and used lubricating oil are disclosed. Mixed waste plastic is processed in a pyrolysis unit to produce plastic derived oil. The plastic derived oil is subsequently blended with used lubricating oil to form a mixture. The mixture is then separated into (1) a light-end stream comprising C1 to C8 hydrocarbons and (2) a heavy hydrocarbon feed stream. The heavy hydrocarbon feed stream is then processed to produce a steam cracking feedstock stream. The light end-stream and/or the steam cracking feedstock stream are then flowed into a cracking unit to produce one or more olefins.

GASIFICATION OF TORREFIED TEXTILES AND FOSSIL FUELS

Recycle content pyoil is cracked in a cracker furnace to make olefins and the coil outlet temperature of the r-pyoil fed coils can he lowered by adding r-pyoil to the cracker feedstock, or alternatively, the coil outlet temperature of the r-pyoil fed tubes can rise if the mass flow rates of the combined cracker stream containing r-pyoil are kept the same or lowered. Further, increasing the hydrocarbon mass flow rate by addition of r-pyoil can be achieved to also increase the output of ethylene and propylene in the cracker effluent. The cracker furnace can accept ethane and/or propane feedstocks in vapor form along with a liquid and/or vapor feed of r-pyoil.

Processes for converting organic material-containing feeds via pyrolysis

Processes for converting an organic-material-containing feed comprising contacting the feed with a plurality of fluidized hot particles in a pyrolysis zone to product a first pyrolysis effluent, optionally contacting the first pyrolysis effluent with a quenching stream to impart additional pyrolysis of organic materials contained in the quenching stream, separating at least a portion of the particles and feeding them to a combustion zone where the particles are heated to an elevated temperature, optionally contacting the combustion zone effluent with a second organic-material-containing stream to produce, e.g., syngas, and feeding at least a portion of the heated particles to the pyrolysis zone.

CO-PROCESSING OF BIOMASS OIL IN COKER

Systems and methods are provided for co-processing of biomass oil with mineral coker feeds in a coking environment. The coking can correspond to any convenient type of coking, such as delayed coking or fluidized coking. The biomass oil can correspond to biomass oil with a molar ratio of oxygen to carbon of 0.24 or less on a dry basis. Such types of biomass oil can be formed from pyrolysis methods such as hydrothermal pyrolysis, and are in contrast to biomass oils formed from pyrolysis methods such as fast pyrolysis. By using a biomass oil with a molar ratio of oxygen to carbon of 0.24 or less, improved yields of light coker gas oil can be achieved in conjunction with a reduction in the yield of heavy coker gas oil.

SYSTEM AND PROCESS FOR PRODUCING DILUENT FROM DILBIT, TRANSPORTATION, AND TREATMENT OF HEAVY OIL

A process for producing diluent for use in a hydrocarbon recovery process includes heating a dilbit feed stream comprising hydrocarbons produced from a hydrocarbon reservoir and an added diluent, to a temperature of 350° C. or less, fractionating the dilbit feed stream after heating to produce a light fraction and a heavy fraction, the light fraction comprising the diluent, additional light hydrocarbons, and sour water, separating the sour water from a remainder of the light fraction, and stabilizing the remainder of the light fraction to provide recovered diluent and cooling the recovered diluent. A volume of the recovered diluent is greater than a volume of the added diluent.

WASTE TIRE-DERIVED ASPHALT MODIFIER
20230272220 · 2023-08-31 ·

Asphalt binders are modified using fractional products from waste tire pyrolysis, using an initial step of i) at least partially pyrolyzing, separately from such asphaltic binder, whole rubber articles or size-reduced rubber particles to provide one or more pyrolyzed rubber fractions including a pyrolyzed oil fraction having a selected minimum initial boiling point or flash point, and ii) removing some or all polycyclic aromatic hydrocarbon (PAH) compounds from such pyrolyzed oil fraction to provide a reduced-PAH and preferably translucent pyrolyzed oil fraction that may be combined with an asphaltic binder to provide a modified asphalt composition.

PROCESS FOR THE PREPARATION OF AROMATICS FROM WASTE PLASTIC FEEDSTOCKS

The present invention relates to a process for the production of aromatics from waste plastics feedstocks comprising the steps in this order of: (a) providing a hydrocarbon stream A obtained by hydrotreatment of pyrolysis oil produced from a waste plastics feedstock; (b) optionally providing a hydrocarbon stream B; (c) supplying a feed C comprising a fraction of the hydrocarbon stream A and optionally a fraction of the hydrocarbon stream B to a thermal cracker furnace comprising cracking coil(s); (d) performing a thermal cracking operation in the presence of steam to obtain a cracked hydrocarbon stream D; (e) supplying the cracked hydrocarbon stream D to one or more separation units; (f) performing a separation operation to obtain different streams comprising benzene, toluene, styrene, ethylbenzene and xylenes; wherein in step (d): ⋅ the coil outlet temperature is ≥800 and ≤850° C., preferably ≥805 and ≤835° C.; and ⋅ the weight ratio of steam to feed C is >0.3 and <0.8, preferably >0.3 and <0.5. Such process allows for optimisation of the quantity of waste plastic material that finds its way back into products that are produced as outcome of the process. The higher that quantity is, i.e. the higher the quantity of chemical building blocks that are present in the waste plastic material that are converted to the produced products, the better the sustainability footprint of the process is. The process allows for circular utilisation of plastics.