Various embodiments disclosed related to hydrogen-generating compositions for a fuel cell. In various embodiments, the present invention provides a hydrogen-generating composition comprising a hydride and a Lewis acid. Various embodiments provide methods of using a hydrogen fuel cell including generating hydrogen gas using the composition, fuel cell systems including the composition, and methods of making the composition.

The present disclosure relates generally to new forms of portable energy generation devices and methods. The devices are designed to covert formic acid into released hydrogen, alleviating the need for a hydrogen tank as a hydrogen source for fuel cell power.

Membrane modules for hydrogen separation and fuel processors and fuel cell systems including the same are disclosed herein. The membrane modules include a plurality of membrane packs. Each membrane pack includes a first hydrogen-selective membrane, a second hydrogen-selective membrane, and a fluid-permeable support structure positioned between the first hydrogen-selective membrane and the second hydrogen-selective membrane. In some embodiments, the membrane modules also include a permeate-side frame member and a mixed gas-side frame member, and a thickness of the permeate-side frame member may be less than a thickness of the mixed gas-side frame member. In some embodiments, the support structure includes a screen structure that includes two fine mesh screens. The two fine mesh screens may include a plain weave fine mesh screen and/or a Dutch weave fine mesh screen. The fine mesh screens may be selected to provide at most 100 micrometers of undulation in the hydrogen-selective membranes.

A direct carbonaceous material to power generation system integrates one or more solid oxide fuel cells (SOFC) into a fluidized bed gasifier. The fuel cell anode is in direct contact with bed material so that the H.sub.2 and CO generated in the bed are oxidized to H.sub.2O and CO.sub.2 to create a push-pull or source-sink reaction environment. The SOFC is exothermic and supplies heat within a reaction chamber of the gasifier where the fluidized bed conducts an endothermic reaction. The products from the anode are the reactants for the reformer and vice versa. A lower bed in the reaction chamber may comprise engineered multi-function material which may incorporate one or more catalysts and reactant adsorbent sites to facilitate excellent heat and mass transfer and fluidization dynamics in fluidized beds. The catalyst is capable of cracking tars and reforming hydrocarbons.

In aspects of the disclosure, a fuel cartridge wherein the fuel is in a powdered form is admixed with inert materials such as alumina or other ceramics to improve thermal conductivity. Said cartridge having fuel zones, heating zones, and controllers to selectively heat fuel zones and thereby generate hydrogen via decomposition of fuel is disclosed.

A device includes a case having a surface with a perforation and a first cavity containing a gas generating fuel. A first membrane is supported by the case inside the first cavity. The first membrane has an impermeable valve plate positioned proximate the perforation. The first membrane is water vapor permeable and gas impermeable and flexes responsive to a difference in pressure between the cavity and outside the cavity to selectively allow water vapor to pass through the perforation to the fuel as a function of the difference in pressure. A second membrane that is water vapor permeable gas impermeable is coupled between an outside of the case exposed to ambient atmospheric gas and the valve plate creating a reference pressure second cavity configured to reduce the effects of ambient pressure transients on the difference in pressure. A fuel cell membrane may be included in the device to produce electricity.

A SOFC system having a fuel reformer for reforming a gaseous hydrocarbon stream and steam into a hydrogen rich gas, a solid oxide fuel cell stack including an anode and a cathode for electrochemically reacting the hydrogen rich gas and a cathode air stream to produce electricity, an anode exhaust stream and a cathode depleted air stream. The anode exhaust stream and the cathode depleted air stream are kept separate, a burner for combusting a mixture of the anode exhaust stream and a fresh air stream to complete combustion and produce heat for the reformer control unit and a blower are also provided. The control unit controlling the blower for controlling the mass flow rate of the fresh air stream to provide heat to the reformer to reform the gaseous hydrocarbon stream and to produce a burner exhaust stream.

An object of the present invention is to provide a fuel cell system for preventing carbon deposition in a fuel cell stack to be supplied with reformed gas. A fuel cell system 10A of the present invention includes a partial oxidation reformer 22 for partially oxidizing raw fuel to produce carbon monoxide and hydrogen, a shift reactor 23 for shift reacting the carbon monoxide with steam to produce carbon dioxide and hydrogen, a fuel cell stack 20 for generating electric power by electrochemical reaction between oxidant gas and the hydrogen which is produced in at least one of the partial oxidation reformer 22 and the shift reactor 23, and an exhaust gas recirculation pipe P6 for supplying steam contained in exhaust gas of the fuel cell stack 20 to the shift reactor 23.

The invention is a power generation system which involves a water-splitting reaction employing metal feedstock to generate heat, hydrogen and metal hydroxide. The heat produced by the power generation system supplies a Heating-Ventilation-Air Conditioning (HVAC) system for heating and cooling building structures, such as homes, kiosks, commercial buildings and greenhouses. The hydrogen gas component produced by the invention is sufficient to fuel a fuel cell vehicle (FCV) and a fuel cell, which provides electricity to an associated building structure. The invention can be located on-site with a building structure and provides a readily available FCV fueling station associated with the building structure where an FCV is located.

Method and system for producing CO2, purified hydrogen and electricity from a reformed process gas feed using a solid oxide fuel cell. The method having the steps of: introducing the reformed process gas into the solid oxide fuel cell; converting hydrogen and CO of the reformed process gas in combination with oxygen into an anode off-gas including steam, CO.sub.2 and unconverted process gas; introducing the anode off-gas into a high temperature water gas shift reactor; in the high temperature water-gas shift reactor, converting CO and steam into CO.sub.2 and hydrogen, introducing the gas exiting the high temperature water-gas shift reactor into a low temperature water-gas shift membrane reactor, in the low temperature water-gas shift membrane reactor, converting CO and steam into CO.sub.2 and hydrogen, whereby the low temperature water-gas shift membrane reactor comprises a hydrogen pump producing purified hydrogen on a permeate side, while removing hydrogen from a feed side.