In an embodiment is provided a polymer that includes a plurality of N-J-N or N—C—S repeating units, wherein each J is independently a carbon atom, an alkyl group, or an aryl group; a plurality of hydrophilic groups bonded with the repeating units; and a plurality of hydrophobic groups bonded with the hydrophilic groups and the repeating units. In another embodiment is provided hydrogels of such polymers. The hydrogels may be used as delivery vehicles for various payloads. In another embodiment is provided methods of forming such polymers.

In an embodiment is provided a polymer that includes a plurality of N-J-N or N—C—S repeating units, wherein each J is independently a carbon atom, an alkyl group, or an aryl group; a plurality of hydrophilic groups bonded with the repeating units; and a plurality of hydrophobic groups bonded with the hydrophilic groups and the repeating units. In another embodiment is provided hydrogels of such polymers. The hydrogels may be used as delivery vehicles for various payloads. In another embodiment is provided methods of forming such polymers.

A lacquer composition is provided, comprising 20%-79.9% by weight, based on the total weight of the composition, of a thiol compound having two or more thiol groups, 20%-79.9% by weight, based on the total weight of the composition, of a compound having two or more carbon-carbon double bonds and 0.1%-10% by weight, based on the total weight of the composition, of a separating agent having an alkyl radical having 4-20 carbon atoms, where the alkyl radical is unsubstituted or fluorine-substituted and the alkyl radical is bonded to a functional group. Also provided are the use of this lacquer composition as a protective lacquer on an optical surface of an optical element in the production of the optical element, and an optical element comprising the protective lacquer.

A lacquer composition is provided, comprising 20%-79.9% by weight, based on the total weight of the composition, of a thiol compound having two or more thiol groups, 20%-79.9% by weight, based on the total weight of the composition, of a compound having two or more carbon-carbon double bonds and 0.1%-10% by weight, based on the total weight of the composition, of a separating agent having an alkyl radical having 4-20 carbon atoms, where the alkyl radical is unsubstituted or fluorine-substituted and the alkyl radical is bonded to a functional group. Also provided are the use of this lacquer composition as a protective lacquer on an optical surface of an optical element in the production of the optical element, and an optical element comprising the protective lacquer.

A method for setting conditions for use of a polymerization catalyst includes a step of acquiring a physical property value derived from remaining functional groups after maintaining a temperature of a composition including a polymerization-reactive compound and a predetermined amount of a polymerization catalyst, a step of calculating a remaining functional group ratio from the physical property value, a step of calculating a reaction rate constant based on a reaction rate equation from the remaining functional group ratio, a step of calculating an activation energy and a frequency factor from the reaction rate constant using an Arrhenius plot, a step of determining whether or not the activation energy satisfies a predetermined condition for the polymerization catalyst, an step of setting an approximation equation from the frequency factor, and a step of setting an addition range with respect to the polymerization-reactive compound.

A method for setting conditions for use of a polymerization catalyst includes a step of acquiring a physical property value derived from remaining functional groups after maintaining a temperature of a composition including a polymerization-reactive compound and a predetermined amount of a polymerization catalyst, a step of calculating a remaining functional group ratio from the physical property value, a step of calculating a reaction rate constant based on a reaction rate equation from the remaining functional group ratio, a step of calculating an activation energy and a frequency factor from the reaction rate constant using an Arrhenius plot, a step of determining whether or not the activation energy satisfies a predetermined condition for the polymerization catalyst, an step of setting an approximation equation from the frequency factor, and a step of setting an addition range with respect to the polymerization-reactive compound.

A cure promoter composition is disclosed, including an accelerator which may include a thiocarbamate, a hydrated thiocarbamate, a dithiocarbamate, a thiazole, a mercaptothiazole, a sulfenamide, a thiazolesulfenamide, a metal salt of thiocarbamate, sulfur chloride, or combinations thereof. The cure promoter composition also includes a compatibilizing carrier, one or more organic solvents, a catalyst, an optional reducing agent, an optional reactive silane, an optional reactive organometallic, an optional gelling agent, and an optional aqueous component. A method for applying the cure promoter composition is disclosed, including contacting the organic solvents, the accelerator, the carrier, the reactive silanes, the reactive organometallics, the reducing agents, and the catalyst with one another to prepare the cure promoter composition, homogenizing the cure promoter composition, pausing after homogenizing to allow the cure promoter time to react, applying a sealant onto a substrate, and applying the cure promoter composition to a surface of the sealant.

It is an object of the present disclosure to provide a method for efficiently and economically producing a polythioether compound by performing a ring-opening polymerization of an alicyclic episulfide compound.

The present disclosure provides a method for producing a polythioether compound, the method including performing a ring-opening polymerization of an alicyclic episulfide compound in the presence of a base. The base is preferably an amine compound. Further, the base is preferably a strong base.

The present invention relates to a hydrogel precursor formulation, its process of production as well as a kit comprising said formulation and a method of production of a hydrogel using said formulation. The precursor formulation comprises at least one structural compound, preferably vinyl sulfone (acrylated branched) poly(ethylene glycol), and at least one linker compound, preferably a peptide with two cysteines, wherein said structural compound and said linker compound are polymerizable by a selective reaction between a nucleophile and a conjugated unsaturated bond or group. The precursor formulation is in the form of a powder.

The present invention is directed to a liquid sealant composition based on polysulphide, capable of curing on demand, and the process for preparing same, the liquid sealant composition including: (i) a polysulphide comprising an —SH end group, (ii) a crosslinking agent chosen from ethylenically unsaturated or acetylenically unsaturated compounds, the unsaturated ethylenic or unsaturated acetylenic functions of the crosslinking agent being chemically blocked with a blocking agent, and (iii) optionally, a catalyst. The present invention also relates to a process for coating a substrate with a composition according to the invention, and also to the cured sealant materials formed from this composition. Finally, the invention relates to the use of a liquid sealant composition according to the invention for the construction and/or the maintenance, and more particularly for the adhesive bonding and/or the protection, of vehicles and machines.