Vanadium oxide nanomaterials dispersed in a polymeric matrix, substrates including the vanadium oxide nanomaterials dispersed in a polymeric matrix, and related methods of making vanadium oxide nanomaterials dispersed in a polymeric matrix are described.

The present invention provides a method for producing a nitrogen-doped highly graphitic porous carbon body, and a nitrogen-doped highly graphitic porous carbon body produced according to the same. Also, the present invention provides a method for producing a sulfur and nitrogen double-doped highly graphitic porous carbon body, a sulfur and nitrogen double-doped highly graphitic porous carbon body produced according to the same, and an electrode catalyst for a fuel cell and/or a water electrolysis reaction comprising the carbon body.

A method for producing an ion conductor containing LiCB.sub.9H.sub.10 and LiCB.sub.11H.sub.12 includes: preparing a homogeneous solution by mixing LiCB.sub.9H.sub.10 and LiCB.sub.11H.sup.12 in a solvent at a LiCB.sub.9H.sub.10/LiCB.sub.11H.sub.12 molar ratio of from 1.1 to 20; obtaining a precursor by removing the solvent from the homogeneous solution; and obtaining an ion conductor by subjecting the precursor to a heat treatment.

The present application relates to copper-doped double perovskites, for example, copper-doped double perovskites of the formula (I) and to uses thereof, for example as low-bandgap materials such as a semiconducting material in a device. The present application also relates to methods of tuning the bandgap of a Cs.sub.2SbAgZ.sub.6 double perovskite (for example, wherein Z is Cl) comprising doping the double perovskite with copper.
Cs.sub.2Sb.sub.1-aAg.sub.1-bCu.sub.2xZ.sub.6  (I)

A method for making crown ether functionalized substrates, which includes modifying crown ether-based molecules by reacting with carboxylic acid functionalize chains. The crown ether-based molecules are then attached to substrates, thereby forming crown ether functionalized substrates.

The present invention features a new way of doping layered cathode materials in lithium ion batteries. Using a .sup.“high entropy” doping strategy, more than four impurity elements can be introduced to the host materials. The present invention applies this high entropy doping strategy to a high nickel content layered oxide material and a lithium-manganese rich material. This new high entropy doping strategy allows the layered oxide materials used in the positive electrode of lithium ion battery to achieve high energy density, long life cycle and reduced reliance on the expensive and toxic cobalt, all of which are desired attributes for improving the performance of lithium ion batteries and reducing their cost.

The present invention features a new way of doping layered cathode materials in lithium ion batteries. Using a “high entropy” doping strategy, more than four impurity elements can be introduced to the host materials. The present invention applies this high entropy doping strategy to a high nickel content layered oxide material and a lithium-manganese rich material. This new high entropy doping strategy allows the layered oxide materials used in the positive electrode of lithium ion battery to achieve high energy density, long life cycle and reduced reliance on the expensive and toxic cobalt, all of which are desired attributes for improving the performance of lithium ion batteries and reducing their cost.

The present disclosure sets forth battery components for secondary and/or traction batteries. Described herein are new solid-state lithium (Li) conducting electrolytes including monolithic, single layer, and bi-layer solid-state sulfide-based lithium ion (Li.sup.+) conducting catholytes or electrolytes. These solid-state ion conductors have particular chemical compositions which are arranged and/or bonded through both crystalline and amorphous bonds. Also provided herein are methods of making these solid-state sulfide-based lithium ion conductors including new annealing methods. These ion conductors are useful, for example, as membrane separators in rechargeable batteries.

Disclosed herein are aluminum oxide aerogels and methods of making and use thereof. The methods of making the aluminum oxide aerogel include contacting a solid comprising aluminum with a Ga-based liquid alloy to dissolve at least a portion of the aluminum from the solid, thereby forming an aluminum-alloy mixture; and contacting the aluminum-alloy mixture with a fluid comprising water, thereby forming the aluminum oxide aerogel. In some examples, the methods can further comprise capturing and converting carbon dioxide to a syngas comprising carbon monoxide and hydrogen.

A solid-state ion conductor includes a compound of Formula 1:
Li.sub.(6-a)x+2y-b*z-6A.sub.1−xM.sup.a.sub.xO.sub.yX.sup.b.sub.z  Formula 1
wherein, in Formula 1, A is an element having an oxidation state of +6, M is an element having an oxidation state of a, wherein a is +2, +3, +4, +5, or a combination thereof, X is an element having an oxidation state of b, wherein b is −1, −3, or a combination thereof, and 2<[(6−a)x+2y−b*z−6]≤6.5, 0≤x≤1, y>0, and z≥0.