A process for producing a lithium-manganese-rich layered oxide cathode material or a lithium-manganese-rich layered oxide cathode material precursor includes co-precipitating a dissolved Li compound and a dissolved Mn salt selected from the group consisting of Mn(CH.sub.3COO).sub.2, Mn(NO.sub.3).sub.2, MnSO.sub.4, and mixtures thereof, from an aqueous solution, in the presence of a precipitator which reacts at least with the dissolved Mn salt to form a carbonate, thereby providing a precipitate which includes MnCO.sub.3 and a lithium compound as a lithium-manganese-rich layered oxide cathode material precursor. The invention extends to a lithium-manganese-rich layered oxide cathode material or a lithium-manganese-rich layered oxide cathode material precursor, to an electrochemical cell, and to methods of making and operating an electrochemical cell.

A luminophore may have the general formula A.sub.2EZ.sub.zX.sub.x:RE,

where: A is selected from the group of the monovalent elements; E is selected from the group of the tetravalent, pentavalent, or hexavalent elements; Z is selected from the group of the divalent elements; X is selected from the group of the monovalent elements; RE is selected from activator elements; 2+e=2z+x, with the charge number e of the element E; and x+z=5 and z>0.

A process is also disclosed that is directed to producing the luminophore and a corresponding radiation-emitting component.

The present invention relates to a crystalline material having a framework structure comprising O and one or more tetravalent elements Y, and optionally comprising one or more trivalent elements X, wherein the crystalline material displays a crystallographic unit cell of the monoclinic space group C2, wherein the unit cell parameter a is in the range of from 14.5 to 20.5 Å, the M unit cell parameter b is in the range of from 14.5 to 20.5 Å, the unit cell parameter c in the range of from 11.5 to 17.5 Å and the unit cell parameter β is in the range of from 109 to 118°, wherein the framework density is in the range of from 11 to 23 T-atoms/1000 Å.sup.3 wherein the framework structure comprises 12 membered rings, and wherein the framework structure displays a 2-dimensional channel e dimensionality of 12 membered ring channels. The present invention further relates to a process for the production of said material, as N well as to its use, in particular as a catalyst or catalyst component.

The present invention concerns a method for producing a solid material according to general formula (I) as follows: Li.sub.6-.sub.x_.sub.2yCu.sub.xPS.sub.5_.sub.yX (I) wherein X is selected from the group consisting of: F, CI, I and Br; 0.005 ≤ x ≤ 5; and 0 ≤y ≤ 0.5.; comprising at least bringing at least lithium sulfide, phosphorous sulfide, halogen compound and a copper compound, optionally in one or more solvents. The invention also refers to said solid materials and their use as solid electrolytes notably for electrochemical devices.

The present disclosure relates to an anode electrode active material for a secondary battery containing nickel cobalt molybdenum oxide, an anode electrode for a secondary battery including the same, a secondary battery including the anode electrode for a secondary battery, and a method for manufacturing the same. The novel anode electrode material for a sodium secondary battery containing nickel cobalt molybdenum oxide according to the present disclosure allows intercalation/deintercalation reaction of sodium ion during charge/discharge and does not undergo significant volume change during the intercalation reaction because structure is maintained stably during repeated charge/discharge. As a result, electrode damage and electric short circuit are decreased and, thus, improved electrochemical characteristics can be achieved in long-life and high-rate capability.

The disclosure relates to porous garnet ribbons and methods of making such porous garnet ribbons.

Described are lithium transition metal halides which have ionic conductivity for lithium ions, a process for preparing them, their use as a solid electrolyte for an electrochemical cell, and electrochemical cells comprising lithium transition metal halides.

A powder for coating or sintering exhibits a peak assigned to orthorhombic YAlO.sub.3 in an X-ray diffractometry. Of peaks exhibited in the X-ray diffractometry, the peak assigned to the (112) plane of orthorhombic YAlO.sub.3 is a peak that has the highest peak intensity. Preferably, the value of the ratio of S2 to S1, S2/S1, is less than 1 in an X-ray diffractometry using CuKα radiation, where SI represents the peak intensity of the peak assigned to the (112) plane of orthorhombic YAlO.sub.3 and S2 represents the peak intensity of the peak assigned to the (104) plane of trigonal Al.sub.2O.sub.3.

A method for manufacturing a sapphire single-crystal, including melting alumina and/or sapphire in a crucible, and bringing the molten alumina and/or sapphire in contact with a monocrystalline sapphire seed to make the molten alumina and/or sapphire crystallise progressively according to a growth direction to form the sapphire single-crystal. The monocrystalline sapphire seed has a rhombohedral crystallographic structure defining three crystallographic axes [A], [C] and [M] perpendicular to each other and respectively perpendicular to the crystallographic planes. The monocrystalline sapphire seed is a plate delimited by two planar faces which extend parallel to and at a distance from each other, is obtained from an initial sapphire single-crystal which is cut so that one of the crystallographic axes of the monocrystalline sapphire plate forms with a normal to the planar faces of the monocrystalline sapphire plate an angle whose value is comprised between 5 and 85°.

Olivine-type compounds, their preparation and use in cathode materials for sodium-ion batteries. The olivine-type compounds may be obtained by a direct synthesis embodying a hydrothermal method. The method may include preparing an aqueous mixture including a M-containing compound, a M′-containing compound and a M″-containing compound to obtain a M-M′-M″ mixture; adding a P-containing compound to the mixture M-M′-M″ mixture to obtain a M-M′-M″-P mixture; adding a Na-containing compound to the M-M′-M″-P mixture to obtain a Na-M-M′-M″-P mixture; and introducing the Na-M-M′-M″-P mixture into an autoclave to perform crystal growth and obtain the compound of general formula Na.sub.hM.sub.iM′.sub.jM″.sub.kPO.sub.4.