An acid-gas capturing apparatus according to an embodiment includes an absorption unit configured to discharge an absorption-unit exhaust gas, and a regeneration unit configured to discharge a regeneration unit exhaust gas. The regeneration unit exhaust gas is compressed in a compression unit. The absorption-unit exhaust gas or the regeneration unit exhaust gas before it is compressed by the compression unit is cleaned in a first cleaning unit by means of a first cleaning liquid. A compression-condensate liquid, which is generated by the compression of the regeneration unit exhaust gas in the compression unit, is mixed into the first cleaning liquid through a first compression-condensate-liquid line whose one end is connected to the compression unit.

Smoking article include a smokable material and an activated carbon particle downstream of the smokable material. The activated carbon particle is produced from a whole seed. The activated carbon particle has a length, width and height. At least two of the length width and height are independently in a range from about 1 mm to about 7.5 mm. The particles can be spheroids, in which case the length, width and height would be the same or similar.

The invention relates to a gas scrubbing process for purifying crude synthesis gas with methanol as a physical absorption medium, wherein an acid gas comprising at least hydrogen sulfide (H.sub.2S) is produced. The acid gas is produced in a hot regenerator arranged downstream of an absorption apparatus and subsequently separated from gaseous methanol in an acid gas separator by cooling and condensation. The acid gas separator has a condensation region and an absorption region, wherein both regions are separated from one another by a gas-permeable tray. This has the result that impurities such as hydrogen cyanide and/or ammonia outgassing from a first acid gas substream are not reabsorbed in the condensation region of the acid gas separator, thus avoiding an accumulation of impurities in the hot regenerator or other parts of the gas scrubbing plant. The invention further relates to an acid gas separator and to the use of the acid gas separator according to the invention in a process according to the invention.

This disclosure relates to improved methods for alkali metal cyanide production, particularly to improved methods for sodium cyanide production. The improved method of producing sodium cyanide involves the step of contacting hydrogen cyanide with an aqueous solution of sodium carbonate or of a mixture of sodium carbonate and sodium bicarbonate to produce a sodium cyanide solution.

The invention relates to an absorber column and to the use thereof for separation of unwanted, especially acidic, gas constituents, for example carbon dioxide and hydrogen sulfide, from a crude synthesis gas by absorption with an absorbent, especially under low load states of the absorber column in relation to the synthesis gas velocity. According to the invention, a defined concentration of carbon dioxide in the clean synthesis gas is established by mixing at least a portion of the absorbent regenerated by flash regeneration with the absorbent regenerated by means of hot regeneration prior to the recycling thereof into the absorber column.

The invention relates to a gas scrubbing process and plant for purifying raw synthesis gas by physical absorption in methanol. A raw synthesis gas stream which includes hydrogen and carbon monoxide as desired constituents and water and acid gases as undesired constituents is admixed with methanol and subsequently cooled below the freezing point of water. According to the invention a liquid phase including methanol and water is separated from the cooled raw synthesis gas stream. Acid gases are removed from the remaining gaseous phase by physical absorption in methanol at elevated pressure. Separating the water from the raw synthesis gas stream before the absorption of the acid gases prevents larger amounts of water passing into the methanol circuit of the gas scrubbing process. This achieves savings in resources and certain plant parts may be smaller than is customary.

A process for the stepwise separation of accompanying gases from a raw synthesis gas stream by a liquid absorbent countercurrently guided through all process steps and circulated via regeneration plants, wherein either the accompanying gases H.sub.2S, COS and CO.sub.2 are separated in a common absorption step or, in one of the selective absorption steps chiefly H.sub.2S and COS are separated and in the next step in flow direction of the gas chiefly CO.sub.2 is separated, and in the last step a separation of accompanying gas residues (fine wash) is effected, wherein before the separation of H.sub.2S and COS an absorption step chiefly for the separation of aromatics and subsequently an absorption step chiefly for the separation of methyl mercaptan is carried out.

This invention relates to a Cu-BTC MOF which is water stable. The Cu-BTC MOF has been modified by substituting some of the BTC ligand (1,3,5, benzene tricarboxylic acid) with 5-aminoisophthalic acid (AIA). The resultant MOF retains at least 40% of its as synthesized surface area after exposure to liquid water at 60° C. for 6 hours. This is an unexpected result versus the MOF containing only the BTC ligand. This MOF can be used to abate contaminants such as ammonia in gas streams and especially air streams.

The present disclosure provides a process for cleaning raw product gas. The process includes contacting the raw product gas with a flow of catalyst to reform organic contaminants and inorganic contaminants in the raw product gas and to remove particulates. Further, the process includes cooling the resulting product gas via heat exchange with a heat exchange medium in the presence of char or a solid adsorbent medium to condense remaining organic contaminants and inorganic contaminants on the char or solid adsorbent medium and to filter out fine particulates.

The invention is directed to an adsorbent comprising: a) 20-30% porous carbon with incorporated organic nitrogen species; and b) 70-80% inorganic matter. The invention is directed to a method of making an adsorbent which comprises: a) thermally drying dewatered sewage sludge to form granulated organic fertilizer; and b) pyrolyzing said the organic fertilizer at temperatures between 600 and 1000° C. The invention is additionally directed to the process of removing acidic gases from wet air streams comprising putting an adsorbent in contact with the wet air stream and allowing the adsorbent to adsorb the acidic gases.