A method for the formation of tantalum carbides on a graphite substrate includes the steps of: (a) adding an organic tantalum compound, a chelating agent, a pre-polymer to an organic solvent to form a tantalum polymeric solution; (b) subjecting a graphite substrate with the tantalum polymeric solution to a curing process to form a polymeric tantalum film on the graphite substrate; and (c) subjecting the polymeric tantalum film on the graphite substrate in an oven to a pyrolytic reaction in the presence of a protective gas to obtain a protective tantalum carbide on the graphite substrate.

The disclosure provides for methods of oxidizing carbide anions, or negative ions, from salt like carbides at temperatures from about 150° C. to about 750° C. In another aspect, the disclosure provides for reactions with intermediate transition metal carbides. In yet another aspect, the disclosure provides for a system of reactions where salt-like carbide anions and intermediate carbide anions are oxidized to produce pure carbon of various allotropes.

The disclosure provides for methods of oxidizing carbide anions, or negative ions, from salt like carbides at temperatures from about 150° C. to about 750° C. In another aspect, the disclosure provides for reactions with intermediate transition metal carbides. In yet another aspect, the disclosure provides for a system of reactions where salt-like carbide anions and intermediate carbide anions are oxidized to produce pure carbon of various allotropes.

This invention describes a method and apparatus for the capture, storage and release of carbon dioxide for use in the horticulture industry, the method including reduction of a transition metal oxide to form a transition metal and carbon dioxide; carburization or partial carburization of the transition metal to form metal carbide; carbonation of an alkaline metal oxide or alkaline earth metal oxide to form an alkaline metal carbonate or alkaline earth metal carbonate; contacting the metal carbide with air to produce a transition metal oxide and carbon dioxide; and calcining the alkaline metal carbonate or alkaline earth metal carbonate to form carbon dioxide and alkaline metal oxide or alkaline earth metal oxide. Also described is a sorbent material for use in the method and apparatus of the invention.

This invention describes a method and apparatus for the capture, storage and release of carbon dioxide for use in the horticulture industry, the method including reduction of a transition metal oxide to form a transition metal and carbon dioxide; carburization or partial carburization of the transition metal to form metal carbide; carbonation of an alkaline metal oxide or alkaline earth metal oxide to form an alkaline metal carbonate or alkaline earth metal carbonate; contacting the metal carbide with air to produce a transition metal oxide and carbon dioxide; and calcining the alkaline metal carbonate or alkaline earth metal carbonate to form carbon dioxide and alkaline metal oxide or alkaline earth metal oxide. Also described is a sorbent material for use in the method and apparatus of the invention.

A method of manufacturing a tantalum carbide material of the present invention includes heating a tantalum material (1) interposed between a pair of graphite guide members (2 and 3) under an atmosphere of a carbon source-containing gas (4) at 1,500° C. or higher for 0.5 hours or longer.

A method of manufacturing a tantalum carbide material of the present invention includes heating a tantalum material (1) interposed between a pair of graphite guide members (2 and 3) under an atmosphere of a carbon source-containing gas (4) at 1,500° C. or higher for 0.5 hours or longer.

A method for the formation of tantalum carbides on a graphite substrate includes the steps of: (a) adding an organic tantalum compound, a chelating agent, a pre-polymer to an organic solvent to form a tantalum polymeric solution; (b) subjecting a graphite substrate with the tantalum polymeric solution to a curing process to form a polymeric tantalum film on the graphite substrate; and (c) subjecting the polymeric tantalum film on the graphite substrate in an oven to a pyrolytic reaction in the presence of a protective gas to obtain a protective tantalum carbide on the graphite substrate.

The invention generally relates to electrochemically active structures and methods of making thereof. More specifically, the invention relates to electrochemically active structure comprising a crystalline electride comprising a nitride or carbide of at least one of: an alkaline earth metal, a transition metal, a lanthanide metal, or a combination thereof, wherein the electride has a lattice capable of intercalating at least one ion, thereby releasing at least one electron into an external circuit; and wherein a change in lattice volume of the electride upon intercalating the at least one ion is less than about 40%. Further, methods of making these electrochemically active structures are disclosed. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

The invention generally relates to electrochemically active structures and methods of making thereof. More specifically, the invention relates to electrochemically active structure comprising a crystalline electride comprising a nitride or carbide of at least one of: an alkaline earth metal, a transition metal, a lanthanide metal, or a combination thereof, wherein the electride has a lattice capable of intercalating at least one ion, thereby releasing at least one electron into an external circuit; and wherein a change in lattice volume of the electride upon intercalating the at least one ion is less than about 40%. Further, methods of making these electrochemically active structures are disclosed. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.