Embodiments of the present disclosure provide for substrates having an oxide shell layer (e.g., a silica shell layer), methods of making an oxide shell layer, and the like.

Embodiments of the present disclosure provide for substrates having an oxide shell layer (e.g., a silica shell layer), methods of making an oxide shell layer, and the like.

The disclosure relates to a method of performing ozonolysis or ozone-based oxidation on a liquid or emulsified reagent using a tubular falling film reactor with one or multiple tubes wherein the combined ozone and carrier gas flow is co-current.

The disclosure relates to a method of performing ozonolysis or ozone-based oxidation on a liquid or emulsified reagent using a tubular falling film reactor with one or multiple tubes wherein the combined ozone and carrier gas flow is co-current.

Disclosed herein is a constant shear continuous reactor device, comprising: an annular gas delivery tube comprising a gas inlet and a gas outlet; a first annular liquid delivery tube comprising a first liquid inlet and a first liquid outlet arranged concentrically around the annular gas delivery tube along a common axis, where the first liquid outlet is located at a downstream position relative to the gas outlet or is coterminous with the gas outlet; and an annular reactor wall tube comprising a final liquid inlet, a mixing zone section and a reactor outlet, where the annular reactor wall tube is arranged concentrically around the first annular liquid delivery tube along the common axis.

Disclosed herein is a constant shear continuous reactor device, comprising: an annular gas delivery tube comprising a gas inlet and a gas outlet; a first annular liquid delivery tube comprising a first liquid inlet and a first liquid outlet arranged concentrically around the annular gas delivery tube along a common axis, where the first liquid outlet is located at a downstream position relative to the gas outlet or is coterminous with the gas outlet; and an annular reactor wall tube comprising a final liquid inlet, a mixing zone section and a reactor outlet, where the annular reactor wall tube is arranged concentrically around the first annular liquid delivery tube along the common axis.

A gas-liquid contact apparatus has a gas-liquid contact unit, a liquid supply system, and a gas supply system. The gas-liquid contact unit includes a plurality of stages which are allocated so as to be arranged in the lateral direction. Each of the plurality of stages includes a plurality of vertical flat plates arranged parallel to each other at intervals. The liquid supply system supplies a liquid to the gas-liquid contact unit, and causes the liquid to be circulated along the arrangement of the plurality of stages successively. The gas supply system supplies a gas to the gas-liquid contact unit, and causes the gas to be circulated along the arrangement of the plurality of stages successively. The supplied liquid flows down on the plurality of vertical flat plates in each of the plurality of stages, and comes into contact with the supplied gas.

A shell-and-tube equipment has a cylindrical geometry and is arranged along a vertical axis. The shell-and-tube equipment comprises an upper chamber and a lower chamber connected to a common tube bundle on opposite sides. The upper chamber is provided with at least an inlet nozzle for inletting a first fluid. The tube bundle is surrounded by a shell provided with nozzles for inletting and outletting a second fluid which exchanges heat with the first fluid through the tube bundle. The upper chamber encloses at least a distribution device configured for uniformly delivering the first fluid towards the tube bundle. The distribution device comprises an annular channel which is arranged around the vertical axis and is in fluid communication with the inlet nozzle. The distribution device comprises a plurality of channel modules of circular trapezoid shape, tightly joined together at their respective vertical edges for forming the annular channel.

A shell-and-tube equipment has a cylindrical geometry and is arranged along a vertical axis. The shell-and-tube equipment comprises an upper chamber and a lower chamber connected to a common tube bundle on opposite sides. The upper chamber is provided with at least an inlet nozzle for inletting a first fluid. The tube bundle is surrounded by a shell provided with nozzles for inletting and outletting a second fluid which exchanges heat with the first fluid through the tube bundle. The upper chamber encloses at least a distribution device configured for uniformly delivering the first fluid towards the tube bundle. The distribution device comprises an annular channel which is arranged around the vertical axis and is in fluid communication with the inlet nozzle. The distribution device comprises a plurality of channel modules of circular trapezoid shape, tightly joined together at their respective vertical edges for forming the annular channel.

The disclosure relates to a method of performing ozonolysis or ozone-based oxidation on a liquid or emulsified reagent using a tubular falling firm reactor with one or multiple tubes wherein the combined ozone and carrier gas flow is co-current.