Patent classifications
B01D2255/65
PGM catalyst coupled with a non-PGM catalyst with HC oxidation capability
The present invention relates to a diesel oxidation catalyst comprising a substrate and a wash-coat comprising a first layer and a second layer, wherein the substrate has a substrate length, a front end and a rear end, the washcoat comprising the first layer comprising a first metal oxide and comprising a platinum group metal supported on a metal oxide support material; the second layer comprising a second metal oxide and comprising one or more of an oxidic compound of vanadium, an oxidic compound of tungsten and a zeolitic material comprising one or more of Fe and Cu; wherein the first layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on an intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on x % of the length of the substrate from the front end of the substrate, and wherein the second layer is at least partially disposed directly on the substrate, or is at least partially disposed directly on the intermediate layer which is disposed directly on the substrate over the entire length of the substrate, on y % of the length of the substrate from the rear end of the substrate, wherein x is in the range of from 25 to 75 and y is in the range of from 25 to 75 and wherein x+y is in the range of from 95 to 105, wherein the intermediate layer comprises alumina.
EXHAUST PURIFICATION CATALYST
The present invention provides an exhaust gas purification catalyst in which platinum group metal migration from a catalyst layer to a base material during high temperature duration is suppressed. The exhaust gas purification catalyst disclosed herein includes a base material, a catalyst layer, and an intermediate layer arranged between the base material and the catalyst layer. The base material contains SiC. The catalyst layer contains a platinum group metal as a catalyst component. The intermediate layer contains substantially no platinum group metal. A product of a thickness of the intermediate layer (μm) and a specific surface area (m.sup.2/g) of the intermediate layer is 1100 or more.
Purification catalyst for interior of polymer film production furnace and purification method for interior of polymer film production furnace
A method for purifying a gas inside a polymer film production furnace with the use of the purification catalyst is provided. A purification catalyst for a gas inside a polymer film production furnace, contains a mixed oxide composed of a manganese-based oxide containing manganese and potassium and having a cryptomelane structure, and copper oxide. A method for purifying a gas inside a polymer film production furnace, includes a step 1 of bringing hot air containing volatile and/or sublimable organic substances, generated during production of a polymer film by the polymer film production furnace, into contact with the catalyst provided inside or outside the furnace, at a temperature in the range of 200 to 350° C. to decompose the organic substances oxidatively, and a step 2 of refluxing all or a part of a resultant decomposition gas to the polymer film production furnace.
CATALYST FOR PARTICULATE COMBUSTION IN GASOLINE EMISSION TREATMENT SYSTEMS
Disclosed herein is a catalyst for particulate combustion which is essentially free of platinum group metal compounds and the catalyst comprises a carrier and at least one metal oxide chosen from iron oxide and manganese oxide, and combinations thereof.
A catalyst for CO2 capture and conversion coupling with biomass oxidation, a preparation method therefor and an application thereof
The present invention discloses a catalyst for in-situ CO2 capture and coupling reduction with biomass oxidation, a preparation method therefor and an application thereof. The catalyst is applied to the coupling reaction of photocatalytic CO2 reduction and biomass oxidation. The preparation of the catalyst is to synthesize layered double hydroxides (LDHs) containing CO32− between layers by using coprecipitation method, hydrothermal method, sol-gel method and the like, wherein the chemical formula is [M1-x2+Mx3+(OH)2]x+(An−)x/n.Math.mH2O, which has a thickness of 20-30 nm and an average particle diameter of 60-90 nm. Then metal ion vacancy defects are produced on LDHs laminate by using a NaOH/KOH selective etching to obtain the corresponding catalyst. The catalyst is used in photocatalytic reaction, characterized in that CO32− is continuously consumed in the reaction process, and the catalyst can absorb CO2 in the air for recovery after the reaction, and can be repeatedly used to continuously consume CO2 in the air, thus realizing the direct capture and effective utilization of CO2.
Exhaust gas purifying catalyst
The exhaust gas purifying catalyst presented here includes a substrate and a catalyst coat layer formed on the surface of the substrate. The catalyst coat layer is formed in a laminate structure having two layers, with a first layer being nearer to the surface of the substrate and a second layer being relatively further from this surface. The second layer includes a carrier and a noble metal supported on the carrier. The first layer is a noble metal-free layer that does not contain a noble metal but does contain an OSC material having oxygen storage capacity.
OXYGEN STORAGE CAPACITY OF NON-COPPER SPINEL OXIDE MATERIALS FOR TWC APPLICATIONS
Zero-Rare Earth Metal (ZREM) and Zero-platinum group metals (ZPGM) compositions of varied binary spinel oxides are disclosed as oxygen storage material (OSM) to be used within TWC systems. The ZREM-ZPGM OSM systems comprise binary non-Cu spinel oxides of Co—Fe, Fe—Mn, Co—Mn, or Mn—Fe. The oxygen storage capacity (OSC) property associated with the non-Cu ZREM-ZPGM OSM systems is determined employing isothermal OSC oscillating condition testing. Further, the OSC test results compare the OSC properties of a ZREM-ZPGM reference OSM system including a Cu—Mn binary spinel oxide and PGM reference catalysts including Ce-based OSMs. The non-Cu spinel oxides ZREM-ZPGM OSM systems exhibit significantly improved OSC properties, which are greater than the OSC property of the Ce-based OSM PGM reference systems.
APPLICATION OF SYNERGIZED-PGM WITH ULTRA-LOW PGM LOADINGS AS CLOSE-COUPLED THREE-WAY CATALYSTS FOR INTERNAL COMBUSTION ENGINES
Synergized platinum group metals (SPGM) with ultra-low PGM loadings employed as close-coupled (CC) three-way catalysts (TWC) systems with varied material compositions and configurations are disclosed. SPGM CC catalysts in which ZPGM compositions of binary or ternary spinel structures supported onto support oxides are coupled with commercialized PGM UF catalysts and tested under Federal Test Procedure FTP-75 within TGDI and PI engines. The performance of the TWC systems including SPGM CC (with ultra-low PGM loadings) catalyst and commercialized PGM UF catalyst is compared to the performance of commercialized PGM CC and PGM UF catalysts. The disclosed TWC systems indicate that SPGM CC TWC catalytic performance is comparable or even exceeds high PGM-based conventional TWC catalysts, with reduced tailpipe emissions.
Catalyst for Use in the Selective Catalytic Reduction (SCR) of Nitrogen Oxides
The present invention pertains to a catalyst for use in the selective catalytic reduction (SCR) of nitrogen oxides comprising a monolithic substrate and a coating A, which comprises an oxidic metal carrier comprising an oxide of titanium and a catalytic metal oxide which comprises an oxide of vanadium wherein the mass ratio vanadium/titanium is 0.07 to 0.26.
METHODS AND MATERIALS FOR DIRECT NOX DECOMPOSITION IN LEAN EXHAUST GASES
A noble metal-free lanthanum transition metal perovskite catalyst material. The noble metal-free lanthanum transition metal perovskite catalyst material may include a two phase mixture of a lanthanum transition metal perovskite with an alkali or alkaline earth metal carbonate, a lanthanum transition metal perovskite doped with an alkali or alkaline earth metal, or a combination thereof. The lanthanum transition metal perovskite catalyst material provides direct decomposition of NOx into N.sub.2 and O.sub.2 without the presence of a noble metal and in the presence of excess O.sub.2.