The invention relates to a process for coating metallic surfaces with a composition containing silane/silanol/siloxane/polysiloxane, wherein, in addition to a) at least one compound selected from silanes, silanols, siloxanes and polysiloxanes, b) at least one compound containing titanium, hafnium, zirconium, aluminium and/or boron, and c) at least one type of cation selected from cations of metals of subgroups 1 to 3 and 5 to 8, including lanthanides, and of main group 2 of the periodic table of the elements, and/or at least one corresponding compound,
the composition contains at least one substance d) selected from: d.sub.1) silicon-free compounds having at least one amino, urea and/or ureido group in each case, d.sub.2) anions of nitrite and/or compounds having at least one nitro group, d.sub.3) compounds based on peroxide, and d.sub.4) phosphorus-containing compounds, anions of at least one phosphate and/or anions of at least one phosphonate, as well as e) water, and f) optionally also at least one organic solvent. The invention further relates to corresponding aqueous compositions.

Described herein is a method for treatment of a metallic surface, including the step of contacting the metallic surface with an acidic aqueous composition. Also described herein is an acidic aqueous composition used in the method for treatment, a master batch to produce such acidic aqueous composition, a method of using the acidic aqueous composition to treat metallic surfaces and substrates including the thus treated metallic surfaces.

A housing for a spark plug. The housing includes a bore along the longitudinal axis X of the housing, as the result of which the housing has an outer side and an inner side, and an electroplated or chemically applied nickel-containing protective layer situated on at least one portion of the outer side of the housing and a sealing layer situated on the nickel-containing protective layer. The sealing layer contains silicon. A first intermediate layer is applied between the housing and the nickel-containing protective layer and/or a second intermediate layer is applied between the nickel-containing protective layer and the sealing layer and/or a cover layer is applied on the sealing layer. The sealing layer may be free of chromium.

Devices, systems and techniques are described for producing and implementing articles and materials having nanoscale and microscale structures that exhibit superhydrophobic, superoleophobic or omniphobic surface properties and other enhanced properties. In one aspect, a surface nanostructure can be formed by adding a silicon-containing buffer layer such as silicon, silicon oxide or silicon nitride layer, followed by metal film deposition and heating to convert the metal film into balled-up, discrete islands to form an etch mask. The buffer layer can be etched using the etch mask to create an array of pillar structures underneath the etch mask, in which the pillar structures have a shape that includes cylinders, negatively tapered rods, or cones and are vertically aligned. In another aspect, a method of fabricating microscale or nanoscale polymer or metal structures on a substrate is made by photolithography and/or nano imprinting lithography.

A coating composition and a method is used to coat metallic substrates for corrosion resistance. The coating composition includes acid, metal acetate, organosilane and water. The method includes steps of depositing the composition on an aluminum or aluminum alloy substrate and allowing the composition to dry to form a sol-gel coating on the substrate.

A process for anticorrosion treatment of a metallic surface, including bringing the surface into successive contact with the an alkaline or acidic cleaner composition, a first rinsing composition, optionally a second rinsing composition, an acidic conversion composition, optionally a third rinsing composition, and a composition including a (meth)acrylate- and/or epoxide-based cathodic electrophoretic coating. At least one of the compositions includes at least one compound of the formula R.sup.1O—(CH.sub.2).sub.x—Z—(CH.sub.2).sub.y—OR.sup.2. R.sup.1 and R.sup.2 are each, independently of one another, H or an HO—(CH.sub.2).sub.w— group with w≥2. X and y are each, independently of one another, from 1 to 4 and Z is an S atom or a C—C triple bond. An aqueous composition for reducing corrosive removal of material in anticorrosion treatment of metallic surfaces is disclosed.

A method of forming a corrosion-resistant ceramic coating on a metallic substrate, the method comprising providing a passivation layer on a surface of the metallic substrate by electrochemical passivation of the metallic substrate under a first electrical current and using a first electrically conducting solution; and providing the corrosion-resistant ceramic coating on an outermost surface of the metallic substrate, the outermost surface in use adapted to be exposed to a corrosive environment, by plasma electrolytic oxidation of the metallic substrate with the passivation layer, in a second electrically conducting solution and under a second electrical current having a discharge voltage. The first and the second electrically conducting solutions comprise a tetrafluoroborate compound.

A composition for a stainless coating according to the present disclosure includes a sodium silicate, a lithium silicate, a polysiloxane, ethanol, and a residual solvent. The composition may be uniformly and smoothly coated on a curved, stainless steel surface, cleaning may be easier, and yellowing may be reduced or prevented.

Invention relates to corrosion-inhibiting compositions and the process of using said compositions to protect metal from corrosion. The compositions comprise of sulfonates, a carboxylic-sulfonic acid metal complex, antioxidants, fluorinated copolymers, hydrophobic silanes and siloxane additives and solvent.

This disclosure relates to a method for obtaining superhydrophobic corrosion-resistant coatings. State-of-the-art approaches involve etching methods with elevated temperatures and/or longer duration which are complex and use high concentration of combination of acids, alkali, and salt solutions in etching process to obtain a roughness which makes it difficult to handle usage of chemicals and controlling process. The method of the present disclosure has addressed this issue by selection of optimum concentrations of combinations of one or more type of acids, oxidizing agents which are safe, easy to handle and provide better control over the process. The method of the present disclosure is easy, inexpensive, and environmentally friendly. The superhydrophobic corrosion-resistant coatings possess contact angles greater than 151° and coating efficiency more than 85 percent arrived at by using corrosion currents from polarization studies.