Provided are a coating film-forming composition for forming a coating film on a metal surface that exhibits excellent adhesiveness between a metal and a resin, and a surface-treated metal member having a coating film formed by using the composition. The coating film-forming composition is a solution containing a silane coupling agent having an amino group, a metallic ion and a halide ion. The metallic ion is preferably a copper ion, and a copper ion concentration in the solution is preferably 0.1 to 60 mM. The amount of Si based on the amount of Cu in the solution is preferably 30 or less, in terms of molar ratio. The pH of the solution is preferably 2.8 to 6.2.

Disclosed is a surface-treatment solution for producing a zinc or zinc alloy coated steel sheet with a surface-coating layer that does not contain a chromium compound in the surface-coating layer and that is excellent in all of heat discoloration resistance, heat cracking resistance, planar part anti-corrosion property, corrosion resistance after alkali degreasing, blackening resistance, stack blackening resistance, anti-water stain property, solvent resistance, perspiration resistance, coating adhesion property, and storage stability. The disclosed surface-treatment solution contains a glycidyl group-containing silane coupling agent (A), a tetraalkoxysilane (B), a zirconium carbonate compound (C), and an anionic polyurethane resin (D) having a glass transition temperature (Tg) of 80° C. to 130° C., a vanadium compound (E), a molybdic acid compound (F), and water, the surface-treatment solution having a pH of 8.0 to 10.0, and the amount of each component satisfying a predetermined relationship.

The present invention relates to a composition comprising —a specific binder containing at least one cocondensate based on at least one ω-glycidyloxyalkylalkoxysilane and a bis(alkoxyalkylsilyl)amine, —water, —alcohol in an amount of less than 3% by weight, based on the composition, —at least one addition selected from the group consisting of particulate metals, metal alloys and metal compounds and —optionally at least one additive, where the pH of the composition is from 1 to 14 and the dry residue of the binder is from 1 to 50% by weight, based on the binder used, a process for the production thereof and also the use thereof for coatings, in particular for the protection of metals against corrosion.

An apparatus for the implementation of a process for the continuous manufacturing of steel strips for packaging coated with a passivation layer is provided. An apparatus contains a transfer roller; a coating roller contacting the transfer roller, a surface of the coating roller having a plurality of hexagonally shaped cells with a line count being from 50 to 200 lines per centimeter and a volume being from 5.Math.10.sup.−6 to 10.Math.10.sup.−6 m.sup.3 per square meter of the coating roller surface; and a tank containing an aqueous passivation solution, the tank providing the aqueous passivation solution to the coating roller.

A method to treat the magnesium surface to manufacture the metallic assembly with the polymer and magnesium to have excellent bonding strength is disclosed. As a method to treat the magnesium surface for the bonded coupling of the mixture of the polymer and magnesium, this is a method including, (a) an etching step, wherein the magnesium surface is treated with an acidic solution; (b) a first surface treatment step, wherein the magnesium surface is treated with ultrasonic waves; (c) a second surface treatment step, wherein the magnesium surface is treated with an acidic solution; (d) a first silane coupling processing step, wherein the magnesium surface is treated with ultrasonic waves; (e) a surface activation treatment step, wherein the magnesium surface is treated with acidic solution; and (f) a second silane coupling processing step, wherein the magnesium surface is treated with ultrasonic waves.

The invention relates generally to liquid-repellent coatings, and in particular, to porous liquid-repellent coatings, a method of preparing the porous liquid-repellent coatings, and a method of characterizing a porous surface for the liquid-repellent coatings. The invention further relates to a porous liquid-repellent coating comprising a porous layer of a transition metal oxide and/or hydroxide and a layer of a liquid-repellent compound deposited onto the porous layer of the transition metal oxide and/or hydroxide, wherein the porous layer of the transition metal oxide and/or hydroxide is comprised of a plurality of surface pores of varying angles with an average angle that is re-entrant.

Described herein are compounds for use in coating compositions and methods of using the same. Also described herein is a method of treating metal products (e.g., aluminum alloy products), including applying the coating composition to at least one surface of the metal product. Further described herein is a joined structure, including the coated aluminum alloy product and another metal or alloy. The coating compositions enhance the bond performance of the joined structures.

There is provided a more versatile technique that is useful for enhancing the sintering delay property of a metal powder. A metal powder surface-treated with at least one coupling agent comprising Si, Ti, Al or Zr, wherein a total adhesion amount of Si, Ti, Al and Zr is 200 to 10,000 μg with respect to 1 g of the surface-treated metal powder, wherein a 1% by mass aqueous solution of the coupling agent indicates a pH of 7 or less, and wherein a sintering starting temperature is 500° C. or higher.

Provided is a solution composition for steel sheet surface treatment, comprising 30 wt % to 60 wt % of a trivalent chromium compound containing chromium phosphate (A) and chromium nitrate (B); 0.2 wt % to 0.4 wt % of a rust-inhibiting and corrosion-resisting agent; 0.1 wt % to 0.3 wt % of a molybdenum-based compound; 5 wt % to 10 wt % of a water-soluble cationic urethane resin; 0.5 wt % to 2.0 wt % of a silane coupling agent; and 27.3 wt % to 64.2 wt % of water, a zinc-based plated steel sheet surface-treated with the same, and a manufacturing method therefor, the zinc-based plated steel sheet surface-treated with the solution composition for steel sheet surface treatment containing trivalent chromium may have an excellent effect on corrosion resistance, blackening resistance, fingerprint resistance, oil resistance, and alkali resistance.

Described herein is an improved process for an anticorrosion pretreatment of a metallic surface including steel, galvanized steel, aluminum, magnesium and/or a zinc-magnesium alloy, wherein the metallic surface is brought into contact with an aqueous composition A including a) from 0.01 to 0.5 g/l of a copolymer and the metallic surface is brought into contact with an acidic aqueous composition B including b1) a compound selected from the group consisting of titanium, zirconium and hafnium compounds, wherein the metallic surface is brought into contact i) firstly with the composition A and then with the composition B, ii) firstly with the composition B and then with the composition A and/or iii) simultaneously with the composition A and the composition B. Also described herein is a corresponding aqueous composition A, an aqueous concentrate for producing this composition, a correspondingly coated metallic surface and a method of using a correspondingly coated metallic substrate.