A high-temperature fuel cell system includes a reformer that reforms a hydrocarbon-based raw fuel to generate a reformed gas containing hydrogen, a fuel cell that generates power by using the reformed gas and an oxidant gas, and a burner that heats the reformer. The burner includes an anode-off-gas gathering portion that has an anode-off-gas ejection hole and at which an anode off-gas discharged from an anode of the fuel cell gathers. The anode-off-gas gathering portion surrounds a first cathode-off-gas passing area through which a cathode off-gas discharged from a cathode of the fuel cell passes. The anode-off-gas ejection hole is formed such that the anode off-gas ejected upward from the anode-off-gas ejection hole approaches the cathode off-gas passing upward through the first cathode-off-gas passing area. The anode off-gas ejected from the anode-off-gas ejection hole and the cathode off-gas that has passed through the first cathode-off-gas passing area are burned.

A high-temperature fuel cell system includes a fuel cell that includes an anode and a cathode and that generates power by using a fuel gas and an oxidant gas, a fuel-gas path along which the fuel gas flows, an oxidant-gas path along which the oxidant gas flows, an anode-off-gas path along which an anode off-gas flows, a cathode-off-gas path along which a cathode off-gas flows, a combustion space in communication with the anode-off-gas path and the cathode-off-gas path and in which the anode off-gas and the cathode off-gas are burned, a flue-gas path along which a flue gas flows, a cathode-off-gas branch portion disposed on the cathode-off-gas path between the combustion space and the cathode and at which some of the cathode off-gas is branched from the cathode-off-gas path, and a first heat exchanger that enables heat exchange between the oxidant gas, the flue gas, and the cathode off-gas.

The invention relates to petroleum sludge or other wastes recycle treatment system, which comprises a pre-treatment operation facility for a treated matter to be treated as a raw material. A feeding unit is arranged to feed the raw material into at least one gasification reactor with a push rod or a screw for pyrolysis gasification. The upper half of the at least one gasification reactor is provided with a syngas collecting pipe which can be connected with a gas collecting pump, and the lower half is provided with a liquid petroleum output pipe and an ash residue outlet, in which the ash residue outlet can be provided with a spiral pipe to draw the ash residue out. The petroleum sludge and other wastes in a dense fluid state are transported from a raw material tank to the at least one gasification reactor end which is bent upward through at least one pipe body, and the feeding mode of pyrolysis gasification of the raw material from below to upper of the gasification reactor is adopted. The top of the at least one gasification reactor is provided with a syngas collecting pipe, and the other side is provided with an ash residue accumulation chamber. The ash residue can be centralized and discharged through the lower buffer chamber and the slag discharge chamber, so as to convert the petroleum sludge or other wastes into more energy-efficient syngas providing human beings as users of electric or thermal energy.

The present specification discloses a membrane reactor comprising a reaction region; a permeate region; and a composite membrane disposed at a boundary of the reaction region and the permeate region, wherein the reaction region comprises a bed filled with a catalyst for dehydrogenation reaction, wherein the composite membrane comprises a support layer including a metal with a body-centered-cubic (BCC) crystal structure, and a catalyst layer including a palladium (Pd) or a palladium alloy formed onto the support layer, wherein ammonia (NH.sub.3) is supplied to the reaction region, the ammonia is converted into hydrogen (H.sub.2) by the dehydrogenation reaction in the presence of the catalyst for dehydrogenation reaction, and the hydrogen permeates the composite membrane and is emitted from the membrane reactor through the permeate region.

The disclosure provides a system and method for synthesizing ultra-pure hydrogen from biomass waste. The present invention comprises a gasifier, an oils and tars filter, a steam generator, a water gas shift reactor (“WGS”), a heat-exchange two-phase water separator, a scrubber, a hydrogen separator, and fluid conduits in fluid communication with the various system components, which together convert hydrocarbon-based biomass, e.g., woodchips, into ultra-pure hydrogen gas. Fluid conduits connect the gasifier and the steam generator, separately, to the WGS, the WGS to the two-phase separator, the two-phase separator to the scrubber, and the scrubber to the hydrogen separator, which further comprises an outlet port through which hydrogen gas may flow free of carbon monoxide. The hydrogen may flow to a device that utilizes hydrogen to generate energy, such as a hydrogen fuel cell or to an internal combustion engine.

A SOFC system for producing a refined carbon dioxide product, electrical power, and a compressed hydrogen product is presented. The system can include a hydrodesulfurization system, a steam reformer, a water-gas shift reactor system, a hydrogen purification system, a hydrogen compression and storage system, a pre-reformer, and a CO2 purification and liquidification system.

An apparatus of power generation is provided. The apparatus uses a stack of dense solid oxide fuel cells (SOFC). The exhaust gas generated by a burner of the apparatus enters into the SOFC stack for heating. At the same time, the SOFC stack is heated by the thermal radiation and heat transfer of the burner as well as the thermal convection of gases between the anode and the cathode. Thus, the SOFC stack is heated to reach an operating temperature for generating power without any additional electroheat device. The present invention has a simple structure, flexible operation. Moreover, it increased efficiency, reduced pollutant emission with lowered costs of equipment and operation.

A method of generating electricity with a fuel cell includes a phase in which the cell is primed; and a phase in which the cell functions at a stable rate, during which the cell, fed with a hydrogenated gas, generates electricity and heat. In order to prime the cell, it is fed with a hydrogenated gas including at least 70 vol. % hydrogen, generated by self-sustaining combustion of at least one hydrogenated gas-generating solid pyrotechnic charge; and while it is operating at a stable rate, the cell is fed with a hydrogenated gas containing at least 85 vol. % hydrogen, generated by thermal decomposition of at least one hydrogenated gas-generating solid pyrotechnic charge; a portion of the heat produced by the operating cell being transferred to the at least one solid charge in order to start and maintain the thermal decomposition thereof.

Systems and methods are provided integrating an annular pre-reformer as part of an anode recuperator of a fuel cell system.

Integrated liquid fuel catalytic partial oxidation (CPOX) reformer and fuel cell systems can include a plurality or an array of spaced-apart CPOX reactor units, each reactor unit including an elongated tube having a gas-permeable wall with internal and external surfaces. The wall encloses an unobstructed gaseous flow passageway. At least a portion of the wall has CPOX catalyst disposed therein and/or comprising its structure. The catalyst-containing wall structure and open gaseous flow passageway enclosed thereby define a gaseous phase CPOX reaction zone, the catalyst-containing wall section being gas-permeable to allow gaseous CPOX reaction mixture to diffuse therein and hydrogen rich product reformate to diffuse therefrom. The liquid fuel CPOX reformer also can include a vaporizer, one or more igniters, and a source of liquid reformable fuel. The hydrogen-rich reformate can be converted to electricity within a fuel cell unit integrated with the CPOX reactor unit.