An emissions clean-up process is provided to remove detrimental exhaust gases from a fossil fuel power plant and to produce and/or reclaim various useful commercial byproducts. The process includes mixing a blended liquid solution with a solubilizer in a mixing tank to create a chemical reaction therein to produce an ionic solid and an alkaline liquid solution. By mixing various blended solutions with desired solubilizers, alkaline liquids are produced which may be chemically combined to create other byproducts or sold commercially. Likewise, the alkaline liquids may be passed through a wet scrubber to create a byproduct that when chemically mixed with an acid creates desired byproducts. Other byproducts such as a sodium bicarbonate liquid solution exits the wet scrubber and is sold or used in the subject process to produce various other byproducts.

An alkaline aqueous ferric iron salt solution is disclosed. Generally, the alkaline aqueous ferric iron salt solution comprises ferric ions (Fe.sup.3+), potassium ions (K.sup.+), carbonate ions (CO.sub.3.sup.2−), bicarbonate ions (HCO.sub.3.sup.−), hydroxide ions (OH.sup.−), optionally nitrate ions (NO.sub.3.sup.−). Further, a molar ratio of the potassium ions to the ferric ions is generally at least 5.0. The ferric iron is complexed with carbonate, bicarbonate or both to form a water-soluble complex that is anionic in nature and highly soluble in the alkaline aqueous ferric iron salt solution at pH above 8.5, and a pH of the alkaline aqueous ferric iron salt solution is at least 8.5.

The present invention is directed to the removal of mercury from a gas phase by injecting a scavenger solution into the gas phase.

A partitioning wall is provided in a fluid space formed between a cover member and a body member, which surrounds a forward end of a fluid injection valve. The partitioning wall divides the fluid space into an inlet-side fluid space and an outlet-side fluid space in a circumferential direction of the fluid injection valve. A forward-end space, which is formed at a bottom of the fluid space, is communicated to the inlet-side and the outlet-side fluid spaces, so that cooling water flows from the inlet-side fluid space to the outlet-side fluid space through the forward-end space. The cooling water circulates in the forward-end space surrounding the forward end of the fluid injection valve to effectively cool down the fluid injection valve.

The boiler (1) has side tubed walls (2) enclosing an inner space (3) and a device for selective non catalytic reduction (7). The device for selective non catalytic reduction (7) has a lance (8) carrying a hose (9) having at least a nozzle (10) and a hose drive mechanism (11) for driving the hose within the lance. The lance (8) protrudes into the inner space (3) from a side tubed wall (2) of the boiler (1).

The invention relates to a method for treating emergency spill or leak of halogen which is bromine or chlorine, comprising contacting an aqueous solution of quaternary ammonium halide with the halogen.

Disclosed are compositions and methods of ammonia removal in contaminated liquid and gas streams. The compositions may comprise water-soluble phosphonium compounds that react selectively with ammonia at ambient conditions to form covalent compounds. For liquid-phase treatment, the water-soluble phosphonium compounds may be dosed into the contaminated streams followed by pH adjustment using pH elevating compounds to form insoluble compounds. For gas-phase treatment, the water-soluble phosphonium compounds may be used either as scrubbing solution or as solid adsorbent obtained by impregnation into solid substrates to form solid scavengers, to selectively absorb and react with ammonia in a scrubber system.

The present invention provides a new carbon dioxide fixation apparatus. The carbon dioxide fixation apparatus (1) of the present invention includes: a first reaction vessel (10); a carbon dioxide fixing agent feeding unit (110); and a gas-liquid mixing unit. The first reaction vessel (10) can contain a carbon dioxide fixing agent, the carbon dioxide fixing agent feeding unit (110) can feed the carbon dioxide fixing agent into the first reaction vessel (10), and the gas-liquid mixing unit can mix a gas containing carbon dioxide into the carbon dioxide fixing agent.

A fluid injection system includes a mixing chamber locatable in an exhaust gas conduit upstream of a selective catalytic reduction device for providing an exhaust gas flow path and space for receiving injected fluid, an injector with a plurality of bundled capillary tubes each having an inlet configured to receive a fluid for injection into the chamber and an outlet wherein the injector is mounted on the chamber with the tube outlets in fluid communication with the chamber space, a base plate disposed in the chamber spaced from and aligned with the bundled tubes, a voltage supply connected to the tubes and to the base plate for providing a charge to the tubes and to the base plate to create an electric field to the fluid in the tubes, and a valve disposed on a wall of the chamber for at least one of priming and purging of the tubes.

A co-axial co-current contactor (CA-CCC) is described herein. The CA-CCC includes an outer annular support ring and an inner annular support ring configured to maintain the CA-CCC within an outer pipe and an inner pipe, respectively. The CA-CCC includes rich liquid flow channels located between the outer annular support ring and the inner annular support ring that are configured to allow a rich liquid stream to flow through the CA-CCC, and a central gas entry cone and gas flow channels configured to allow a gas stream to flow through the CA-CCC. The CA-CCC further includes radial blades configured to secure the central gas entry cone to the inner annular support ring and allow a lean liquid stream to flow into the central gas entry cone and the gas flow channels. The CA-CCC provides for efficient incorporation of liquid droplets formed from the lean liquid stream into the gas stream.