Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock.

Process for manufacturing a hydrogen-containing synthesis gas from a natural gas feedstock, comprising the conversion of said natural gas into a raw product gas and purification of said product gas, the process having a heat input provided by combustion of a fuel; said process comprises a step of conversion of a carbonaceous feedstock, and at least a portion of said fuel is a gaseous fuel obtained by said step of conversion of said carbonaceous feedstock.

Process for the synthesis of ammonia comprising the steps of reforming of a hydrocarbon feedstock into a raw product gas, purification of said raw product gas obtaining a make-up synthesis gas, conversion of said synthesis gas into ammonia; said purification includes shift conversion of carbon monoxide into carbon dioxide and the reforming process requires a heat input which is at least partially recovered from at least one of said step of shift conversion, which is carried out with a peak temperature of at least 450 C., and said step of conversion into ammonia.

A CO shift catalyst according to the present invention reforms carbon monoxide (CO) in gas. The CO shift catalyst has one of molybdenum (Mo) or iron (Fe) as a main component and has an active ingredient having one of nickel (Ni) or ruthenium (Ru) as an accessory component and one or two or more kinds of oxides from among titanium (Ti), zirconium (Zr), and cerium (Ce) for supporting the active ingredient as a support. The temperature at the time of manufacturing and firing the catalyst is equal to or higher than 550 C.

Disclosed is a technology based upon the nesting of tubes to provide chemical reactors or chemical reactors with built in heat exchanger. As a chemical reactor, the technology provides the ability to manage the temperature within a process flow for improved performance, control the location of reactions for corrosion control, or implement multiple process steps within the same piece of equipment. As a chemical reactor with built in heat exchanger, the technology can provide large surface areas per unit volume and large heat transfer coefficients. The technology can recover the thermal energy from the product flow to heat the reactant flow to the reactant temperature, significantly reducing the energy needs for accomplishment of a process.

The present process invention in continuation to the U.S. Ser. No. 14/392,066 appertains to Advanced Combustion in post-combustion carbon capture, wherein the CO.sub.2-containing flue gas, said CO2-Stream, is cleaned from harmful constituents, recirculated, oxygenized and employed for combustion for the fossil fuels, referred to Flue Gas Oxy-Fueling in order to obtain a CO.sub.2-rich gas upstream to CO2-CC with significantly less gas flow rate subject to further processing. This continuation process patent also presents processing to prepare a CO.sub.2-rich CO2-Stream for the pre-combustion carbon capture downstream of gasification and gas cleaning process; or from the secondary CO2-Stream that stems from the cathodic syngas [CO/2H.sub.2] downstream of HPLTE-SG of patent parent, then downstream of the HP/IP-water shift converters in [CO.sub.2/3H.sub.2] composition, whereas the CO.sub.2-rich CO2-Stream from either pre-combustion process is routed to the CO2-CC for CO.sub.2 cooling and condensation section of the U.S. Ser. No. 14/392,066 to obtain liquid carbon dioxide for re-use as new fossil energy resource.

Disclosed herein are methods and systems for the production of hydrogen-containing compounds, such as ammonia and urea from a product stream of a fuel cell unit. The production of ammonia and optionally urea can also include a net power production. Alternatively, the hydrogen stream from the fuel cell unit can be directed to the production of synthetic hydrocarbons liquids.

A system and method for supplying an energy grid with energy from an intermittent renewable energy source having a production unit for producing Hydrogen, Nitrogen, and Oxygen. The production unit is operated by using energy provided by the renewable energy source. An Oxygen storage receives and stores Oxygen produced by the production unit, a mixing unit receives and mixes the Hydrogen and the Nitrogen produced by the production unit to form a Hydrogen-Nitrogen-mixture, an Ammonia source receives and processes the Hydrogen-Nitrogen-mixture for generating a gas mixture containing Ammonia, an Ammonia power generator generates energy for the energy grid. The Ammonia power generator is fluidly connected to the Ammonia storage vessel, is configured to combust the received Ammonia in a combustion chamber to generate the energy, and is fluidly connected to the Oxygen storage to introduce Oxygen into the combustion chamber for combustion of Ammonia.

A process for the production of formaldehyde-stabilised urea is described comprising the steps of: (a) generating a synthesis gas; (b) subjecting the synthesis gas to one or more stages of water-gas shift in one or more water-gas shift reactors to form a shifted gas; (c) cooling the shifted gas to below the dew point and recovering condensate to form a dried shifted gas; (d) recovering carbon dioxide from the dried shifted gas in a carbon dioxide removal unit to form a carbon dioxide-depleted synthesis gas; (e) synthesising methanol from the carbon dioxide-depleted synthesis gas in a methanol synthesis unit and recovering the methanol and a methanol synthesis off-gas; (f) subjecting at least a portion of the recovered methanol to oxidation with air to form formaldehyde in a stabiliser production unit; (g) subjecting the methanol synthesis off-gas to methanation in a methanation reactor containing a methanation catalyst to form an ammonia synthesis gas; (h) synthesising ammonia from the ammonia synthesis gas in an ammonia production unit and recovering the ammonia; (i) reacting a portion of the ammonia and at least a portion of the recovered carbon dioxide stream in a urea production unit to form a urea stream; and (j) stabilising the urea by mixing the urea stream and a stabiliser prepared using the formaldehyde produced in the stabiliser production unit, wherein the carbon dioxide removal unit operates by means of absorption using a liquid absorbent and comprises an absorbent regeneration unit, wherein the process includes recovering a carbon dioxide-containing gas stream from the absorbent regeneration unit, compressing at least a portion of the recovered carbon dioxide-containing gas stream to form a compressed carbon dioxide-containing gas stream and passing the compressed carbon dioxide-containing gas stream to the methanol synthesis unit.

The present invention relates to a method for forming a three-dimensional article through successively depositing individual layers of powder material that are fused together so as to form the article, the method comprising the step of heating a first portion of a support surface while depositing a layer of powder material on a second portion of the support surface.