C01B2203/068

AMMONIA PRODUCTION METHOD
20210002141 · 2021-01-07 ·

High purity hydrogen is produced by a steam reforming hydrogen production unit with at least one of a bayonet reactor for reforming steam and a hydrocarbon, a recuperative burner, and a regenerative burner such that the steam reforming unit produces little or no steam in excess of the steam reforming process requirements. High purity hydrogen is separated from the syngas exiting the reformer via a pressure swing adsorption unit and combined with high purity nitrogen from an air separation unit as feedstock to a Haber process ammonia synthesis unit. Compressors for the ammonia synthesis unit are driven by higher efficiency drivers than are possible using the low temperature steam conventionally exported from a steam reforming unit. Compression power requirements are reduced.

METHOD FOR REVAMPING AND INCREASING THE CAPACITY OF A HYDROCARBON REFORMING SECTION
20200399123 · 2020-12-24 ·

A method for revamping a reforming section of a chemical plant, wherein the reforming section treats a first hydrocarbon feed stream, and an apparatus downstream of the reforming section, designed as a steam generator, is converted into a GHR by means of the following steps: replacing the heat exchange bodies of said steam generator with heat exchange bodies containing a reforming catalyst; directing a second hydrocarbon feed stream inside said heat exchange bodies containing catalyst; extracting a reformed gas stream from said heat exchange bodies.

Process for production of ammonia and derivatives, in particular urea
10858313 · 2020-12-08 · ·

A process for producing ammonia and a derivative of ammonia from a natural gas feed comprising conversion of natural gas into a make-up synthesis gas; synthesis of ammonia; use of said ammonia to produce said derivative of ammonia, wherein a portion of the natural gas feed is used to fuel a gas turbine; power produced by said gas turbine is transferred to at least one power user of the process, such as a compressor; heat is recovered from exhaust gas of said gas turbine, and at least part of said heat is recovered as low-grade heat available at a temperature not greater than 200 C., to provide process heating to at least one thermal user of the process, such as CO.sub.2 removal unit or absorption chiller; a corresponding plant and method of modernization are also disclosed.

Method for the combined production of methanol and ammonia
10843989 · 2020-11-24 · ·

Method and system for the combined production of methanol and of ammonia, and method for producing a fuel using methanol, wherein a carbon-containing energy carrier flow and an oxygen flow from an oxygen-producing assembly are fed to a synthesis gas reactor assembly for obtaining a synthesis gas flow with hydrogen and carbon oxides, wherein the synthesis gas flow is fed to a methanol reactor assembly for the partial conversion into methanol, and wherein, from the methanol reactor assembly, a residual gas flow is obtained from which a hydrogen-containing flow is obtained, which is at least partially fed to an ammonia reactor assembly and at least partially converted into ammonia there. In an enrichment step, the molar fraction of hydrogen in the synthesis gas flow obtained from the synthesis gas reactor assembly is increased relative to the molar fraction of carbon oxides prior to the feeding to the methanol reactor assembly.

Process for purification of a synthesis gas containing hydrogen and impurities

A process for purification of a current of hydrogen synthesis gas (100), particularly in the front-end of an ammonia plant, wherein said gas contains hydrogen and minor amounts of carbon monoxide, carbon dioxide, water and impurities, said process including steps of methanation (13) of said current (100), converting residual amounts of carbon monoxide and carbon dioxide to methane and water, dehydration (14) of the gas to remove water, and then a cryogenic purification (15) such as liquid nitrogen wash, to remove methane and Argon; a corresponding plant and method for revamping an ammonia plant are also disclosed.

Conditioned syngas composition, method of making same and method of processing same to produce fuels and/or fischer-tropsch products

A system and method for processing unconditioned syngas first removes solids and semi-volatile organic compounds (SVOC), then removes volatile organic compounds (VOC), and then removes at least one sulfur containing compound from the syngas. Additional processing may be performed depending on such factors as the source of syngas being processed, the products, byproducts and intermediate products desired to be formed, captured or recycled and environmental considerations.

METHOD AND SYSTEM COMBINATION FOR THE PREPARATION OF SYNTHESIS PRODUCTS CONTAINING NITROGEN

The invention relates to a process (100), in which, with the inclusion of an air-separation method (10), an oxygen-rich substance flow (b) is formed, which, with a methane-rich substance flow (e), is subjected to a method for oxidative methane coupling. From the product flow (e) of the method for oxidative coupling of methane (20), one or more substance flows (f, i) are formed, which are subjected to one or more synthesis methods (40, 50) for the production of one or more nitrogen-containing synthesis products.

HYDROGEN PRODUCTION FROM HYDROCARBONS WITH NEAR ZERO GREENHOUSE GAS EMISSIONS

Methods and systems for producing hydrogen substantially without greenhouse gas emissions, the method including producing a product gas comprising hydrogen and carbon dioxide from a hydrocarbon fuel source; separating hydrogen from the product gas to create a hydrogen product stream and a byproduct stream; injecting the byproduct stream into a reservoir containing mafic rock; and allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

METHOD FOR SYNGAS SEPARATION AT HYDROGEN PRODUCING FACILITIES FOR CARBON CAPTURE AND STORAGE

Methods and systems for gas separation of syngas applying differences in water solubilities of syngas components, the method including producing a product gas comprising hydrogen and carbon dioxide from a hydrocarbon fuel source; separating hydrogen from the product gas to create a hydrogen product stream and a byproduct stream by solubilizing components in water that are more soluble in water than hydrogen; injecting the byproduct stream into a reservoir containing mafic rock; and allowing components of the byproduct stream to react in situ with components of the mafic rock to precipitate and store components of the byproduct stream in the reservoir.

Oxidative coupling of methane methods and systems

The present disclosure provides natural gas and petrochemical processing systems including oxidative coupling of methane reactor systems that integrate process inputs and outputs to cooperatively utilize different inputs and outputs of the various systems in the production of higher hydrocarbons from natural gas and other hydrocarbon feedstocks.