Formulations and methods for stimulating the production from wells in nano-darcy shale formations. In one embodiment, the method includes injecting a treatment mixture containing a metal complexing agent into a nano-darcy shale formation adjacent to a well at a pressure below the fracture pressure of the formation. A sufficient contact time is allowed and then the treatment mixture is pumped from the subsurface. This has been shown to stimulate well production in shale formations. Without being held to a particular theory it appears that the metal complexing agent is binding with naturally occurring metals in the shale formation, and particularly divalent metal ions, which are then extracted with the spent fluid. This removal of naturally occurring metals may be increasing the permeability of the formation in the contact region adjacent to the well, thereby causing the observed increased production.

A method for storing an energy-storage fluid within a subterranean formation having suppressed microbial activity includes injecting a high-salinity aqueous solution into the subterranean formation via at least one injection wellbore extending from a terranean surface and penetrating the subterranean formation, such that at least a portion of the high-salinity aqueous solution is held within the subterranean formation. The high-salinity aqueous solution includes water and an inorganic salt, and is configured to suppress microbial activity in the subterranean formation. The method also includes injecting the energy-storage fluid into the subterranean formation via the at least one injection wellbore to store at least a portion of the energy-storage fluid within the subterranean formation.

Disclosed herein are compositions and methods for delaying crosslinking of aqueous crosslinkable polymers such as polysaccharides in injectable compositions for hydraulic fracturing and related applications. The compositions and methods provide delayed crosslinking at high temperatures and pressures, such as those encountered by hydraulic fracturing compositions injected into subterranean environments. Compositions include injectable solutions comprising a competing agent that is a reaction product of a dialdehyde having 2 to 4 carbon atoms with a non-polymeric cis-hydroxyl compound. Provided are methods of making and using delayed-crosslinking compositions comprising crosslinker compositions containing zirconium complexes and the competing agents.

An oil-based slurry composition comprising hydratable (water-soluble) materials with improved settling properties is disclosed with the addition of a suspending agent to the slurry mixture. The suspending agent is a styrenic diblock copolymer of formula A-B. The styrenic diblock copolymer is a hydrogenated styrene-(ethylene/propylene) (S-EP) block copolymer having a molecular weight of 175-225 kg/mole and a polystyrene (PSC) content of 30-50%. The block copolymer maintains the water-soluble materials in suspension in the mixture with less than 3 wt. % free hydrocarbon solvent separation after at least 1 day standing.

Proppant compositions and methods for using same are disclosed herein. In particular, a proppant composition for use in hydraulic fracturing is disclosed herein. The proppant composition can contain a plurality of particulates and at least one particulate of the plurality of particulates containing a chemical treatment agent. The at least one particulate having a long term permeability measured in accordance with ISO 13503-5 at 7,500 psi of at least about 10 D. The at least one chemical treatment agent can separate from the at least one particulate when located inside a fracture of a subterranean formation after a period of time.

The technology described herein includes methods and uses in oil and gas hydraulic fracking for a quaternary ammonium organosilane, and particularly AMOSILQ™ quaternary ammonium organosilane. Uses include coating and treating filters for use in the hydraulic fracking process, premixing in fracking fluid/water; flowback water treatment and proppant coating.

According to one aspect of the invention, a method of converting an oxy halide salt into a halide dioxide in a reaction zone under certain conditions is provided. More specifically, the method includes generating chlorine dioxide from a stable composition comprising an oxy halide salt by introducing said composition to a reducing agent and minimum temperature within the reaction zone. According to another aspect of the invention, a composition for a stable chlorine dioxide precursor comprising an oxy halide salt is provided.

Proppant compositions and methods for using same are disclosed herein. In particular, a proppant composition for use in hydraulic fracturing is disclosed herein. The proppant composition can contain a plurality of particulates and at least one particulate of the plurality of particulates containing a chemical treatment agent. The at least one particulate having a long term permeability measured in accordance with ISO 13503-5 at 7,500 psi of at least about 10 D. The at least one chemical treatment agent can separate from the at least one particulate when located inside a fracture of a subterranean formation after a period of time.

Disclosed herein are compositions and methods for delaying crosslinking in injectable compositions for hydraulic fracturing and related applications. The compositions and methods are effective in injectable compositions comprising or substantially excluding dissolved reactive species. The compositions and methods provide delayed crosslinking at high temperatures and pressures, such as those encountered by hydraulic fracturing compositions injected into subterranean environments. Compositions include injectable solutions comprising a competing agent that is the reaction product of a dialdehyde having 2 to 4 carbon atoms with a non-polymeric cis-hydroxyl compound. Also provided are methods of making and using delayed-crosslinking compositions comprising crosslinker compositions containing zirconium complexes and the competing agents.

The present disclosure generally relates to a system and methods for stimulation with particle-stabilized emulsion treatment fluids during hydraulic fracturing operations. A treatment fluid is disclosed, the treatment fluid including a continuous fluid phase, a dispersed fluid phase dispersed throughout the continuous fluid phase, a surfactant, and a plurality of solid particles adsorbed to an interface between the continuous and dispersed fluid phases thereby stabilizing the dispersed fluid phase in the continuous fluid phase. A method for treating a subterranean formation is disclosed, the method including providing a treating fluid comprising a plurality of solid particles adsorbed to an interface between a continuous fluid phase and a dispersed fluid phase, thereby stabilizing the continuous and dispersed fluid phases, and pumping the treating fluid under pressure via a pump to invert the emulsion so that at least a portion of the solid particles are deposited in the subterranean formation.